New research progress on bifunctional catalysts for one-step direct production of low carbon olefins from syngas

ZAO Hui-jie; YAO Jin-gang; LIU Jing; CHEN Guan-yi; YI Wei-ming; XIONG Jia-lin

doi:10.19906/j.cnki.JFCT.2022052

Volume 51 Issue 1

Jan. 2023

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ZAO Hui-jie, YAO Jin-gang, LIU Jing, CHEN Guan-yi, YI Wei-ming, XIONG Jia-lin. New research progress on bifunctional catalysts for one-step direct production of low carbon olefins from syngas[J]. Journal of Fuel Chemistry and Technology, 2023, 51(1): 19-33. doi: 10.19906/j.cnki.JFCT.2022052

Citation:

ZAO Hui-jie, YAO Jin-gang, LIU Jing, CHEN Guan-yi, YI Wei-ming, XIONG Jia-lin. New research progress on bifunctional catalysts for one-step direct production of low carbon olefins from syngas[J]. Journal of Fuel Chemistry and Technology, 2023, 51(1): 19-33. doi: 10.19906/j.cnki.JFCT.2022052

Citation:

ZAO Hui-jie, YAO Jin-gang, LIU Jing, CHEN Guan-yi, YI Wei-ming, XIONG Jia-lin. New research progress on bifunctional catalysts for one-step direct production of low carbon olefins from syngas[J]. Journal of Fuel Chemistry and Technology, 2023, 51(1): 19-33. doi: 10.19906/j.cnki.JFCT.2022052

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New research progress on bifunctional catalysts for one-step direct production of low carbon olefins from syngas

doi: 10.19906/j.cnki.JFCT.2022052

ZAO Hui-jie^{1, 2, 3
,},
YAO Jin-gang^{1, 2, 3
,
,},
LIU Jing^{1, 2, 3
,
,},
CHEN Guan-yi⁴,
YI Wei-ming^{1, 3},
XIONG Jia-lin⁵

1.
School of Agricultural Engineering and Food Science, Shandong University of Technology, Zibo 255000, China
2.
Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development, Guangzhou 510640, China
3.
Shandong Research Center of Engineering & Technology for Clean Energy, Zibo 255000, China
4.
School of Environmental Science and Engineering, Tianjin University, Tianjin 300072, China
5.
Huaneng (Zhejiang) Energy Development Co., LTD. Yuhuan Branch, Yuhuan 317604, China

Funds: The project was supported by the National Natural Science Foundation of China (52006129, 51906129), Shandong Provincial Natural Science Foundation (ZR2020QE205) and Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development (E039kf0701, E239kf0401).

Received Date: 2022-04-29
Accepted Date: 2022-06-14
Rev Recd Date: 2022-06-04

Available Online: 2022-07-11

Publish Date: 2023-01-10

Abstract

Abstract

The light olefins, mainly ethylene, propylene and butene, are basic building blocks in chemical industry. The direct conversion of syngas to lower olefins considered as a new significant and attractive process for producing lower olefins from non-petroleum resources, owing to its process simplicity and low energy consumption. The light olefins can be directly produced from syngas via two routes, namely, the Fischer-Tropsch to olefins (FTO) reaction and oxide-zeolite (OX-ZEO) bifunctional catalysis strategy (SDTO). This paper mainly reviews recent developments of SDTO, with emphasis on the effects of catalyst design, catalyst preparation and interphase renovation on reactivity. The targeting control of operating parameters such as H₂/CO ratio, temperature, pressure and contact for higher production of light olefins has also been clarified. Applications of new in situ, in real-time techniques to identify the structure-function relationship and the reaction mechanism are summarized. The recent progress including the applications of new in situ, real-time techniques to identify the structure-function relationship and the reaction mechanism are reviewed in detail. With this, the authors put forward insights into significant promising tendencies and confronting challenges in the strategy of OX-ZEO.
- light olefin,
- syngas,
- Fischer-Tropsch synthesis,
- bifunctional catalyst,
- reaction mechanism

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References(75)

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