Preparation and structural analysis of humic acid by co-thermal oxidation of wheat straw and Heilongjiang lignite

LI Yan-ling; CHEN Xi; ZHANG Cui-qing; LI Xiao-feng; LIU Peng; CHEN Wen-xuan; REN Su-xia; LEI Ting-zhou

doi:10.1016/S1872-5813(22)60033-1

Volume 51 Issue 2

Jan. 2023

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Article Navigation > Journal of Fuel Chemistry and Technology > 2023 > 51(2): 145-154

LI Yan-ling, CHEN Xi, ZHANG Cui-qing, LI Xiao-feng, LIU Peng, CHEN Wen-xuan, REN Su-xia, LEI Ting-zhou. Preparation and structural analysis of humic acid by co-thermal oxidation of wheat straw and Heilongjiang lignite[J]. Journal of Fuel Chemistry and Technology, 2023, 51(2): 145-154. doi: 10.1016/S1872-5813(22)60033-1

Citation:

LI Yan-ling, CHEN Xi, ZHANG Cui-qing, LI Xiao-feng, LIU Peng, CHEN Wen-xuan, REN Su-xia, LEI Ting-zhou. Preparation and structural analysis of humic acid by co-thermal oxidation of wheat straw and Heilongjiang lignite[J]. Journal of Fuel Chemistry and Technology, 2023, 51(2): 145-154. doi: 10.1016/S1872-5813(22)60033-1

Citation:

LI Yan-ling, CHEN Xi, ZHANG Cui-qing, LI Xiao-feng, LIU Peng, CHEN Wen-xuan, REN Su-xia, LEI Ting-zhou. Preparation and structural analysis of humic acid by co-thermal oxidation of wheat straw and Heilongjiang lignite[J]. Journal of Fuel Chemistry and Technology, 2023, 51(2): 145-154. doi: 10.1016/S1872-5813(22)60033-1

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Preparation and structural analysis of humic acid by co-thermal oxidation of wheat straw and Heilongjiang lignite

doi: 10.1016/S1872-5813(22)60033-1

1.
Institute of Urban and Rural Mines, Changzhou University, Changzhou 213164, China
2.
National Institute of Clean-and-low-carbon Energy, Beijing 102211, China

Funds: The project was supported by the National Key Research and Development Program of China (2021YFC2101604), Changzhou Key Research and Development Project (Agricultural Science and Technology support) (CE20212043), National Natural Science Foundation of China (51906021), and Technology Innovation Project of CHN ENERGY (GJNY-21-95).

Received Date: 2022-03-20
Accepted Date: 2022-05-09
Rev Recd Date: 2022-05-06

Available Online: 2022-06-09

Publish Date: 2023-01-18

Abstract

Abstract

Combining with the characteristics of high yield of mineral humic acid (HA) and high activity of biochemical HA, co-thermal oxidation of low rank coal and biomass to produce complex HA (MIXHA) was newly proposed. The mixture (MIX) of Heilongjiang lignite (HL) and wheat straw (WS) was co-thermally oxidized in 10% HNO₃ solution to prepare MIXHA. This work focused on comparison of the macro morphology and microstructure of MIXHA between HLHA and WSHA by SEM, FT-IR and ¹³C NMR analyses, and explored the synergistic effect between HL and WS during the co-thermal oxidation process. The results show that MIXHA content is higher than the theoretical value. Decomposition of HNO₃ molecular produces active oxygen atoms and nitrogen oxides to attack the molecular structure of WS and HL. Due to hydrogen bond rearrangement, glycosidic bond rupture, and crosslinking, plenty of alkyl radicals generated in WS are combined with the condensation aromatic ring in HL. Thus, the protonated aromatic carbon is changed into aliphatic substituted aromatic carbon. The obtained MIXHA is rich in oxygen-containing functional groups, and has high activity. Obvious characteristic peaks are observed in FTIR spectra of MIXHA. This work would provide a new idea for classification and resource utilization of low-rank coal and agricultural and forestry wastes.
- humic acid,
- biomass,
- lignite,
- co-thermal oxidation,
- ¹³C NMR

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References(34)

References

[1]	王苗, 李艳红, 张远琴, 訾昌毓, 梁光兵, 张殿凯, 赵文波. 不同溶剂提取宝清褐煤腐植酸的工艺优化及其特性研究[J]. 煤炭转化,2021,44(2):51−61. WANG Miao, LI Yan-hong, ZHANG Yuan-qin, ZI Chang-yu, LIANG Guang-bing, ZHANG Dian-kai, ZHAO Wen-bo. Study on process optimization and characteristics of humic acid extraction from Baoqing lignite with different solvents[J]. Coal Convers,2021,44(2):51−61.
[2]	张彩凤, 李丽荣, 张树青, 王业娟, 王阳, 薛芬. 腐植酸对砷的吸附作用研究[J]. 燃料化学学报,2010,38(6):733−738. doi: 10.3969/j.issn.0253-2409.2010.06.018 ZHANG Cai-feng, LI Li-rong, ZHANG Shu-qing, WANG Ye-juan, WANG Yang, XUE Fen. Adsorption of arsenic by humic acid[J]. J Fuel Chem Technol,2010,38(6):733−738. doi: 10.3969/j.issn.0253-2409.2010.06.018
[3]	于晓东, 郭新送, 洪丕征, 陈士更, 朱福军, 孙昆, 丁方军. 不同配方腐植酸型土壤调理剂对滨海盐碱地土壤性质及小麦产量的影响[J]. 腐植酸,2019,(5):52−57. YU Xiao-dong, GUO Xin-song, HONG Pi-zheng, CHEN Shi-geng, ZHU Fu-jun, SUN Kun, DING Fang-jun. Effects of different humic acid soil conditioners on wheat yield and main properties of coastal alkali-saline soil[J]. Humic Acid,2019,(5):52−57.
[4]	SALATI S, PAPA G, ADANI F. Perspective on the use of humic acids from biomass as natural surfactants for industrial applications[J]. Biotechnol Adv,2011,29(6):913−922. doi: 10.1016/j.biotechadv.2011.07.012
[5]	ARAFAT R Y, KHAN S H, SAIMA. Evaluation of humic acid as an aflatoxin binder in broiler chickens[J]. Ann Anim Sci,2017,17(1):241−255. doi: 10.1515/aoas-2016-0050
[6]	杨静, 何静, 丁亚芳, 庄文婷, 向诚, 秦谊, 李宝才. 云南昭通年青褐煤黄腐酸钠对血管新生作用的影响[J]. 天然产物研究与开发,2015,27(4):691−694+714. YANG Jing, HE Jing, DING Ya-fang, ZHUANG Wen-ting, XIANG Cheng, QIN Yi, LI Bao-cai. Angiogenesis effect of sodium fulvate extracted from young lignite of Zhaotong region in Yunnan province[J]. Nat Prod Res Dev,2015,27(4):691−694+714.
[7]	QIN Y, ZHANG M, DAI W F, XIANG C, LI B C, JIA Q M. Antidiarrhoeal mechanism study of fulvic acids based on molecular weight fractionation[J]. Fitoterapia,2019,137(3):104270.
[8]	贺文强, 李斌, 宋剑峰. 矿物源腐植酸的活化[J]. 磷肥与复肥,2017,32(1):19−21. doi: 10.3969/j.issn.1007-6220.2017.01.008 HE Wen-qiang, LI Bin, SONG Jian-feng. Activation of humic acid from mineral[J]. Phos Comp Fert,2017,32(1):19−21. doi: 10.3969/j.issn.1007-6220.2017.01.008
[9]	YUAN Y, LIU J P, CHEN Z, LI H C. Extraction study of nitro humic acid from lignite by dry and wet process[J]. Appl Mech Mater,2013,483:119−123. doi: 10.4028/www.scientific.net/AMM.483.119
[10]	MAE K, SHINDO H, MIURA K. A new two-step oxidative degradation method for producing valuable chemicals from low rank coals under mild conditions[J]. Energy fuels,2001,15(3):611−617. doi: 10.1021/ef000177e
[11]	张水花, 李宝才, 张惠芬, 林雪飞, 刘建珍. H₂O₂氧解褐煤产腐植酸的试验研究[J]. 安徽农业科学,2012,40(15):8677−8679. doi: 10.3969/j.issn.0517-6611.2012.15.104 ZHANG Shui-hua, LI Bao-cai, ZHANG Hui-fen, LIN Xue-fei, LIU Jian-zhen. Experimental study on the production of humic acids from brown coal using hydrogen peroxide[J]. J Anhui Agric Sci,2012,40(15):8677−8679. doi: 10.3969/j.issn.0517-6611.2012.15.104
[12]	ZHANG X Y, ZHEN W J, SUN M G. Green preparation process of fulvic acid from qitai weathered coal based on hydrothermal method[J]. Mod Chem Ind,2017,37(2):116−119.
[13]	李建, 刘猛, 段钰锋, 许超. 污泥掺混褐煤水热制固体燃料的理化特性[J]. 浙江大学学报,2016,50(2):327−332+340. LI Jian, LIU Meng, DUAN Yu-feng, XU Chao. Physicochemical analysis on hydrothermal upgrading of sewage sludge with lignite for solid fuel[J]. J Zhejiang Univ,2016,50(2):327−332+340.
[14]	钟世霞, 徐玉新, 骆洪义, 赵越, 郭祥, 李家家. 超声波活化风化煤腐植酸的影响研究[J]. 山东农业大学学报(自然科学版),2014,45(1):6−9+16. ZHONG Shi-xia, XU Yu-xin, LUO Hong-yi, ZHAO Yue, GUO Xiang, LI Jia-jia. Impact study of ultrasonic activation on humic acid in danty[J]. J Shandong Agric Univ (Nat Sci),2014,45(1):6−9+16.
[15]	张敬东, 毛东萍, 刘加龙. 风化煤及轻变质煤的电化学氯化作用[J]. 腐植酸,1987,(4):31−34. ZHANG Jing-dong, MAO Dong-ping, LIU Jia-long. Electrochemical chlorination of weathered coal and light metamorphic coal[J]. Humic Acid,1987,(4):31−34.
[16]	黄良仙, 韩星星, 马展, 陈桦, 王佳惠, 牛育华. 甘肃某地褐煤中腐植酸的提取工艺研究[J]. 陕西科技大学学报,2019,37(6):105−110. doi: 10.3969/j.issn.1000-5811.2019.06.017 HUANG Liang-xian, HAN Xing-xing, MA Zhan, CHEN Hua, WANG Jia-hui, NIU Yu-hua. Study on the extraction technology of humic acid from the lignite in a place of Gansu province[J]. J Shaanxi Univ Sci,2019,37(6):105−110. doi: 10.3969/j.issn.1000-5811.2019.06.017
[17]	袁蕊, 王学江, 李峰. 风化煤氧化改性对其提取物腐植酸钾抗硬水性能影响[J]. 磷肥与复肥,2018,33(11):4−6. doi: 10.3969/j.issn.1007-6220.2018.11.003 YUAN Rui, WANG Xue-jiang, LI Feng. Effect of oxidation modification of weathered coal on resistance to hard water of its extract potassium humate[J]. Phos Comp Fert,2018,33(11):4−6. doi: 10.3969/j.issn.1007-6220.2018.11.003
[18]	李斌斌, 吴诗勇, 吴幼青, 黄胜, 高晋生. 稻秸秆硝解制备黄腐酸和腐植酸研究[J]. 华东理工大学学报(自然科学版),2021,47(2):189−194. LI Bin-bin, WU Shi-yong, WU You-qing, HUANG Sheng, GAO Jin-sheng. Preparation of fulvic acid and humic acid by nitric acid oxidized rice straw[J]. J East Chin Univ Sci Technol (Nat Sci),2021,47(2):189−194.
[19]	YANG F, ZHANG S, CHENG K, ANTONIETTI M. A hydrothermal process to turn waste biomass into artificial fulvic and humic acids for soil remediation[J]. Sci Total Environ,2019,686:1140−1151. doi: 10.1016/j.scitotenv.2019.06.045
[20]	吕品, 于志民, 马献发. 低酸催化水解稻草制备腐植酸的工艺研究[J]. 腐植酸,2011,(2):16−23. doi: 10.3969/j.issn.1671-9212.2011.02.005 LV Pin, YU Zhi-min, MA Xian-fa. Technical study on preparation of humic acid through hydrolyzing straw under catalysis of low-concentration of acid[J]. Humic Acid,2011,(2):16−23. doi: 10.3969/j.issn.1671-9212.2011.02.005
[21]	李善祥. 腐植酸产品分析及标准[M]. 北京: 化学工业出版社, 2007. LI Shan-xiang. Humic Acid Product Analysis and Standards[M]. Beijing: Chemical Industry Press, 2007.
[22]	杨天华, 孙海朋, 孙洋, 开兴平, 李杰, 李润东. 脱灰预处理对水稻秸秆物化性/水蒸气气化反应特性的影响[J]. 燃料化学学报,2015,43(5):598−606. YANG Tian-hua, SUN Hai-peng, SUN Yang, KAI Xing-ping, LI Jie, LI Run-dong. Effects of deashing pretreatment on physicochemical properties and steam gasification characteristics of Rice straw[J]. J Fuel Chem Technol,2015,43(5):598−606.
[23]	张文达, 王鹏翔, 孙绍增, 赵义军, 赵虹翔, 严泰森, 吴江全. 酸洗脱灰对准东次烟煤结构和反应活性的影响[J]. 化工学报,2017,68(8):3291−3300. ZHANG Wen-da, WANG Peng-xiang, SUN Shao-zeng, ZHAO Yi-jun, ZHAO Hong-xiang, YAN Tai-sen, WU Jiang-quan. Effect of acid pickling deashing on structure and Reactivity of quasi-eastern sub-bituminous coal[J]. J Chem Ind Eng,2017,68(8):3291−3300.
[24]	阳虹, 李永生, 范云场, 张磊. 风化煤中腐植酸的提取及其光谱学研究[J]. 煤炭转化,2013,36(2):87−91. doi: 10.3969/j.issn.1004-4248.2013.02.022 YANG Hong, LI Yong-sheng, FAN Yun-chang, ZHANG Lei. Humic acid extraction from weathered coal and its spectroscopic research[J]. Coal Convers,2013,36(2):87−91. doi: 10.3969/j.issn.1004-4248.2013.02.022
[25]	LI C Z, SATHE C, KERSHAW J R, PANG Y. Fates and roles of alkali and alkaline earth metals during the pyrolysis of a Victorian brown coal[J]. Fuel,2000,79(3/4):427−438. doi: 10.1016/S0016-2361(99)00178-7
[26]	任麒帆, 刘海飞, 李洋, 许美玲, 张会平, 冯梦喜. 浅谈矿物源腐植酸的理化性质、活化提取及应用展望[J]. 腐植酸,2021,(4):7−12. REN Qin-fan, LIU Hai-fei, LI Yang, XU Mei-ling, ZHANG Hui-ping, FENG Meng-xi. Talking about the physical and chemical properties, activation extraction and application prospects of mineral humic acid[J]. Humic Acid,2021,(4):7−12.
[27]	马连刚, 肖保华. 土壤腐殖质提取和分组综述[J]. 矿物岩石地球化学通报,2011,30(4):465−471. MA Lian-gang, XIAO Bao-hua. Review on extraction and grouping of soil humus[J]. Bull Min, Petr Geochem,2011,30(4):465−471.
[28]	路亚楠, 王晓霞, 马力通. 液体酸对碱溶酸析法提取泥炭腐植酸光谱学变化特征的影响[J]. 光谱学与光谱分析,2020,40(2):574−578. LU Ya-nan, WANG Xiao-xia, MA Li-tong. Effects of liquid acid on the spectral characteristics during peat humic acid extracted by alkali-extraction acid-precipitation method[J]. Spectrosc Spect Anal,2020,40(2):574−578.
[29]	NASIR S, SARFARAZ T B, VERHEYEN T V, CHAFFEE A L. Structural elucidation of humic acids extracted from Pakistani lignite using spectroscopic and thermal degradative techniques[J]. Fuel Process Technol,2011,92(5):983−991. doi: 10.1016/j.fuproc.2010.12.020
[30]	ZHANG Z Q, GAO Q, XIE Z L, YANG J M, LIU J H. Adsorption of nitrification inhibitor nitrapyrin by humic acid and fulvic acid in black soil: characteristics and mechanism[J]. RSC Adv,2020,11(1):114−123.
[31]	EVANGELOU V P, MARSI M, CHAPPELL M A. Potentiometric-spectroscopic evaluation of metal-ion complexes by humic fractions extracted from corn tissue[J]. Spectrochim Acta, Part A,2002,58(10):2159−2175. doi: 10.1016/S1386-1425(01)00690-4
[32]	FOOKEN U, LIEBEZEIT G. An IR study of humic acids isolated from sediments and soils[J]. Mar Biodivers,2003,32(1):183−189.
[33]	LIN Y, MUOROE P, JOSEPH S, HENDERSON R, ZIOLKOWSKI A. Water extractable organic carbon in untreated and chemical treated biochars[J]. Chemosphere,2012,87(2):151−157. doi: 10.1016/j.chemosphere.2011.12.007
[34]	YAN L J, BAI Y H, ZHAO R F, LI F, XIE K. Correlation between coal structure and release of the two organic compounds during pyrolysis[J]. Fuel,2015,145:12−17. doi: 10.1016/j.fuel.2014.12.056