聚乙烯塑料在连续超临界水反应器中的油化研究

The effects of temperature, residence time, and pressure on the degradation of polyethylene (PE) to oil were investigated in supercritical water (SCW) using a 180mL continuous reactor. The yield of oil product increases with the increase of temperature, reaching 79% at 530℃, and then decreases as the temperature further increases. The yield of gas product increases from 3% to 22% as the temperature increases from 500℃to 550℃. The product distribution shifts toward shorter chain hydrocarbons with the prolongation of reaction time. Furthermore, the ratio of alkenes to alkanes of products increases with the increase of temperature and pressure, and decreases with the increase of reaction time. The effect of pressure on both products' yield and composition is less significant.