牛胜利, 韩奎华, 路春美. 生物质先进再燃脱硝特性研究[J]. 燃料化学学报(中英文), 2010, 38(06): 745-751.
引用本文: 牛胜利, 韩奎华, 路春美. 生物质先进再燃脱硝特性研究[J]. 燃料化学学报(中英文), 2010, 38(06): 745-751.
NIU Sheng-Li, Han-Kui-Hua, Lu-Chun-Mei. Study on nitrogen oxides reduction by advanced biomass reburning process[J]. Journal of Fuel Chemistry and Technology, 2010, 38(06): 745-751.
Citation: NIU Sheng-Li, Han-Kui-Hua, Lu-Chun-Mei. Study on nitrogen oxides reduction by advanced biomass reburning process[J]. Journal of Fuel Chemistry and Technology, 2010, 38(06): 745-751.

生物质先进再燃脱硝特性研究

Study on nitrogen oxides reduction by advanced biomass reburning process

  • 摘要: 在沉降炉上研究草本类棉秆、玉米秸、麦秆和木本类梧桐木四种生物质的先进再燃脱硝特性。结果表明,20%再燃比、0.7s停留时间能保证较优的反应工况。在过量空气系数为0.7~0.9、氨氮摩尔比为1.5左右时,棉杆、玉米秸、麦秆以及梧桐木先进再燃在1273K附近取得最高脱硝效率,其值分别为89.11%、88.34%、90.33%和88.28%,比基本再燃提高25%~30%,并且生物质的再燃反应是脱硝的主体,喷氨是对再燃的完善和优化。在1173K~1473K四种生物质的先进再燃可以保持80%以上的脱硝效率。实验过程中加入100×10-6的碱金属、碱土金属添加剂可进一步改良先进再燃脱硝进程。碳酸钠、碳酸钾使脱硝效率提高3%~6%;醋酸钙在1273K~1473K将脱硝率提高4.0%~5.0%,在1073K~1273K作用规律不明显。

     

    Abstract: Advanced reburning (AR) tests were conducted in a vertical-tube experimental system using herbaceous biomass of cotton-haulm, corn-stalk, wheat-stalk and woody biomass of phoenix tree as reburning fuels. The results show that the Rff of 20% and residence time of 0.7s are better for the reburning process. When the excess air ratio ranges from 0.7 to 0.9, and NH3/NO mol ratio (NSR) is about 1.5, the maximum efficiency of nitrogen oxides (NOx) reduction at 1273K by cotton-haulm, corn-stalk, wheat-stalk and phoenix reburning reaches 89.11%, 88.34%, 90.33% and 88.28%, respectively, which is 25%~30% higher than that by general reburning. It indicates that the biomass reburning plays a great role for the NOx reduction in AR and the ammonia-ejection plays a role for optimizing the course. In a broad range of 1173K~1473K, the AR of all tested biomass could gain NOx reduction beyond 80%. The NOx reduction can be further meliorated by adding alkali metals and alkaline earth promoters with 100×10-6 vol concentration, and the promoting effect differs from each other. The sodium carbonate and potassium carbonate can enhance the efficiency by 3%~6%; and the calcium acetate can enhance the efficiency by 4.0%~5.0% at 1273K~1473K but by nothing at 1073K~1273K.

     

/

返回文章
返回