One-pot construction of ionic liquid-functionalized MOF material as the catalyst for CO<sub>2</sub> cycloaddition under atmospheric pressure

LI Dong-na; QIU Ming-yue; ZHANG Qi-ri; YI Qun; FAN Hai-ming; LI Xiang-yuan; LI Jian-chuan; SHI Li-juan; ZHANG Ding

doi:10.1016/S1872-5813(21)60195-0

Volume 50 Issue 7

Aug. 2022

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Article Navigation > Journal of Fuel Chemistry and Technology > 2022 > 50(7): 824-831

LI Dong-na, QIU Ming-yue, ZHANG Qi-ri, YI Qun, FAN Hai-ming, LI Xiang-yuan, LI Jian-chuan, SHI Li-juan, ZHANG Ding. One-pot construction of ionic liquid-functionalized MOF material as the catalyst for CO2 cycloaddition under atmospheric pressure[J]. Journal of Fuel Chemistry and Technology, 2022, 50(7): 824-831. doi: 10.1016/S1872-5813(21)60195-0

Citation:

LI Dong-na, QIU Ming-yue, ZHANG Qi-ri, YI Qun, FAN Hai-ming, LI Xiang-yuan, LI Jian-chuan, SHI Li-juan, ZHANG Ding. One-pot construction of ionic liquid-functionalized MOF material as the catalyst for CO₂ cycloaddition under atmospheric pressure[J]. Journal of Fuel Chemistry and Technology, 2022, 50(7): 824-831. doi: 10.1016/S1872-5813(21)60195-0

Citation:

LI Dong-na, QIU Ming-yue, ZHANG Qi-ri, YI Qun, FAN Hai-ming, LI Xiang-yuan, LI Jian-chuan, SHI Li-juan, ZHANG Ding. One-pot construction of ionic liquid-functionalized MOF material as the catalyst for CO₂ cycloaddition under atmospheric pressure[J]. Journal of Fuel Chemistry and Technology, 2022, 50(7): 824-831. doi: 10.1016/S1872-5813(21)60195-0

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One-pot construction of ionic liquid-functionalized MOF material as the catalyst for CO₂ cycloaddition under atmospheric pressure

doi: 10.1016/S1872-5813(21)60195-0

LI Dong-na^{1, 2
,},
QIU Ming-yue^{1, 2
,},
ZHANG Qi-ri²,
YI Qun¹,
FAN Hai-ming³,
LI Xiang-yuan⁴,
LI Jian-chuan⁴,
SHI Li-juan^{1, 2, 4
,
,},
ZHANG Ding²

1.
School of Chemical Engineering and Pharmacy, Wuhan Institute of Technology, Wuhan 430205, China
2.
State Key Laboratory of Clean and Efficient Utilization of Coal-based Energy, Taiyuan university of technology, Taiyuan 030021, China
3.
Shandong Key Laboratory of Oilfield Chemistry, China University of Petroleum (East China), Qingdao 266580, China
4.
Technical Center, Shanxi Tianji Coal Chemical Co. LTD, Lucheng 047507, China

Funds: The project was supported by the National Natural Science Foundation of China (U1810125, 51776133, U1710110), the Joint Fund of the Yulin University and the Dalian National Laboratory for Clean Energy (YLU-DNL Fund 2021021), the Natural Science Foundation of Shanxi Province (201901D111082) and the Opening Fund of Shandong Key Laboratory of Oilfield Chemistry and Fundamental Research Funds for the Central Universities (19CX05006A)

Received Date: 2021-12-17
Accepted Date: 2022-01-24
Rev Recd Date: 2022-01-20

Available Online: 2022-02-12

Publish Date: 2022-08-01

Abstract

Abstract

Carboxylic ionic liquid 1-propionic acid-3-methylimidazolium chloride (CFIL) was immobilized in a metal-organic framework (MOF) material NH₂-MIL-101 in one-pot by the in-situ assembly method; as a heterogeneous catalyst with multiple active sites, the catalytic performance of NH₂-FMOF-CFIL in the cycloaddition of CO₂ with epichlorohydrin (ECH) to synthesize chloropropylene carbonate (CPC) was investigated. The immobilized of CFIL in NH₂-MIL-101 was proved by Fourier transform infrared spectroscopy (FT-IR) and elemental analysis, while the powder X-ray diffraction (PXRD), scanning electron microscopy (SEM) and N₂ adsorption-desorption measurements demonstrated that CFIL neither damages the crystal structure nor blocks the pore of NH₂-MIL-101, but induce the formation of mesopores. The catalytic reaction results reveal that there is a catalytic synergy between imidazole N and Cl⁻ on CFIL and Cr³⁺ and amino group on MOF, which endow the NH₂-FMOF-CFIL composite excellent catalytic performance in the cycloaddition of CO₂ with ECH; under mild conditions, viz., 0.1 MPa CO₂, 25–70 ℃ and without using any solvent and cocatalyst, the CPC yield reaches 99% after reaction for 24 h. Moreover, the crystal structure and high activity of the NH₂-FMOF-CFIL catalyst are well preserved even after reuse for 5 cycles.
- ionic liquids,
- heterogeneous catalyst,
- CO₂,
- chloropropylene carbonate,
- mild conditions

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References(30)

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