Structural features and combustion reactivity of residual carbon in fine slag from entrained-flow gasification

LÜ Deng-pan; BAI Yong-hui; WANG Jiao-fei; SONG Xu-dong; SU Wei-guang; YU Guang-suo; ZHU he; TANG Guang-jun

doi:10.1016/S1872-5813(21)60011-7

Volume 49 Issue 2

Feb. 2021

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Article Navigation > Journal of Fuel Chemistry and Technology > 2021 > 49(2): 129-136

LÜ Deng-pan, BAI Yong-hui, WANG Jiao-fei, SONG Xu-dong, SU Wei-guang, YU Guang-suo, ZHU he, TANG Guang-jun. Structural features and combustion reactivity of residual carbon in fine slag from entrained-flow gasification[J]. Journal of Fuel Chemistry and Technology, 2021, 49(2): 129-136. doi: 10.1016/S1872-5813(21)60011-7

Citation:

LÜ Deng-pan, BAI Yong-hui, WANG Jiao-fei, SONG Xu-dong, SU Wei-guang, YU Guang-suo, ZHU he, TANG Guang-jun. Structural features and combustion reactivity of residual carbon in fine slag from entrained-flow gasification[J]. Journal of Fuel Chemistry and Technology, 2021, 49(2): 129-136. doi: 10.1016/S1872-5813(21)60011-7

Citation:

LÜ Deng-pan, BAI Yong-hui, WANG Jiao-fei, SONG Xu-dong, SU Wei-guang, YU Guang-suo, ZHU he, TANG Guang-jun. Structural features and combustion reactivity of residual carbon in fine slag from entrained-flow gasification[J]. Journal of Fuel Chemistry and Technology, 2021, 49(2): 129-136. doi: 10.1016/S1872-5813(21)60011-7

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Structural features and combustion reactivity of residual carbon in fine slag from entrained-flow gasification

doi: 10.1016/S1872-5813(21)60011-7

1.
State Key Laboratory of High-efficiency Coal Utilization and Green Chemical Engineering, College of Chemistry and Chemical Engineering, College of Chemistry and Chemical Engineering Ningxia University, Yinchuan 750021, China
2.
Institute of Clean Coal Technology, East China University of Science and Technology, Shanghai 200237, China
3.
ShandongYankuangguotuo Science & Engineering Co., Ltd, Zoucheng 273500, China

Funds: The project was supported by the National Natural Science Foundation of China (21968024) and the Project of Key Research Plan of Ningxia(2019BEB04001)

Received Date: 2020-09-24
Rev Recd Date: 2020-11-10
Publish Date: 2021-02-08

Abstract

Abstract

The carbon content in fine slag during entrained-flow gasification is very high, at present, most of the fine slag was disposed by landfill. It is expected to provide a favorable technology by adding the fine slag to the circulating fluidized bed boilers to participate in combustion reaction. In this study, the gasification fine slags generated from GE, OMB and GSP gasifier, which are typical gasification processes in Ningdong energy and chemical base, was selected for investigation. The structural features and combustion reactivity of the residual carbon in the gasification fine slag were systematically studied by physical adsorption apparatus, laser Raman spectrum and thermogravimetric analyzer. The results showed that the materials in the original gasification fine slag could be divided into cohesive spherical particles, porous irregular particles and isolated large spherical particles, while the acid-washed gasification fine slag was mostly composed of loose fine particles and porous irregular massive particles. Additionally, the particle size of the residual carbon was clustered to 4–8 nm, and the specific surface area and active sites of that decreased orderly as follows: GE>OMB>GSP. The order degree of the residual carbon structure in GE slag was the lowest, and the amorphous carbon structure in it was the highest, while the case in GSP was the opposite. The combustion rate of the residual carbon in GE slag was the fastest, mainly due to its large specific surface area, more amorphous carbon structure and active site, and the comprehensive combustion index of residual carbon in GE slag was 5.26×10⁻⁷%²/(min²·^oC ³).
- fine slag,
- physic-chemical properties,
- structure characteristics,
- combustion characteristics

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References(24)

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