Synergistic hydrogenolysis of biomass furfuryl alcohol over Ru/solid base catalysts in hydrothermal reaction environment

WENG Yu-jing; MENG Shi-hang; ZHU Wan-sheng; ZHANG Ming-wei; SUN Qi; ZHANG Yu-long

doi:10.1016/S1872-5813(21)60111-1

Volume 49 Issue 12

Dec. 2021

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Article Navigation > Journal of Fuel Chemistry and Technology > 2021 > 49(12): 1867-1875

WENG Yu-jing, MENG Shi-hang, ZHU Wan-sheng, ZHANG Ming-wei, SUN Qi, ZHANG Yu-long. Synergistic hydrogenolysis of biomass furfuryl alcohol over Ru/solid base catalysts in hydrothermal reaction environment[J]. Journal of Fuel Chemistry and Technology, 2021, 49(12): 1867-1875. doi: 10.1016/S1872-5813(21)60111-1

Citation:

WENG Yu-jing, MENG Shi-hang, ZHU Wan-sheng, ZHANG Ming-wei, SUN Qi, ZHANG Yu-long. Synergistic hydrogenolysis of biomass furfuryl alcohol over Ru/solid base catalysts in hydrothermal reaction environment[J]. Journal of Fuel Chemistry and Technology, 2021, 49(12): 1867-1875. doi: 10.1016/S1872-5813(21)60111-1

Citation:

WENG Yu-jing, MENG Shi-hang, ZHU Wan-sheng, ZHANG Ming-wei, SUN Qi, ZHANG Yu-long. Synergistic hydrogenolysis of biomass furfuryl alcohol over Ru/solid base catalysts in hydrothermal reaction environment[J]. Journal of Fuel Chemistry and Technology, 2021, 49(12): 1867-1875. doi: 10.1016/S1872-5813(21)60111-1

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Synergistic hydrogenolysis of biomass furfuryl alcohol over Ru/solid base catalysts in hydrothermal reaction environment

doi: 10.1016/S1872-5813(21)60111-1

1.
School of Chemistry and Chemical Engineering, Henan Polytechnic University, Jiaozuo 454003, China
2.
Henan Key Laboratory of Coal Green Conversion, Jiaozuo 454003, China

More Information

Corresponding author: E-mail：wengyj@hpu.edu.cn；Tel：0391-3987810
Received Date: 2021-03-19
Rev Recd Date: 2021-05-08

Available Online: 2021-06-09

Publish Date: 2021-12-29

Abstract

Abstract

In this paper, Ru/solid base catalysts were employed to realize the direct hydrogenolysis of furfuryl alcohol into tetrahydrofurfuryl alcohol and 1,2-pentanediol. Moreover, the catalyst preparation, activation and reaction conditions were screened. It was found that the yield and selectivity of 1, 2-pentanediol were improved by the preparation of Ru based catalyst with basic metal oxides as support. The total yield of tetrahydrofurfuryl alcohol (53%) and 1, 2-pentanediol (32%) was 85% under the optimal reaction conditions over Ru/MnO₂. Subsequently, N₂ adsorption-desorption, XRD and XPS were employed to reveal the catalytic mechanism which suggested that the synergistic between the surface basic groups and active metals might account for the better catalytic performance.
- furfuryl alcohol,
- 1,2-pentanediol,
- tetrahydrofurfuryl alcohol,
- catalysis,
- hydrogenolysis

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References(32)

References

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