Research progress on mordenite catalyzed carbonylation of dimethyl ether

ZHAO Sheng-ying; GENG Hai-lun; XU Bing; WU Xue-mei; TAN Ming-hui; YANG Guo-hui; TAN Yi-sheng

doi:10.19906/j.cnki.JFCT.2021083

Volume 50 Issue 2

Feb. 2022

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Article Navigation > Journal of Fuel Chemistry and Technology > 2022 > 50(2): 166-179

ZHAO Sheng-ying, GENG Hai-lun, XU Bing, WU Xue-mei, TAN Ming-hui, YANG Guo-hui, TAN Yi-sheng. Research progress on mordenite catalyzed carbonylation of dimethyl ether[J]. Journal of Fuel Chemistry and Technology, 2022, 50(2): 166-179. doi: 10.19906/j.cnki.JFCT.2021083

Citation:

ZHAO Sheng-ying, GENG Hai-lun, XU Bing, WU Xue-mei, TAN Ming-hui, YANG Guo-hui, TAN Yi-sheng. Research progress on mordenite catalyzed carbonylation of dimethyl ether[J]. Journal of Fuel Chemistry and Technology, 2022, 50(2): 166-179. doi: 10.19906/j.cnki.JFCT.2021083

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Research progress on mordenite catalyzed carbonylation of dimethyl ether

doi: 10.19906/j.cnki.JFCT.2021083

ZHAO Sheng-ying^{1, 2
,},
GENG Hai-lun^{1, 2},
XU Bing^{1, 2},
WU Xue-mei^{1, 2},
TAN Ming-hui¹,
YANG Guo-hui^{1
,
,},
TAN Yi-sheng¹

1.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
2.
University of Chinese Academy of Sciences, Beijing 10049, China

Funds: The project was supported by the National Natural Science Foundation of China (21978312, 21908235), the Key Research Program of Frontier Sciences, CAS (QYZDB-SSW-JSC043), International Partnership Program of Chinese Academy of Sciences (122214KYSB20170007), Research Project Supported by Shanxi Scholarship Council of China and Fund Program for the Scientific Activities of Selected Returned Overseas Professionals in Shanxi Province

Received Date: 2021-07-28
Rev Recd Date: 2021-09-04

Available Online: 2021-10-08

Publish Date: 2022-02-12

Abstract

Abstract

The carbonylation reaction of dimethyl ether is an important carbon addition reaction with directed insertion of carbon monoxide into dimethyl ether molecule, which is of great significance in industrial production. In recent years, it has been found that inexpensive mordenite has higher activity and very excellent carbonylation product selectivity for catalyzing the carbonylation reaction of dimethyl ether, hence widely studied. This review surveys researches on mordenite catalyzed carbonylation of dimethyl ether, introduces the mechanism of carbonylation reaction, and summarizes the various methods of controlling the acidic sites inside mordenite and their effects on the carbonylation reaction.
- dimethyl ether,
- methyl acetate,
- mordenite,
- acidic sites,
- carbonylation

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References(95)

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