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CO2 valorization through methyl N-phenylcarbamate synthesis

XUN Jia-yao SONG Qing-wen ZHANG Qian-xia HAN Li-hua ZHANG Kan ZHANG Jian-li LIU Ping

荀家瑶, 宋清文, 张乾霞, 韩丽华, 张侃, 张建利, 刘平. 二氧化碳高值利用合成苯氨基甲酸甲酯[J]. 燃料化学学报. doi: 10.1016/S1872-5813(22)60047-1
引用本文: 荀家瑶, 宋清文, 张乾霞, 韩丽华, 张侃, 张建利, 刘平. 二氧化碳高值利用合成苯氨基甲酸甲酯[J]. 燃料化学学报. doi: 10.1016/S1872-5813(22)60047-1
XUN Jia-yao, SONG Qing-wen, ZHANG Qian-xia, HAN Li-hua, ZHANG Kan, ZHANG Jian-li, LIU Ping. CO2 valorization through methyl N-phenylcarbamate synthesis[J]. Journal of Fuel Chemistry and Technology. doi: 10.1016/S1872-5813(22)60047-1
Citation: XUN Jia-yao, SONG Qing-wen, ZHANG Qian-xia, HAN Li-hua, ZHANG Kan, ZHANG Jian-li, LIU Ping. CO2 valorization through methyl N-phenylcarbamate synthesis[J]. Journal of Fuel Chemistry and Technology. doi: 10.1016/S1872-5813(22)60047-1

二氧化碳高值利用合成苯氨基甲酸甲酯

doi: 10.1016/S1872-5813(22)60047-1
详细信息
  • 中图分类号: TQ217

CO2 valorization through methyl N-phenylcarbamate synthesis

More Information
  • 摘要: 苯氨基甲酸甲酯(MPC)是合成二苯甲烷二异氰酸酯(MDI)的关键原料。以二氧化碳(CO2)及其等价物或衍生物作为碳源合成MPC代表了绿色和可持续的精细化学品合成方法。基于该领域研究,文章概述了基于CO2转化合成苯氨基甲酸甲酯的研究方法进展。合成路线包括研究较多的CO2等价物(尿素或苯基脲)醇解法,碳酸二甲酯(DMC)氨解法以及二苯基脲和DMC耦合反应法。另外,最理想的合成方法是近几年发展的苯胺、CO2和甲醇三组分“一锅”反应法,以及使用脂肪胺类原料构建氨基甲酸烷基酯类化合物,其代表了最有前景的CO2利用途径之一。文中详细探讨了反应机理和催化剂选择等问题。研究进展将为进一步提升绿色催化和可持续化学过程效率提供重要理论支持。
  • 1  Traditional MDI synthetic methods

    2  Proposed routes to MPC via three different processes [50]

    3  Possible route of CeO2-catalyzed four-component reaction

    Table  1  Metal catalysts for MPC synthesis from aniline and DMC

    EntryCatalystSupporterConditionsResultsRef.
    T(oC)P(MPa)t(h)Conv.(%)Sel.(%)Y.(%)
    1Zn(OAc)2AC1500.14--9878[31]
    2Zn(OAc)2--1700.129990--[33]
    3Zn(OAc)2SiO21900.1597.289.4--[34]
    4Zn(OAc)2--1300.1398--97[35]
    5zinc alkyl carboxylatesilica1700.1194.696.891.6[36]
    6Zn/Al/Ce mixed oxide--2000.1795.881.678.2[37]
    7ZnO-TiO2SiO21700.1749.952.3--[38]
    8ZrO2SiO21700.1779.280.1--[39]
    9PbOSiO21500.1291.0890.3782.31[40]
    10In2O3SiO21500.1275.9878.2459.45[40]
    11PbOSiO21600.1499.799.899.5[41]
    12Pb3O4-ZnO--1700.1481----[42]
    Note: Conversion (Conv.), Selectivity (Sel.), Yield (Y.). (--: The mark indicates no available information in the reference)
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  • 收稿日期:  2022-05-20
  • 录用日期:  2022-06-20
  • 修回日期:  2022-06-20
  • 网络出版日期:  2022-07-11

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