Study of calcium-based waste on adsorption enhanced biomass gasification for hydrogen production

CHEN Yuan; YANG Hai-ping; ZOU Jun; ZHAO Yu-jia; CHEN Han-ping

doi:10.19906/j.cnki.JFCT.2022054

Volume 51 Issue 4

Apr. 2023

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Article Navigation > Journal of Fuel Chemistry and Technology > 2023 > 51(4): 538-543

CHEN Yuan, YANG Hai-ping, ZOU Jun, ZHAO Yu-jia, CHEN Han-ping. Study of calcium-based waste on adsorption enhanced biomass gasification for hydrogen production[J]. Journal of Fuel Chemistry and Technology, 2023, 51(4): 538-543. doi: 10.19906/j.cnki.JFCT.2022054

Citation:

CHEN Yuan, YANG Hai-ping, ZOU Jun, ZHAO Yu-jia, CHEN Han-ping. Study of calcium-based waste on adsorption enhanced biomass gasification for hydrogen production[J]. Journal of Fuel Chemistry and Technology, 2023, 51(4): 538-543. doi: 10.19906/j.cnki.JFCT.2022054

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Study of calcium-based waste on adsorption enhanced biomass gasification for hydrogen production

doi: 10.19906/j.cnki.JFCT.2022054

CHEN Yuan^{1, 2
,},
YANG Hai-ping¹,
ZOU Jun^{1
,
,},
ZHAO Yu-jia^{1, 2},
CHEN Han-ping¹

1.
State Key Laboratory on Coal Combustion, Huazhong University of Science and Technology, Wuhan 430074, China
2.
China-Europe Institution for Clean and Renewable Energy, Wuhan 430074, China

Funds: The project was supported by the National Key Research and Development Program of China (2019YFB1503900)

Received Date: 2022-04-12
Rev Recd Date: 2022-06-15

Available Online: 2022-07-11

Publish Date: 2023-04-15

Abstract

Abstract

In order to improve the efficiency of biomass gasification to hydrogen production, the comprehensive utilization of industrial solid waste resources, the use of calcium-based waste-calcium carbide slag as a CO₂ adsorbent, experiments were carried out in a two-stage fixed bed to explore the effect of calcium-based waste addition, reaction temperature on the biomass gasification hydrogen production characteristics, focusing on the study of the adsorbent in practical applications of the cyclic adsorption performance, and thus discuss the influence mechanism of calcium carbide slag on biomass adsorption enhanced gasification. The results show that with the gradual increase of calcium carbide slag addition, H₂ yield and concentration show an increasing trend. With the increase of temperature, the yield and concentration of H₂ increase first and then decrease. When the CaO/C molar ratio is 1 and the temperature of the reforming section is 700 ℃, the yield and concentration of H₂ in the gas product are 154.34 mL/g biomass and 26.76%, and the maximum value is obtained. When the number of calcium carbide slag cycles is less than 5, the concentration and yield of H₂ increase compared to the initial reaction.
- carbide slag,
- biomass,
- hydrogen production by adsorption-enhanced gasification

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References(14)

References

[1]	UDOMSIRICHAKORN J, BASU P, SALAM P A, ACHARYA B. Effect of CaO on tar reforming to hydrogen-enriched gas with in-process CO₂ capture in a bubbling fluidized bed biomass steam gasifier[J]. Int J Hydrog Energy,2013,38(34):14495−14504. doi: 10.1016/j.ijhydene.2013.09.055
[2]	DUAN W, YU Q. Thermodynamic analysis of hydrogen-enriched syngas generation coupled with in situ CO₂ capture using chemical looping gasification method[J]. J Therm Anal Calorim,2017,131(2):1671−1680.
[3]	DONG J, NZIHOU A, CHI Y, WEISS-HORTALA E, NI M, LYCZKO N, TANG Y, DUCOUSSO M. Hydrogen-rich gas production from steam gasification of bio-char in the presence of CaO[J]. Waste Biomass Valori,2016,8(8):2735−2746.
[4]	LI B, MAGOUA MBEUGANG C F, HUANG Y, LIU D, WANG Q, ZHANG S. A review of CaO based catalysts for tar removal during biomass gasification[J]. Energy,2022,244:1.
[5]	耿一琪, 郭彦霞, 樊飙, 程芳琴, 成怀刚. CaO基吸附剂捕集CO₂及其抗烧结改性研究进展[J]. 燃料化学学报,2021,49(7):998−1013. doi: 10.1016/S1872-5813(21)60040-3 GENG Yi-qi, GUO Yan-xia, FAN Biao, CHENG Fang-qin, CHENG Huai-gang. Research progress of calcium-based adsorbents for CO₂ capture and anti-sintering modification[J]. J Fuel Chem Technol,2021,49(7):998−1013. doi: 10.1016/S1872-5813(21)60040-3
[6]	ZHANG H, JIANG T, YASEEN H A S M, ZHAO Y, WANG S, MA X. Pelletization and attrition of CaO‐based adsorbent for CO₂ capture[J]. Asia-Pac J Chem Eng,2021,16(4):2656-1−2656-19.
[7]	XU Y, LUO C, ZHENG Y, DING H, WANG Q, SHEN Q, LI X, ZHANG L. Characteristics and performance of CaO-based high temperature CO₂ sorbents derived from a sol-gel process with different supports[J]. RSC Adv,2016,6(83):79285−79296. doi: 10.1039/C6RA15785H
[8]	WANG S, SHEN H, FAN S, ZHAO Y, MA X, GONG J. Enhanced CO₂ adsorption capacity and stability using CaO-based adsorbents treated by hydration[J]. AIChE J,2013,59(10):3586−3593. doi: 10.1002/aic.14126
[9]	YANG H, WANG D, LI B, ZENG Z, QU L, ZHANG W, CHEN H. Effects of potassium salts loading on calcium oxide on the hydrogen production from pyrolysis-gasification of biomass[J]. Bioresour Technol,2018,249:744−750. doi: 10.1016/j.biortech.2017.10.083
[10]	XU A, ZHOU W, ZHANG X, ZHAO B, CHEN L, SUN L, DING W, YANG S, GUAN H, BAI B. Gas production by catalytic pyrolysis of herb residues using Ni/CaO catalysts[J]. J Anal Appl Pyrolysis,2018,130:216−223. doi: 10.1016/j.jaap.2018.01.006
[11]	LIU F, LI W, LIU B, LI R. Synthesis, characterization, and high temperature CO₂ capture of new CaO based hollow sphere sorbents[J]. J Mater Chem A,2013,1(27):8037. doi: 10.1039/c3ta11369h
[12]	刘小通. 改性钙基CO₂高温吸附剂的研究[D]. 西安: 西北大学, 2017. LIU Xiao-tong . Study of modified CaO-based sorbents for CO₂ at high temperture[D]. Xi 'an : Northwest University, 2017.
[13]	LV S Z, ZHAO S Y, LIU M M, WU P P. Preparation of calcium carbonate by calcium carbide residue[J]. Adv Mat Res,2013,864−867:1963−1967.
[14]	LI Y, WANG W, CHENG X, SU M, MA X, XIE X. Simultaneous CO₂/HCl removal using carbide slag in repetitive adsorption/desorption cycles[J]. Fuel,2015,142:21−27. doi: 10.1016/j.fuel.2014.10.071