Effect of manganese modification on the low-temperature formaldehyde oxidation performance of ZIF-67 derived Co<sub>3</sub>O<sub>4</sub>

XIANG Ning; HAN Xiao-jin; ZHENG Jian-feng; LI Qiao-yan; ZHAO Qing-song; HOU Ya-qin; HUANG Zhang-gen

doi:10.19906/j.cnki.JFCT.2022005

Volume 50 Issue 7

Aug. 2022

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Article Navigation > Journal of Fuel Chemistry and Technology > 2022 > 50(7): 859-867

XIANG Ning, HAN Xiao-jin, ZHENG Jian-feng, LI Qiao-yan, ZHAO Qing-song, HOU Ya-qin, HUANG Zhang-gen. Effect of manganese modification on the low-temperature formaldehyde oxidation performance of ZIF-67 derived Co3O4[J]. Journal of Fuel Chemistry and Technology, 2022, 50(7): 859-867. doi: 10.19906/j.cnki.JFCT.2022005

Citation:

XIANG Ning, HAN Xiao-jin, ZHENG Jian-feng, LI Qiao-yan, ZHAO Qing-song, HOU Ya-qin, HUANG Zhang-gen. Effect of manganese modification on the low-temperature formaldehyde oxidation performance of ZIF-67 derived Co₃O₄[J]. Journal of Fuel Chemistry and Technology, 2022, 50(7): 859-867. doi: 10.19906/j.cnki.JFCT.2022005

Citation:

XIANG Ning, HAN Xiao-jin, ZHENG Jian-feng, LI Qiao-yan, ZHAO Qing-song, HOU Ya-qin, HUANG Zhang-gen. Effect of manganese modification on the low-temperature formaldehyde oxidation performance of ZIF-67 derived Co₃O₄[J]. Journal of Fuel Chemistry and Technology, 2022, 50(7): 859-867. doi: 10.19906/j.cnki.JFCT.2022005

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Effect of manganese modification on the low-temperature formaldehyde oxidation performance of ZIF-67 derived Co₃O₄

doi: 10.19906/j.cnki.JFCT.2022005

1.
Department of Life Sciences, Changzhi University, Changzhi 046011, China
2.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
3.
College of Environmental Science and Engineering, Taiyuan University of Technology, Jinzhong 030600, China

Funds: The project was supported by the National Natural Science Foundation of China (21978314), the Scientific and Technological Innovation Programs of Higher Education Institutions of Shanxi Province (2021L527) and the Fund for Shanxi Province “1331 project”

Received Date: 2021-12-19
Accepted Date: 2022-01-19
Rev Recd Date: 2022-01-12

Available Online: 2022-01-28

Publish Date: 2022-08-01

Abstract

Abstract

In consideration of the inferior performance of ZIF-67 derived Co₃O₄ catalyst in the low-temperature formaldehyde oxidation, manganese was utilized to modify Co₃O₄ catalyst. The results showed that the Mn-Co₃O₄ catalyst exhibited the superior HCHO oxidation activity and achieved 90% HCHO conversion at a WHSV of 60000 mL/(g_cat·h) and inlet HCHO concentration of 98.16 mg/m³ at 118 ℃. XRD, Raman and BET results demonstrated that the Mn-Co₃O₄ catalyst possessed lower crystallinity, more defects and specific surface area, which was conducive to the adsorption of reactants and exposure of more active sites. XPS, H₂-TPR and O₂-TPD results indicated that the strong interaction between Mn and Co species prominently improved the low temperature reducibility and O₂ activation performance of Mn-Co₃O₄ catalyst, which endowed it with more abundant Co³⁺ and surface-adsorbed oxygen species. Therefore, the Mn-Co₃O₄ catalyst exhibited superior HCHO oxidation performance. Based on in-situ DRIFTS results, dioxymethylene and formate species were recognized as the main reaction intermediates of HCHO oxidation over the Mn-Co₃O₄ catalyst.
- formaldehyde,
- catalytic oxidation,
- ZIF-67,
- Mn-Co oxide

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References(39)

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