反应条件对悬浮床加氢裂化过程的影响
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摘要: 在间歇式反应釜中,考察了氢分压3MPa~28MPa对叔丁基苯和正丁基苯裂化反应的影响。结果表明,氢分压变化对不同分子结构的反应物有不同的影响。叔丁基苯的转化率随氢分压的升高而提高,正丁基苯的转化率随氢分压的升高而降低。氢分压的提高促进了与芳香环连接的碳键的断裂,与反应物的分子结构无关。在此基础上,考察了初氢压的变化对轮古常压渣油(LGAR)和克拉玛依常压渣油(KMAR)悬浮床加氢裂化的影响,讨论了温度和反应时间对悬浮床加氢过程的影响,初氢压的提高对渣油的转化和甲苯不溶物的生成都有促进作用。Abstract: The effect of partial hydrogen pressure within 3MPa~28MPa on cracking of butylbenzene and tert-butylbenzene were examined in a batch reactor. Pressure has different effects depending on the molecular structure of reactants. With the raising of partial hydrogen pressure, the cracking reaction of tert-butylbenzene is prompted, while the conversion of butylbenzene is restricted. In any case, the break of C—C bonds between the aromatic ring and the whole branch chain are promoted with the increasing of partial hydrogen pressure. Based on the above result, the effect of initial hydrogen pressure on slurry bed hydrocracking of Lungu and Karamay atmospheric residues was studied. With the raising of initial hydrogen pressure, the reactions of hydrocracking and the formation of toluene insoluble fraction are promoted simultaneously. Effects of reaction temperature and time are also discussed.
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Key words:
- reaction condition /
- butylbenzene /
- tert-butylbenzene /
- residue /
- slurry /
- hydrocracking
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