Recent advances in integrated carbon dioxide capture and methanation technology
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摘要: 开发新型高效的二氧化碳捕集或利用技术对于减少化石能源利用过程的二氧化碳排放、缓解全球变暖等具有重要意义。集成二氧化碳捕集与利用技术（ICCU）因其能耗低和效率高等优势获得了广泛关注。该技术利用一种双功能材料通过集成二氧化碳吸附和原位转化两个主要过程，实现CO2的高效转化并获得含碳燃料。本工作综述了ICCU中主要技术之一集成二氧化碳捕集与甲烷化转化。首先对实现该过程的双功能材料的组成和特性进行概述，重点从反应温度、反应时间、反应气体成分等角度探讨了影响ICCU甲烷化反应的因素，并对该技术未来的机遇和挑战进行总结和展望，以期为中国“双碳”目标下致力于二氧化碳捕集和利用的相关研究提供一定的借鉴。Abstract: The development of novel carbon dioxide capture or utilization technology is of great significance to reduce carbon dioxide emissions from fossil energy utilization, as well as to alleviate global warming. The integrated carbon dioxide capture and utilization (ICCU) technology, which integrate carbon dioxide adsorption and in-situ conversion to realize efficient conversion of carbon dioxide to carbon containing fuels over dual function material, has attracted extensive attentions due to its advantages of low energy consumption and high efficiency. In this paper, the composition and characteristics of the dual function materials for CO2 capture and methanation were summarized. The factors which affected the methanation process were discussed from the perspectives of reaction temperature, reaction time, feed gas compositions. The challenges and opportunities in the near future were also proposed.
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Key words:
- carbon dioxide /
- capture and utilization /
- methanation /
- dual function materials
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图 1 利用DFMs进行集成CO2的捕集和转化系统示意图
Figure 1 Schematic diagram of integrated CO2 capture and conversion system using DFMs
表 1 CO2的捕集和利用
Table 1 Summary of CO2 capture and utilization technology
Technology Description Advantages Disadvantages Ref. CO2 capture technology pre-combustion capture separate other combustibles from CO2 before carbon based fuel combustion high CO2 concentration
and easy separationneed upgrade current power plant which is difficult and high-cost [8,9] oxy-fuel combustion capture burning fuel using pure oxygen, or a mixture of oxygen, capture CO2 in
tail gasproducts can be stored directly high cost of oxygen production, sensitive to air leakage [10] post-combustion capture adsorption separation the different binding force between porous materials and gases is used to realize the separation of gas mixtures flexible operation, safe and low cost poor selectivity, unstable performance of some inorganic adsorbents [11,12] absorption separation separation of gas mixtures using different solubility high CO2 concentration and high yield high energy consumption, high equipment investment [13] membrane separation capture using differences in solubility and diffusivity high selectivity, low
energy consumptionnarrow application, poor stability [14,15] CO2 utilization technology electrochemical conversion the reduction of CO2 into chemicals is driven by the potential difference between the two electrodes flexible operation, mild reaction conditions low stability of electrocatalyst, high energy consumption [16] solar thermochemical conversion technology solar radiation is used to drive CO2 and H2O to produce strong endothermic reaction for utilization low energy consumption low conversion efficiency [17] photochemical
conversionCO2 conversion reaction is promoted by absorbing heat energy and overcoming activation energy mild reaction conditions, strong oxidation ability low efficiency in light energy utilization rate, difficulty in control [18] catalytic conversion catalysts are used to promote the formation and fracture of chemical bonds low cost and good safety stability and conversion efficiency need improvement [19,20] 
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