Preparation of NiPt/SBA-15 nanocatalyst and its catalytic performance for the dehydrogenation of hydrous hydrazine

LIANG Yu; LI Gui; ZHENG Jun-ning; XU Li-xin; YE Ming-fu; WAN Chao

doi:10.19906/j.cnki.JFCT.2022072

Volume 51 Issue 5

May 2023

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LIANG Yu, LI Gui, ZHENG Jun-ning, XU Li-xin, YE Ming-fu, WAN Chao. Preparation of NiPt/SBA-15 nanocatalyst and its catalytic performance for the dehydrogenation of hydrous hydrazine[J]. Journal of Fuel Chemistry and Technology, 2023, 51(5): 684-692. doi: 10.19906/j.cnki.JFCT.2022072

Citation:

LIANG Yu, LI Gui, ZHENG Jun-ning, XU Li-xin, YE Ming-fu, WAN Chao. Preparation of NiPt/SBA-15 nanocatalyst and its catalytic performance for the dehydrogenation of hydrous hydrazine[J]. Journal of Fuel Chemistry and Technology, 2023, 51(5): 684-692. doi: 10.19906/j.cnki.JFCT.2022072

Citation:

LIANG Yu, LI Gui, ZHENG Jun-ning, XU Li-xin, YE Ming-fu, WAN Chao. Preparation of NiPt/SBA-15 nanocatalyst and its catalytic performance for the dehydrogenation of hydrous hydrazine[J]. Journal of Fuel Chemistry and Technology, 2023, 51(5): 684-692. doi: 10.19906/j.cnki.JFCT.2022072

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Preparation of NiPt/SBA-15 nanocatalyst and its catalytic performance for the dehydrogenation of hydrous hydrazine

doi: 10.19906/j.cnki.JFCT.2022072

LIANG Yu^1
,,
LI Gui¹,
ZHENG Jun-ning¹,
XU Li-xin^{1
,
,},
YE Ming-fu^{1, 2, 3, 4},
WAN Chao^{1, 5
,
,}

1.
College of Chemistry and Chemical Engineering, Institute of Engineering, Anhui University of Technology, Ma’anshan 243000, China
2.
Jiangxi Province Engineering Research Center of Ecological Chemical Industry, Jiujiang University, Jiujiang 332005, China
3.
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Nankai University, Tianjin 300071, China
4.
Anhui Key Laboratory of Photoelectric-Magnetic Functional Materials, Anhui Key Laboratory of Functional Coordination Compounds, Anqing Normal University, Anqing 246011, China
5.
College of Chemical Engineering and Biological Engineering, Zhejiang University, Hangzhou 310027, China

Funds: The project was supported by the National Natural Science Foundation of China (22108238, U22A20408), Anhui Provincial Natural Science Foundation (1908085QB68), Major Science and Technology Project of Anhui Province (201903a05020055), China Postdoctoral Science Foundation (2019M662060, 2020T130580), Postdoctoral International Exchange Program（PC2022046), Open Research Funds of Anhui Key Laboratory of Photoelectric-Magnetic Functional Materials (ZD2021007) and Open Research Funds of Jiangxi Province Engineering Research Center of Ecological Chemical Industry (STKF2109).

Received Date: 2022-06-25
Accepted Date: 2022-09-07
Rev Recd Date: 2022-08-26

Available Online: 2022-09-08

Publish Date: 2023-05-15

Abstract

Abstract

As the most promising hydrogen storage material, hydrous hydrazine (N₂H₄·H₂O) has attracted extensive attention and interest of researchers. In this paper, NiPt bimetallic supported SBA-15 (mesoporous silica) catalysts with different metal ratios were prepared by a simple impregnation reduction method, and their catalytic hydrous hydrazine dehydrogenation performance was studied. The research results show that Pt and Ni form an alloy during the preparation of the catalyst, the electronic synergistic effect of the two metals can effectively promote the catalytic performance of the catalyst, and the interaction between SBA-15 and the metal active components helps to improve the catalytic performance and cycling stability of catalysts. The activation energy of the Pt₆Ni₄/SBA-15 catalyst is 45.6 kJ/mol and the TOF value is 2123.3 h⁻¹, which are better than most of the reported catalysts.
- hydrous hydrazine,
- dehydrogenation,
- NiPt,
- SBA-15

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References(44)

References

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