Solvothermal synthesis of TiO<sub>2</sub>@MIL-101(Cr) for efficient photocatalytic fuel denitrification

LU Yi; LIANG Ruo-wen; YAN Gui-yang; LIANG Zhi-yu; HU Wei-neng; XIA Yu-zhou; HUANG Ren-kun

doi:10.1016/S1872-5813(21)60170-6

Volume 50 Issue 4

Apr. 2022

Turn off MathJax

Article Contents

Article Navigation > Journal of Fuel Chemistry and Technology > 2022 > 50(4): 456-463

LU Yi, LIANG Ruo-wen, YAN Gui-yang, LIANG Zhi-yu, HU Wei-neng, XIA Yu-zhou, HUANG Ren-kun. Solvothermal synthesis of TiO2@MIL-101(Cr) for efficient photocatalytic fuel denitrification[J]. Journal of Fuel Chemistry and Technology, 2022, 50(4): 456-463. doi: 10.1016/S1872-5813(21)60170-6

Citation:

LU Yi, LIANG Ruo-wen, YAN Gui-yang, LIANG Zhi-yu, HU Wei-neng, XIA Yu-zhou, HUANG Ren-kun. Solvothermal synthesis of TiO₂@MIL-101(Cr) for efficient photocatalytic fuel denitrification[J]. Journal of Fuel Chemistry and Technology, 2022, 50(4): 456-463. doi: 10.1016/S1872-5813(21)60170-6

Citation:

PDF( 1299 KB)

Solvothermal synthesis of TiO₂@MIL-101(Cr) for efficient photocatalytic fuel denitrification

doi: 10.1016/S1872-5813(21)60170-6

LU Yi^{1, 2
,},
LIANG Ruo-wen^{1, 2, 3},
YAN Gui-yang¹,
LIANG Zhi-yu^{1, 3},
HU Wei-neng²,
XIA Yu-zhou¹,
HUANG Ren-kun^{1, 2, 3
,
,}

1.
Province University Key Laboratory of Green Energy and Environment Catalysis, Ningde Normal University, Ningde 352100, China
2.
State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou 350002, China
3.
Fujian Provincial Key Laboratory of Featured Materials in Biochemical Industry, Ningde Normal University, Ningde 352100, China

Funds: The project was supported by Program for Innovative Research Team in Science and Technology in Fujian Province University, Natural Science Foundation of Fujian Province (2019J05121), Research Project of Ningde Normal University (2019T03) and the Training Program Foundation for Distinguished Young Scholar by Fujian Province.

More Information

Author Bio:
957832459@qq.com
Corresponding author: Tel: +86-593-2965018; E-mail: t1432@ndnu.edu.cn
Received Date: 2021-08-04
Rev Recd Date: 2021-09-23

Available Online: 2021-10-25

Publish Date: 2022-04-26

Abstract

Abstract

Solvothermal synthesis technique is an effective method to create composite materials. In this paper, a series of TiO₂@MIL-101(Cr) were prepared by the solvothermal method for photocatalytic denitrification of pyridine in fuel under visible light irradiation. The products were characterized by XRD, FT-IR, SEM, TEM, BET, DRS and ESR. The result shows that 20%TiO₂@MIL-101(Cr) has high catalytic activity, the pyridine removal efficiency reaches values as high as 70% after irradiation for 240 min. Finally, we obtained the possible mechanism of photocatalytic denitrification according to the HPLC-MS spectrometry results analysis.
- photocatalytic,
- fuel,
- denitrification,
- MIL-101(Cr),
- TiO₂

FullText(HTML)

References(25)

References

[1]	YIN C. International law regulation of offshore oil and gas exploitation[J]. Environ Impact Assess Rev,2021,88:106551.
[2]	PRADO G H C, RAO Y, KLERK A. Nitrogen removal from oil: A review[J]. Energy Fuels,2016,31(1):14−36.
[3]	BHADRA B N, BAEK Y S, CHOI C H, JHUNG S H. How neutral nitrogen-containing compounds are oxidized in oxidative-denitrogenation of liquid fuel with TiO₂@carbon[J]. Phys Chem Chem Phys,2021,23(14):8368−8374. doi: 10.1039/D1CP00633A
[4]	DEESE R D, MORRIS R E, METZ A E, MYERS K M, JOHNSON K, LOEGEL T N. Characterization of organic nitrogen compounds and their impact on the stability of marginally stable diesel fuels[J]. Energy Fuels,2019,33(7):6659−6669. doi: 10.1021/acs.energyfuels.9b00932
[5]	PAUCAR N E, KIGGINS P, BLAD B, DE JESUS K, AFRIN F, PASHIKANTI S, SHARMA K. Ionic liquids for the removal of sulfur and nitrogen compounds in fuels: A review[J]. Environ Chem Lett,2021,19(2):1205−1228. doi: 10.1007/s10311-020-01135-1
[6]	JURY M R. Meteorology of air pollution in Los Angeles[J]. Atmospheric Pollut Res,2020,11(7):1226−1237. doi: 10.1016/j.apr.2020.04.016
[7]	LIANG R, HUANG R, WANG X, YING S, YAN G, WU L. Functionalized MIL-68(In) for the photocatalytic treatment of Cr(VI)-containing simulation wastewater: Electronic effects of ligand substitution[J]. Appl Surf Sci,2019,464:396−403. doi: 10.1016/j.apsusc.2018.09.100
[8]	ALVARO M, CARBONELL E, FERRER B, LLABRES I XAMENA F X, GARCIA H. Semiconductor behavior of a metal-organic framework (MOF)[J]. Chem Eur J,2007,13(18):5106−51112. doi: 10.1002/chem.200601003
[9]	DHAKSHINAMOORTHY A, LI Z, GARCIA H. Catalysis and photocatalysis by metal organic frameworks[J]. Chem Soc Rev,2018,47(22):8134−8172. doi: 10.1039/C8CS00256H
[10]	GAO P, LIU R, HUANG H, JIA X, PAN H. MOF-templated controllable synthesis of α-Fe₂O₃ porous nanorods and their gas sensing properties[J]. RSC Adv,2016,6(97):94699−94705. doi: 10.1039/C6RA21567J
[11]	LI Q, WU J, HUANG L, GAO J, ZHOU H, SHI Y, PAN Q, ZHANG G, DU Y, LIANG W. Sulfur dioxide gas-sensitive materials based on zeolitic imidazolate framework-derived carbon nanotubes[J]. J Mater Chem A,2018,6(25):12115−12124. doi: 10.1039/C8TA02036A
[12]	CUI Y F, JIANG W, LIANG S, ZHU L F, YAO Y W. MOF-derived synthesis of mesoporous In/Ga oxides and their ultra-sensitive ethanol-sensing properties[J]. J Mater Chem A,2018,6(30):14930−14938. doi: 10.1039/C8TA00269J
[13]	FANG Y, MA Y, ZHENG M, YANG P, ASIRI A M, WANG X. Metal-organic frameworks for solar energy conversion by photoredox catalysis[J]. Coord Chem Rev,2018,373:83−115. doi: 10.1016/j.ccr.2017.09.013
[14]	YUAN S, FENG L, WANG K, PANG J, BOSCH M, LOLLAR C, SUN Y, QIN J, YANG X, ZHANG P, WANG Q, ZOU L, ZHANG Y, ZHANG L, FANG Y, LI J, ZHOU H C. Stable metal-organic frameworks: Design, synthesis, and applications[J]. Adv Mater,2018,30(37):e1704303. doi: 10.1002/adma.201704303
[15]	XUE D-X, WANG Q, BAI J. Amide-functionalized metal-organic frameworks: Syntheses, structures and improved gas storage and separation properties[J]. Coord Chem Rev,2019,378:2−16. doi: 10.1016/j.ccr.2017.10.026
[16]	YING M, TANG R, YANG W, LIANG W, YANG G, PAN H, LIAO X, HUANG J. Tailoring electronegativity of bimetallic Ni/Fe metal-organic framework nanosheets for electrocatalytic water oxidation[J]. ACS Appl Nano Mater,2021,4(2):1967−1975. doi: 10.1021/acsanm.0c03310
[17]	LIANG R, HUANG R, YING S, WANG X, YAN G, WU L. Facile in situ growth of highly dispersed palladium on phosphotungstic-acid-encapsulated MIL-100(Fe) for the degradation of pharmaceuticals and personal care products under visible light[J]. J Nano Res,2017,11(2):1109−1123.
[18]	WANG C-C, DU X-D, LI J, GUO X-X, WANG P, ZHANG J. Photocatalytic Cr(VI) reduction in metal-organic frameworks: A mini-review[J]. App Catal B: Environ,2016,193:198−216. doi: 10.1016/j.apcatb.2016.04.030
[19]	KHAN N A, JHUNG S H. Phytic acid-encapsulated MIL-101(Cr): Remarkable adsorbent for the removal of both neutral indole and basic quinoline from model liquid fuel[J]. Chem Eng J,2019,375.
[20]	GUO Q, ZHOU C, MA Z, YANG X. Fundamentals of TiO₂ photocatalysis: Concepts, mechanisms, and challenges[J]. Adv Mater,2019,31(50):1901997. doi: 10.1002/adma.201901997
[21]	FUJIMOTO T M, PONCZEK M, ROCHETTO U L, LANDERS R, TOMAZ E. Photocatalytic oxidation of selected gas-phase VOCs using UV light, TiO₂, and TiO₂/Pd[J]. Environ Sci Pollut Res Int,2017,24(7):6390−6396. doi: 10.1007/s11356-016-6494-7
[22]	LIN J Y, LEE J, WEN D O, KWON E, LIN K. Hierarchical zif-decorated nanoflower-covered 3-dimensional foam for enhanced catalytic reduction of nitrogen-containing contaminants[J]. J Colloid Interface Sci 2021, 602: 95-104.
[23]	HU W, YAN G, LIANG R, JIANG M, HUANG R, XIA Y, CHEN L, LU Y. Construction of a novel step-scheme CdS/Pt/Bi₂MoO₆ photocatalyst for efficient photocatalytic fuel denitrification[J]. RSC Adv,2021,11(38):23288−23300. doi: 10.1039/D1RA04417F
[24]	LIANG R, LIANG I, CHEN F, XIE P, WV Y, WANG X, YAN G, WV L. Sodium dodecyl sulfate-decorated MOF-derived porous Fe₂O₃ nanoparticles: High performance, recyclable photocatalysts for fuel denitrification[J]. Chin J Catal,2020,41(1):188−199.
[25]	HUANG R, LIANG R, FAN H, YING S, WU L, WANG X, YAN G. Enhanced Photocatalytic fuel denitrification over TiO₂/alpha-Fe₂O₃ nanocomposites under visible light irradiation[J]. Sci Rep,2017,7(1):7858. doi: 10.1038/s41598-017-08439-3