Efficient separation of phenols from phenols-containing oil mixtures via forming hydrogen bonds

JI You-an; ZHAO Xiao-sheng; LIU Qing; YANG Yu-feng; HAN Jiang-ze

doi:10.1016/S1872-5813(21)60137-8

Volume 49 Issue 11

Nov. 2021

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Article Navigation > Journal of Fuel Chemistry and Technology > 2021 > 49(11): 1584-1591

JI You-an, ZHAO Xiao-sheng, LIU Qing, YANG Yu-feng, HAN Jiang-ze. Efficient separation of phenols from phenols-containing oil mixtures via forming hydrogen bonds[J]. Journal of Fuel Chemistry and Technology, 2021, 49(11): 1584-1591. doi: 10.1016/S1872-5813(21)60137-8

Citation:

JI You-an, ZHAO Xiao-sheng, LIU Qing, YANG Yu-feng, HAN Jiang-ze. Efficient separation of phenols from phenols-containing oil mixtures via forming hydrogen bonds[J]. Journal of Fuel Chemistry and Technology, 2021, 49(11): 1584-1591. doi: 10.1016/S1872-5813(21)60137-8

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Efficient separation of phenols from phenols-containing oil mixtures via forming hydrogen bonds

doi: 10.1016/S1872-5813(21)60137-8

1.
College of Chemical and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, China
2.
College of Chemistry and Chemical Engineering, Cangzhou Normal University, Cangzhou 061001, China
3.
Division of Materials Science and Chemical Engineering, Yokohama National University, Yokohama 240-8501, Japan

Funds: The project was supported by the Scientific Research Foundation for the Introduction of Talents of Hebei University of Science and Technology (81/1181381) and the Key Projects of Science and Technology Research in Colleges and Universities of Hebei Province (ZD2021320)

Received Date: 2021-05-31
Rev Recd Date: 2021-07-06

Available Online: 2021-08-10

Publish Date: 2021-11-30

Abstract

Abstract

In this work, the separation of phenol from oil mixtures was proposed by using mildronate (THP), Girard's Reagent T, and Girard's Reagent P. The results showed that the mentioned separation agents could form deep eutectic solvent (DES) with phenol and then separate phenol. The highest separation efficiency of phenol was 96.5% by THP, and the residual phenol content in oil was as low as 1.3 g/L; the separation could be finished in 10 min; the initial phenol content had no effect on the minimum residual phenol content (about 8.8 g/L) in oil after separation. An n-hexane washing method was used to remove the neutral oil entrained in DES. The results showed that the mass ratio of neutral oil to phenol in DES was reduced to 0.04, indicated that the purity of phenol product was greatly improved. THP was renewable and its properties remained unchanged after be reused for 5 times. Finally, FT-IR spectra showed that hydrogen bonds were formed between THP and phenol.
- phenolic compounds,
- separation,
- deep eutectic solvent,
- neutral oil

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References(33)

References

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