生物柴油树种油脂脂肪酸组成对燃料特性的影响

王利兵; 于海燕; 贺晓辉; 刘瑞英

生物柴油树种油脂脂肪酸组成对燃料特性的影响

1.
中国林业科学研究院林业研究所, 北京 100091;
2.
中国林业科学研究院林业新技术研究所, 北京 100091;
3.
鄂尔多斯市林业治沙科学研究所,内蒙古鄂尔多斯 017000;
4.
乌兰察布市职业技术学校,内蒙古乌兰察布 012000

基金项目: 国家科技部科技支撑计划(2011BAD22B08); 国家财政部、科技部公益性行业科研专项(201004001)。

详细信息

通讯作者:
于海燕(1968-), 女, 副研究员, 主要从事生物质能源方面的研究, E-mail: 13520914079@163.com。

中图分类号: TK6
计量
- 文章访问数: 2054
- HTML全文浏览量: 33
- PDF下载量: 1221
- 被引次数: 0
出版历程
- 收稿日期: 2011-10-25
- 修回日期: 2011-12-20
- 刊出日期: 2012-04-30

Influence of fatty acid composition of woody biodiesel plants on the fuel properties

1.
Research Institute of Forestry, Chinese Academy Forestry, Beijing 100091, China;
2.
Research Institute of New Technology of Forestry, Chinese Academy Forestry, Beijing 100091, China;
3.
Ordos Research Institute of Forestry Sand Control, Ordos 017000, China;
4.
Wulanchabu Vocational and Technical School, Wulanchabu 012000, China

摘要

摘要: 以目前中国主要开发或具有开发潜能的10种生物柴油树种为研究对象,分析其果实或种子油脂脂肪酸组成对合成生物柴油燃料特性的影响。结果表明,木本植物生物柴油产品十六烷值、碘值、氧化安定性等燃料特性主要由原料油脂肪酸的不饱和度决定,脂肪酸不饱和度低于133.13,十六烷值(GB/T 20828-2007)和碘值(EN 14214)就可以达标。生物柴油产品冷滤点随着长碳链饱和脂肪酸的增加而升高,脂肪酸饱和碳链长度因子分别小于8.41和2.72时,可以满足冷滤点0℃和-10℃的要求。高品质生物柴油的原料中应该具有较高的单元不饱和脂肪酸含量。通过油脂脂肪酸单不饱和脂肪酸、多不饱和脂肪酸和饱和脂肪酸的组成绘制出生物柴油特性三角预测图,为预测生物柴油产品燃料特性提供参考依据。
- 木本植物 /
- 生物柴油 /
- 脂肪酸组成 /
- 燃料特性
Abstract: Ten major trees that can be used as the potential raw materials of biodiesel are taken as the research objects, and the influence of their fruit or seeds’ fatty acid composition on the biodiesel was studied. The results showed that the fuel properties such as cetane number, idodine number and oxidation stability were mainly determined by the degree of unsaturation of raw oils fatty acid. When the degree of unsaturation of raw oils fatty acid was lower than 133.13, cetane number (GB/T 20828-2007) and iodine number (EN 14214) could be up to the standards. With the increase of the long chain saturated fatty acids, cold filter plugging point of the biodiesel product tended to be higher. When the chain length saturated factors less than 8.41 and 2.72, it could meet the standards of 0℃ and -10℃ of cold filter plugging point. The raw materials for high-quality biodiesel should have high content of monounsaturated fatty acids. Basis on the study of the compositions of monounsaturated, polyunsaturated and saturated methyl esters, a triangular prediction graph for biodiesel fuel properties was worked out, which could provide references for the prediction of the fuel properties of biodiesel product.
- woody plants /
- biodiesel /
- fatty acid composition /
- biodiesel properties

HTML全文

参考文献(27)

KARMAKAR A, KARMAKAR S, MUKHERJEE S. Properties of various plants and animals feedstocks for biodiesel production[J]. Bioresour Technol, 2010, 101(19): 7201-7210.

楼狄明, 沈航泉, 胡志远, 谭丕强, 李博. 基于不同原料生物柴油混合燃料的发动机性能研究[J]. 内燃机工程, 2011, 32(1): 40-41. (LOU Di-ming, SHEN Hang-quan, HU Zhi-yuan, TAN Pi-qiang, LI Bo. Research on performance of diesel engine operating on different biodiesel blends[J]. Chinese Internal Combustion Engine Engineering, 2011, 32(1): 40-41.)

林水富, 沈芸. 发展木本油料生物柴油产业的思考[J]. 林业经济问题, 2010, 30(2): 131-135. (LIN shui-fu, SHEN yun. Thinking about the wood-oil biodiesel industry[J]. Issues of Forestry Economics, 2010, 30(2): 131-135.)

RAMOS M J, FERNÁNDEZ C M, CASAS A, RODRÍGUEZ L , PEREZ A. Influence of fatty acid composition of raw materials on biodiesel properties[J]. Bioresour Technol, 2009, 100(1): 261-268.

CARDONE M, MAZZONCINI M, MENINI S, ROCCO V, SENATORE A, SEGGIANI M , VITOLO S. Brassica carinata as an alternative oil crop for the production of biodiesel in Italy: Agronomic evaluation, fuel production by transesterification and characterization[J]. Biomass Bioenergy, 2003, 25(6): 623-636.

PINZI S, LEIVA D, ARZAMENDI G, GANDIA L M , DORADO M P. Multiple response optimization of vegetable oils fatty acid composition to improve biodiesel physical properties[J]. Bioresour Technol, 2011, 102(15): 7280-7288.

GHEBRETINSAE A G, GRAHAM S A, CAMILO G R , BARBER J C. Natural infraspecific variation in fatty acid composition of Cuphea (Lythraceae) seed oils[J]. Ind Crops Prod, 2008, 27(3): 279-287.

王存文. 生物柴油制备技术及实例[M]. 北京:化学工业出版社,2009. (WANG Cun-wen. Preparation technology and example of biodiesel[M]. Beijing: Chemical Industry Press, 2009.)

佘珠花, 刘大川, 刘金波, 叶平, 张安清. 麻疯树籽油理化特性和脂肪酸组成分析[J]. 中国油脂, 2005, 30(5): 30-31. (SHE Zhu-hua, LIU Da-chuan, LIU Jin-bo, YE Ping, ZHANG An-qing. Physicochemical properties and ratty acid composition of Jatropha curcas L. seed oil[J]. China Oils and Fats, 2005, 30(5): 30-31.)

FOIDL N, FOIDL G, SANCHEZ M, MITTELBACH M, HACKEL S. Jatropha curcas L. as a source for the production of biofuel in Nicaragua[J]. Bioresour Technol, 1996, 58(1): 77-82.

李昌珠, 张爱华, 肖志红, 蒋丽娟, 李培旺. 用碱性离子液体催化光皮树果实油制备生物柴油[J]. 中南林业科技大学学报, 2011, 31(3): 38-43. (LI Chang-zhu, ZHANG Ai-hua, XIAO Zhi-hong, JIANG Li-juan, LI Pei-wang. Preparation of biodiesel from Cornus wilsoniana fruit oil with basic ionic liquids as catalyst[J]. Journal of Central South University of Forestry & Technology, 2011, 31(3): 38-43.)

龙川. 生物柴油原料树种综合评价及乌桕基FAME的开发利用. 福州: 福建农林大学, 2008. (LONG Chuan. Comprehensive assessment in biodiesel feedstock and exploration of sapium sebferum seed oils FAME. Fuzhou: Fujian Agriculture and Forestry University, 2008.)

周燕君, 陆向红, 俞云良, 计建炳. 桐油制取生物柴油的研究[J]. 能源工程, 2008, (5): 32-36. (ZHOU Yan-jun, LU Xiang-hong, YU Yun-liang, JI Jian-bin. The research about production of biodiesel from tung oil[J]. Energy Engineering, 2008, (5): 32-36.)

罗艳, 刘梅. 开发木本油料植物作为生物柴油原料的研究[J]. 中国生物工程杂志, 2007, 27(7): 68-74. (LUO Yan, LIU Mei. Oil-bearing trees as a source for biodiesel[J]. China Biotechnology, 2007, 27(7): 68-74.)

戴国富, 谢世友, 万腾, 安小凤. 山桐子开发利用前景与展望[J]. 重庆三峡学院学报, 2011, 27(132):105-109. (DAI Guo-fu, XIE Shi-you, WAN Teng, AN Xiao-feng. Outlook and prospect for Idesia polycarpa exploitation[J]. Journal of Chongqing Three Gorges University, 2011, 27(132): 105-109.)

汪全义, 杜开峰, 李新莹, 兰先秋, 宋航. 毛叶山桐子油制备生物柴油的研究[J]. 粮油加工, 2009, (2): 52-55. (WANG Quan-yi, DU Kai-feng, LI Xin-ying, LAN Xian-qiu, SONG Hang. Preparation biodiesel of idesia polycarpa seed oil[J]. Cereals and Oils Processing, 2009, (2): 52-55.)

刘淑娟, 江映翔, 蔡樱英, 刘艳冰, 张倩倩. 棕榈油制备生物柴油的研究[J]. 热带作物学报, 2011, 32(3): 544-549. (LIU Shu-juan, JIANG Ying-xiang, CAI Ying-ying, LIU Yan-bing, ZHANG Qian-qian. Preparation of biodiesel from palm 0il[J]. Chinese Joumal of Trooical Crops, 2011, 32(3): 544-549.)

邢存章, 谭明臣, 吕海亮, 高菲. 超临界甲醇法制备生物柴油[J]. 石油化工高等学校学报, 2009, 22(1): 9-12. (XING Cun-zhang, TAN Ming-chen, LU Hai-liang, GAO Fei. Biodiese1 produced in supercritical methanol[J]. Journal of Petrochemical Universities, 2009, 22(1): 9-12.)

张春化, 吴占文, 边耀璋, 蹇小平. 生物柴油性能标准分析及建立健全标准体系的建议[J]. 农业工程学报, 2010, 26(3): 298-303. (ZHANG Chun-hua, WU Zhan-wen, BIAN Yao-zhang, JIAN Xiao-ping. Analysis of the standards for biodiesel property and suggestion on establishing and improving its standard system[J]. Transactions of the CSAE, 2010, 26(3): 298-303.)

KNOTHE G, MATHEAUS A C, RYANIII T W. Cetane numbers of branched and straight chain fatty esters determined in an ignition quality tester[J]. Fuel, 2003, 82(8): 971-975.

王利兵. 三种山杏种子生物柴油特征评价[J]. 农业工程学报, 2011, 27(s1): 138-142. (WANG Li-bin. Assessment in three Armeniaca species seed oils for biodiesel traits[J]. Transactions of the CSAE, 2011, 27(supp1): s138-s142.)

LIN C Y, LIN H A , HUNG L B. Fuel structure and properties of biodiesel produced by the peroxidation process [J]. Fuel, 2006, 85(12/13): 1743-1749.

KNOTHE G. Structure indices in FA chemistry:How relevant is the iodine value?[J]. Journal of the American Oil Chemists Society, 2002, 97(9): 847-853.

汪海波, 徐群英. 几种生物柴油的制备及其流变学性能的比较[J]. 燃料化学学报, 2008, 36(5): 570-576. (WANG Hai-bo, XU Qun-ying. Preparation of several bio-diesels and analysis of their rheological behavior[J]. Journal of Fuel Chemistry and Technology, 2008, 36(5): 70-576.)

吕涯, 李骏, 欧阳福生. 生物柴油调合对其低温流动性能的改善[J]. 燃料化学学报, 2011, 39(3): 189-193. (LV Ya, LI Jun, OUYANG Fu-sheng. Effect of biodiesels blending on their low-temperature fluidity[J]. Journal of Fuel Chemistry and Technology, 2011, 39(3): 189-193.)

IMAHARA H, MINAMI E, SAKA S. Thermodynamic study on cloud point of biodiesel with its fatty acid composition[J]. Fuel, 2006, 85(12/13): 1666-1670.

KNOTHE G. Dependence of biodiesel fuel properties on the structure of fatty acid alkyl esters[J]. Fuel Process Technol, 2005, 86(10): 1059-1070.

施引文献

资源附件(0)

访问统计

点击查看大图

计量

文章访问数: 2054
HTML全文浏览量: 33
PDF下载量: 1221
被引次数: 0

姓名
邮箱
手机号码
标题
留言内容
验证码

留言板

生物柴油树种油脂脂肪酸组成对燃料特性的影响

通讯作者:
于海燕(1968-), 女, 副研究员, 主要从事生物质能源方面的研究, E-mail: 13520914079@163.com。

计量

Influence of fatty acid composition of woody biodiesel plants on the fuel properties

计量

目录

2023年《燃料化学学报（中英文）》评优结果公布！

留言板

生物柴油树种油脂脂肪酸组成对燃料特性的影响

通讯作者: 于海燕(1968-), 女, 副研究员, 主要从事生物质能源方面的研究, E-mail: 13520914079@163.com。

计量

出版历程

Influence of fatty acid composition of woody biodiesel plants on the fuel properties

计量

出版历程

目录

2023年《燃料化学学报（中英文）》评优结果公布！

通讯作者:
于海燕(1968-), 女, 副研究员, 主要从事生物质能源方面的研究, E-mail: 13520914079@163.com。