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不同煤燃烧方式降低NOx排放比较及解耦燃烧应用

尚校 高士秋 汪印 董利 许光文 郭景海

尚校, 高士秋, 汪印, 董利, 许光文, 郭景海. 不同煤燃烧方式降低NOx排放比较及解耦燃烧应用[J]. 燃料化学学报(中英文), 2012, 40(06): 672-679.
引用本文: 尚校, 高士秋, 汪印, 董利, 许光文, 郭景海. 不同煤燃烧方式降低NOx排放比较及解耦燃烧应用[J]. 燃料化学学报(中英文), 2012, 40(06): 672-679.
SHANG Xiao, GAO Shi-qiu, WANG Yin, DONG Li, XU Guang-wen, GUO Jing-hai. Comparison of NOx reduction among different coal combustion methods and the application of decoupling combustion[J]. Journal of Fuel Chemistry and Technology, 2012, 40(06): 672-679.
Citation: SHANG Xiao, GAO Shi-qiu, WANG Yin, DONG Li, XU Guang-wen, GUO Jing-hai. Comparison of NOx reduction among different coal combustion methods and the application of decoupling combustion[J]. Journal of Fuel Chemistry and Technology, 2012, 40(06): 672-679.

不同煤燃烧方式降低NOx排放比较及解耦燃烧应用

基金项目: 国家自然科学基金(21076217); 国家重点基础研究发展规划(973计划, 2011CB201304); 国家科技支撑计划(2010BAC66B01); 国家高技术研究发展计划(863计划, 2007AA05Z304); 中国科学院科技支新项目。
详细信息
    通讯作者:

    高士秋, 许光文, Tel: 010-82544885, E-mail: sqgao@home.ipe.ac.cn,gwxu@home.ipe.ac.cn。

  • 中图分类号: TQ534.9

Comparison of NOx reduction among different coal combustion methods and the application of decoupling combustion

  • 摘要: 采用两段反应器研究了三种煤在不同燃烧方式下抑制NOx生成的效果。结果表明,煤的热解气和部分气化生成气再燃均能较好的抑制NOx生成,抑制效果优于空气分级燃烧,解耦燃烧方式抑制NOx生成的效果最显著,相对于传统燃烧其NOx排放降低了32%以上。煤种对各种燃烧方式降低NOx的程度有明显影响,煤中单位氮含量的燃料比(固定碳/挥发分)越小,煤的热解气和部分气化生成气再燃以及解耦燃烧方式下NOx的排放量越低。在煤部分气化生成气再燃烧方式中,部分氧化气化段通氧量不同,降低NOx排放的效果也不同,在氧气体积分数为8%~10%时的NOx生成量最低。基于解耦燃烧技术原理,研制了1.4 MW解耦燃烧工业锅炉,在燃烧同一煤种时,解耦燃烧锅炉和传统立式锅炉相比,烟气中NOx排放量降低了32.9%。
  • 赵钦新, 周屈兰. 工业锅炉节能减排现状、 存在问题及对策[J]. 工业锅炉, 2010, (1): 1-6. (ZHAO Qin-xin, ZHOU Qu-lan. Solutions,questions and status of China's industrial boiler[J]. Industrial Boiler, 2010, (1): 1-6.)
    苏亚欣, 毛玉如, 徐璋. 燃煤氮氧化物排放控制技术[M]. 北京: 化学工业出版社, 2005: 70-118. (SU Ya-xin, MAO Yu-ru, XU Zhang. Coal nitrogen oxide emissions control technology[M]. Beijing: Chemical Industry Press, 2005: 70-118.)
    JOHN P, JOEL B. Natural gas reburn: Cost effective NOx control[J]. Power Eng, 1994, 98(5): 47-50.
    FOLSOM B A, SOMMER T M, PAYNE R. Demonstration of combined NOx and SO2 emission control technologies involving gas reburning//International Conference on Environmental Control of Combustion Processes. 1991, 10.
    FOLSOM B A, PAYNE R, MOYEDA D. Advanced reburning with new process enhancements//In EPRI/EPA 1995 Joint Symposium on Stationary Combustion NOx Control. 1995.
    TREE D R, CLARK A W. Advanced reburning measurements of temperature and species in a pulverized coal flame[J], Fuel, 2000, 79(13): 1687-1695.
    钟北京, 傅维标. 气体燃料再燃对NOx还原的影响[J]. 热能动力工程, 1999, 14(6): 419-423. (ZHONG Bei-jing, FU Wei-biao. Effects of gaseous fuel reburning on NOx reduction[J]. Journal of Engineering for Thermal Energy and Power, 1999, 14(6): 419-423.)
    郭永红. 超细粉再燃低NOx燃烧技术的数值模拟与实验研究. 北京: 华北电力大学, 2006. (GUO Yong-hong. Numerical simulation and experimental study on low-NOx technique by micronized coal reburning. Beijing: North China Electric Power University, 2006.)
    ZARNESCU V, PISUPATI S V. The effect of mixing model and mixing characteristics on NOx reduction during reburning[J]. Energy Fuels, 2001, 15(2): 363-371.
    候祥松, 张海. 焦炉煤气再燃降低NOx排放技术研究[J]. 煤炭转化, 2007, 30(1): 39-42. (HOU Xiang-song, ZHANG Hai.Study on technology of NOx emission reduction by coke oven gas reburning[J]. Coal Conversion, 2007, 30(1): 39-42.)
    江鸿, 金晶, 刘瑞, 姜江, 于新娜. 部分气化煤制气再燃低NOx燃烧技术气化方案探讨[J]. 上海电力, 2009, (1): 68-70. (JIANG Hong, JIN Jing, LIU Rui, JIANG Jiang, YU Xin-na. Study gasification program of reduction of NOx formation with reburning of combustible gas from gasification[J]. Shanghai Electric Power, 2009, (1): 68-70.)
    李静海, 许光文, 杨励丹, 郭慕孙, 张建国, 郭有良, 周章玉. 一种抑制氮氧化物的无烟燃煤方法及燃煤炉: 中国, ZL95102081.1. 1995-03-07. (LI Jing-hai, XU Guang-wen, YANG Li-dan, GUO Mu-sun, Zhang Jian-guo, GUO You-liang, ZHOU Zhang-yu. A NOx-suppressed smokeless coal combustion technique and stove: CN, ZL95102081.1. 1995-03-07.)
    许光文, 高士秋, 刘新华. 燃煤锅炉的低污染高效率燃烧方法及燃烧装置: 中国, ZL200610011353.7. 2006-02-23. (XU Guang-wen, GAO Shi-qiu, LIU Xin-hua. The combustion method and equipment for coal-fired boiler with low pollution and high efficiency: CN, ZL200610011353.7. 2006-02-23.)
    许光文, 郝江平, 高士秋, 董利, 刘新华. 煤热解层燃装置及其燃烧方法: 中国, ZL200710120221.2. 2007-08-13. (XU Guang-wen, HAO Jiang-ping, GAO Shi-qiu, DONG Li, LIU Xin-hua. The grate-firing device with coal pyrolysis and its combustion method: CN, ZL200710120221.2. 2007-08-13.)
    HE J, SONG W, GAO S, DONG L, BARZ M, LI J, LIN W. Experimental study of the reduction mechanisms of NO emission in decoupling combustion of coal [J]. Fuel Process Technol, 2006, 87(9): 803-810.
    董利. 生物质解耦燃烧降低NO排放机理及应用研究. 北京: 中国科学院过程工程研究所. 2007: 60-61. (DONG Li. NO reduction by decoupling combustion of biomass and its application. Beijing: Institute of Process Engineering, Chinese Academy of Sciences, 2007: 60-61.)
    贾靖华, 董利, 高士秋, 尚校, 马晓迅, 许光文. 热解燃烧链条炉低NOx排放特性的数值模拟[J]. 过程工程学报, 2010,10(3): 842-848. (JIA Jing-hua, DONG Li, GAO Shi-qiu, SHANG Xiao, MA Xiao-xun, XU Guang-wen. Numerical simulation of low NOx emission characteristics in a pyrolysis-combustion chain grate boiler[J]. The Chinese Journal of Process Engineering, 2010,10(5): 842-848.)
    何京东. 煤炭解耦燃烧NO抑制机理实验研究. 北京: 中国科学院过程工程研究所, 2006: 71-72. (HE Jing-dong. Experimental study of the reduction mechanisms on NO emission in decoupling combustion of coal. Beijing: Institute of Process Engineering, Chinese Academy of Sciences, 2006: 71-72.)
    LEE B H, SONG J H, KIM R G, KIM S, KIM Y, CHANG Y, JEON C. Simulation of the influence of the coal volatile matter content on fuel NO emissions in a drop-tube furnace[J]. Energy Fuels, 2010, 24(8): 4333-4340.
    RYOICHI K, MICHITAKA I, HISAO M, KIMOTO M, MIYAZAKI T. Pulverized coal combustion characteristics of high-fuel-ratio coals[J]. Fuel , 2004, 83(13): 1777-1785.
    刘艳华, 张晓燕, 刘银河, 车得福. 再燃煤粉的NO还原特性研究[J]. 燃料化学学报, 2007, 35(5): 523-527. (LIU Yan-hua, ZHANG Xiao-yan, LIU Yin-he, CHE De-fu. NO reduction behavior of coal powder used for reburning[J]. Journal of Fuel Chemistry and Technology, 2007, 35(5): 523-527.)
    VISONA S P, STANMORE B R. Modeling NOx release from a single coal particle:Ⅱ Formation of NO from char-nitrogen[J]. Combust Flame, 1996, 106(3): 207-218.
    王俊琪. 煤的部分气化及半焦燃烧系统集成研究. 浙江: 浙江大学, 2008: 79-81. (WANG Jun-qi. System integration research on coal partial gasification and semicoke combustion. Zhejiang: Zhejiang University, 2008: 79-81.)
    周宏仓, 金保升, 仲兆平, 黄亚维. 流化床部分煤气化实验研究[J]. 热能动力工程, 2004, 19(3): 252-256. (ZHOU Hong-cang, JIN Bao-sheng, ZHONG Zhao-ping, HUANG Ya-wei. Experimental study of coal partial gasification in a fluidized bed[J]. Journal of Engineering for Thermal Energy and Power, 2004, 19(3): 252-256.)
    肖睿, 金保升, 欧阳嘉, 黄亚继, 周宏仓, 章名耀. 空气鼓风流化床煤部分气化炉煤气成分与热值试验[J]. 动力工程, 2004, 24(3):416-420. (XIAO Rui, JIN Bao-sheng, OU YANG Jia, HUANG Ya-ji, ZHOU Hong-cang, ZHANG Ming-yao. Experimental research on gas composition and heating value in an air-blown fluidized bed gasifier[J]. Power Engineering, 2004, 24(3): 416-420.)
    张荣光, 常万林, 那永杰, 吕清刚. 空煤比对循环流化床煤气化过程的影响[J]. 煤炭科学技术, 2006, 34(3):46-49. (ZHANG Rong-guang, CHANG Wan-lin, NA Yong-jie, LV Qing-gang. Air and coal ratio effected to circulated fluidized bed coal gasification[J]. Coal Science and Technology, 2006, 34(3): 46-49.)
    郝江平, 高士秋, 李静海, 许光文, 董利. 解耦燃烧炉及解耦燃烧方法: 中国, ZL200810117937.1. 2008-08-15. (HAO Jiang-ping, GAO Shi-qiu, LI Jing-hai, XU Guang-wen, DONG Li. Decoupling combustion boiler and method: CN, ZL200810117937.1. 2008-08-15.)
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出版历程
  • 收稿日期:  2011-08-28
  • 修回日期:  2011-11-21
  • 刊出日期:  2012-06-30

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