One-step catalyst for the preparation of light olefins and liquid fuels from syngas

LIU Sai-sai; YAO Jin-gang; CHEN Guan-yi; YI Wei-ming; YAN Bei-bei; LIU Jing; ZHANG Qing-wen; ZHU Lei

doi:10.19906/j.cnki.JFCT.2022055

Volume 51 Issue 1

Jan. 2023

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Article Navigation > Journal of Fuel Chemistry and Technology > 2023 > 51(1): 34-51

LIU Sai-sai, YAO Jin-gang, CHEN Guan-yi, YI Wei-ming, YAN Bei-bei, LIU Jing, ZHANG Qing-wen, ZHU Lei. One-step catalyst for the preparation of light olefins and liquid fuels from syngas[J]. Journal of Fuel Chemistry and Technology, 2023, 51(1): 34-51. doi: 10.19906/j.cnki.JFCT.2022055

Citation:

LIU Sai-sai, YAO Jin-gang, CHEN Guan-yi, YI Wei-ming, YAN Bei-bei, LIU Jing, ZHANG Qing-wen, ZHU Lei. One-step catalyst for the preparation of light olefins and liquid fuels from syngas[J]. Journal of Fuel Chemistry and Technology, 2023, 51(1): 34-51. doi: 10.19906/j.cnki.JFCT.2022055

Citation:

LIU Sai-sai, YAO Jin-gang, CHEN Guan-yi, YI Wei-ming, YAN Bei-bei, LIU Jing, ZHANG Qing-wen, ZHU Lei. One-step catalyst for the preparation of light olefins and liquid fuels from syngas[J]. Journal of Fuel Chemistry and Technology, 2023, 51(1): 34-51. doi: 10.19906/j.cnki.JFCT.2022055

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One-step catalyst for the preparation of light olefins and liquid fuels from syngas

doi: 10.19906/j.cnki.JFCT.2022055

LIU Sai-sai^{1, 2, 3
,},
YAO Jin-gang^{1, 2, 3
,
,},
CHEN Guan-yi⁴,
YI Wei-ming^{1, 3},
YAN Bei-bei⁴,
LIU Jing^{1, 2, 3
,
,},
ZHANG Qing-wen⁵,
ZHU Lei⁵

1.
School of Agricultural Engineering and Food Science, Shandong University of Technology, Zibo 255000, China
2.
Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development, Guangzhou 510640, China
3.
Shandong Research Center of Engineering & Technology for Clean Energy, Zibo 255000, China
4.
School of Environmental Science and Engineering, Tianjin University, Tianjin 300072, China
5.
Huaneng Shanghai Shidongkou Second Power Plant, Shanghai 200942, China

Funds: The project was supported by the Shandong Provincial Natural Science Foundation (ZR2020QE205), National Natural Science Foundation of China (52006129, 51906129) and Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development (E039kf0701, E239kf0401).

Received Date: 2022-05-23
Accepted Date: 2022-06-30
Rev Recd Date: 2022-06-30

Available Online: 2022-07-11

Publish Date: 2023-01-10

Abstract

Abstract

One-step synthesis of light olefin and liquid fuel using syngas as platform compound is an important way to effectively utilize carbon resources. It has the characteristics of short process, low energy consumption, and is of good industrial application prospects. The one-step direct conversion of syngas to prepare light olefins and liquid fuels consists of two process routes: the Fischer-Tropsch (F-T) route and the bifunctional catalytic route. In this paper, the reaction mechanisms of both routes are briefly described. The optimal design of Fe-based and Co-based catalysts by inert supports, the effect of F-T metal particle size, reaction conditions, and catalyst structure on the catalytic performance and reaction process have been elaborated. In the bifunctional catalytic route, the influences of the CO activation components, zeolite type, the proportion and particle size of the metal oxide elements, the acidity and pore size of zeolites and the methods for coupling the CO activation components and zeolite on the performance of the catalysts were analyzed in detail. The advantages and challenges of the two routes are summarized. The development trends of efficient catalysts in the future have also been prospected.
- syngas,
- catalyst,
- light olefins,
- liquid fuels,
- bifunctional catalysis,
- Fischer-Tropsch synthesis

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References(98)

References

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