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Co-Ni-B/SBA-15催化1-辛烯氢甲酰化活性研究

郭靖 范素兵 高新华 马清祥 张建利 赵天生

郭靖, 范素兵, 高新华, 马清祥, 张建利, 赵天生. Co-Ni-B/SBA-15催化1-辛烯氢甲酰化活性研究[J]. 燃料化学学报(中英文), 2021, 49(7): 945-951. doi: 10.1016/S1872-5813(21)60048-8
引用本文: 郭靖, 范素兵, 高新华, 马清祥, 张建利, 赵天生. Co-Ni-B/SBA-15催化1-辛烯氢甲酰化活性研究[J]. 燃料化学学报(中英文), 2021, 49(7): 945-951. doi: 10.1016/S1872-5813(21)60048-8
GUO Jing, FAN Su-bing, GAO Xin-hua, MA Qing-xiang, ZHANG Jian-li, ZHAO Tian-sheng. Study on catalytic performance of Co-Ni-B/SBA-15 for hydroformylation of 1-octene[J]. Journal of Fuel Chemistry and Technology, 2021, 49(7): 945-951. doi: 10.1016/S1872-5813(21)60048-8
Citation: GUO Jing, FAN Su-bing, GAO Xin-hua, MA Qing-xiang, ZHANG Jian-li, ZHAO Tian-sheng. Study on catalytic performance of Co-Ni-B/SBA-15 for hydroformylation of 1-octene[J]. Journal of Fuel Chemistry and Technology, 2021, 49(7): 945-951. doi: 10.1016/S1872-5813(21)60048-8

Co-Ni-B/SBA-15催化1-辛烯氢甲酰化活性研究

doi: 10.1016/S1872-5813(21)60048-8
基金项目: 宁夏重点研发计划东西部合作项目(2017BY063)资助
详细信息
    作者简介:

    郭靖(1984-),女,博士研究生,研究方向:高碳烯烃氢甲酰化。E-mail:guojingsn@163.com

    通讯作者:

    Tel:0951-2062237, E-mail:zhaots@nxu.edu.cn

  • 中图分类号: O643.3

Study on catalytic performance of Co-Ni-B/SBA-15 for hydroformylation of 1-octene

Funds: The project was supported by the East-West Cooperation Project, Key R & D Plan of Ningxia (2017BY063)
More Information
  • 摘要: 超声辅助浸渍法制备了SBA-15分子筛负载三组分非晶态Co-Ni-B,研究了其对1-辛烯氢甲酰化制壬醛反应的催化性能。SBA-15负载纳米非晶态Co-Ni-B,增加了Co-Ni-B的分散;且非晶态Co-Ni-B转化为晶体的温度升高约280 ℃,耐热稳定性增强。Co-Ni-B/SBA-15催化剂,其中,Co = 17.22%,n(Ni)/n(Co) = 0.157,n(B)/n(Co + Ni) = 0.434,用于120 ℃、5 MPa条件下氢甲酰化反应,间歇反应4 h,1-辛烯完全转化,壬醛选择性91.24%;相比Co-Ni-B,副产物减少一倍。催化剂重复使用五次,活性稳定。
  • FIG. 800.  FIG. 800.

    FIG. 800.  FIG. 800.

    图  1  催化剂的XRD谱图

    Figure  1  XRD patterns of catalysts

    图  2  催化剂的N2吸附-脱附等温曲线和孔径分布

    Figure  2  N2 adsorption isotherms and pore distribution of catalysts

    图  3  催化剂的TEM、SAED照片和元素映射图(Co-Ni-B/SBA-15)

    Figure  3  TEM images and SAED patterns of various catalysts and elemental mapping of Co-Ni-B/SBA-15

    图  4  催化剂的XPS谱图

    Figure  4  XPS spectra of catalysts

    图  5  Co-Ni-B和Co-Ni-B/SBA-15的差示扫描量热谱图

    Figure  5  DSC profiles of Co-Ni-B and Co-Ni-B/SBA-15

    图  6  焙烧Co-Ni-B/SBA-15催化剂的XRD谱图

    Figure  6  XRD patterns of calcined Co-Ni-B/SBA-15

    图  7  Co-Ni-B/SBA-15重复使用五次后的XRD谱图

    Figure  7  XRD patterns of Co-Ni-B/SBA-15 after 5 repetition use

    图  8  Co-Ni-B/SBA-15的可重复使用性

    Figure  8  Repeatability of Co-Ni-B/SBA-15

    表  1  催化剂的织构性质

    Table  1  Textural properties of catalysts

    CatalystReal bulk w/%Real loading w/%ABET/(m2·g−1)vpore/(cm3·g−1)Dpore/nm
    CoNiB
    SBA-157131.037.8
    Co-Ni-B63.5210.747.2522.90.1526.6
    Co-Ni-B/SBA-1517.222.691.5921.505390.646.8
    Co-B/SBA-1515.991.2817.274530.496.6
    Ni-B/SBA-1519.031.6520.684130.577.3
    下载: 导出CSV

    表  2  1-辛烯氢甲酰化催化活性

    Table  2  Catalytic activity for hydroformylation of 1-octene

    CatalystCo/1-octene(molar ratio)x/%Product s/%Aldehyde yield/%n/iTON
    nonanalisononanalisomersothers
    Co-Ni-B/SBA-150.01810054.8936.358.290.4791.241.5155.5
    Co-B/SBA-150.01910050.6434.3010.025.0484.941.4852.3
    Ni-B/SBA-155.8127.6311.5146.2814.582.272.403.3
    Co-Ni-B0.05594.6349.4832.9917.53078.041.5917.3
    cat. 0.25 g, toluene 13 g, 1-octene 3.57 g, 120 ℃, 5 MPa, 1200 r/min, 4 h
    下载: 导出CSV

    表  3  焙烧对催化活性的影响

    Table  3  Effect of calcination on catalytic activity

    Calc. t/℃x/%Product s/%Aldehyde yield/%n/iTON
    nonanalisononanalisomersothers
    Uncalcined10054.8936.358.290.4791.241.5155.5
    30010047.4931.8512.598.0779.341.4955.1
    40097.1549.8630.4917.082.5778.061.5953.2
    50092.6736.5424.0316.9722.4656.131.5250.7
    60024.6235.0321.2318.6125.1313.851.6513.5
    Co-Ni-B/SBA-15 0.25 g, toluene 13 g, 1-octene 3.57 g, 120 ℃, 5 MPa, 1200 r/min, 4 h
    下载: 导出CSV
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  • 收稿日期:  2021-01-11
  • 修回日期:  2021-02-01
  • 网络出版日期:  2021-03-30
  • 刊出日期:  2021-07-15

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