Volume 50 Issue 8
Aug.  2022
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Article Navigation >  Journal of Fuel Chemistry and Technology  > 2022  >  50(8): 1004-1013
SUN Fu-lin, ZHAO Lu, WANG Qian-hao, FANG Ke-gong, WANG Ying-jun. Hydrothermal reduction synthesis of K-Ni-Mo-based catalyst and its catalytic performance for higher alcohol synthesis from syngas[J]. Journal of Fuel Chemistry and Technology, 2022, 50(8): 1004-1013. doi: 10.1016/S1872-5813(22)60015-X
Citation: SUN Fu-lin, ZHAO Lu, WANG Qian-hao, FANG Ke-gong, WANG Ying-jun. Hydrothermal reduction synthesis of K-Ni-Mo-based catalyst and its catalytic performance for higher alcohol synthesis from syngas[J]. Journal of Fuel Chemistry and Technology, 2022, 50(8): 1004-1013. doi: 10.1016/S1872-5813(22)60015-X
shu

Hydrothermal reduction synthesis of K-Ni-Mo-based catalyst and its catalytic performance for higher alcohol synthesis from syngas

doi: 10.1016/S1872-5813(22)60015-X
  • 1.

    College of Chemistry and Chemical Engineering, Northeast Petroleum University, Daqing 163318, China

  • 2.

    State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China

Funds:  The project was supported by the National Natural Science Foundation of China (21978313, 21603255), the Autonomous Research Project of SKLCC (2020BWZ002), the Innovation Foundation of ICC-CAS (SCJC-DT-2022-05), the Youth Innovation Promotion Association of CAS (2020181) and Natural Science Foundation of Shanxi Province, China (201901D111457).
  • Received Date: 2022-01-17
  • Rev Recd Date: 2022-03-06
    • Available Online: 2022-04-22
  • Publish Date: 2022-08-26
    Abstract
  • A series of non-sulfurized K-Ni-Mo-based catalysts with close contact between Ni and K2MoO4 were prepared by hydrothermal reduction for higher alcohol synthesis from syngas. The as-prepared catalysts were characterized by XRD, N2 adsorption-desorption, H2-TPR, HR-TEM, SEM-EDS, XPS, H2-TPD, CO-TPD and CO2-TPD techniques. The results indicate that the introduction of K facilitates the formation of the K2MoO4 phase while brings about a decrease of NiMoO4. It can significantly assist the non-dissociative activation of CO for insertion and subsequently alcohol formation. Moreover, the addition of K increases the surface basicity, which leads to more amount of basic hydroxy groups on the catalytic surface. The catalytic basicity ameliorates the production of alcohols. In particular, the K0.4-Ni-Mo catalyst shows the best catalytic behavior with CO conversion of 19.6%, total alcohol selectivity of 57.8% and C2+ alcohol selectivity in the total alcohols of 66.5% at GHSV of 5000 h−1, 240 °C, and 5 MPa.
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