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油页岩的13C-NMR特征及FLASHCHAIN热解模拟研究

王擎,  任立国,  王锐,  柏静儒,  王浩添,  闫宇赫

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文章导航 > 燃料化学学报（中英文）  > 2014 >  42(03): 303-308
王擎, 任立国, 王锐, 柏静儒, 王浩添, 闫宇赫. 油页岩的13C-NMR特征及FLASHCHAIN热解模拟研究[J]. 燃料化学学报（中英文）, 2014, 42(03): 303-308.
引用本文: 王擎, 任立国, 王锐, 柏静儒, 王浩添, 闫宇赫. 油页岩的13C-NMR特征及FLASHCHAIN热解模拟研究[J]. 燃料化学学报（中英文）, 2014, 42(03): 303-308.
shu
WANG Qing, REN Li-guo, WANG Rui, BAI Jing-ru, WANG Hao-tian, YAN Yu-he. Characterization of oil shales by 13C-NMR and the simulation of pyrolysis by FLASHCHAIN[J]. Journal of Fuel Chemistry and Technology, 2014, 42(03): 303-308.
Citation: WANG Qing, REN Li-guo, WANG Rui, BAI Jing-ru, WANG Hao-tian, YAN Yu-he. Characterization of oil shales by 13C-NMR and the simulation of pyrolysis by FLASHCHAIN[J]. Journal of Fuel Chemistry and Technology, 2014, 42(03): 303-308.
shu

油页岩的13C-NMR特征及FLASHCHAIN热解模拟研究

  • 东北电力大学 油页岩综合利用教育部工程研究中心, 吉林 吉林 132012

基金项目: 国家自然科学基金（51276034）。
详细信息
    通讯作者:

    王擎（1964-），男，博士，教授，E-mail：rlx888@126.com

  • 中图分类号: TK16

Characterization of oil shales by 13C-NMR and the simulation of pyrolysis by FLASHCHAIN

  • Engineering Research Centre of Oil Shale Comprehensive Utilization of Ministry of Education, Northeast Dianli University, Jilin 132012, China

    摘要
  • 摘要: 采用固体 13C-NMR核磁共振技术表征了甘肃窑街矿区油页岩的碳骨架结构，分析并计算了油母质团簇化学结构参数，包括团簇平均碳原子数、芳碳原子数、脂碳原子数及芳环数。在热重红外分析仪（TG-FTIR）上进行了油页岩的热解实验，得到了热解产物的生成规律。结合样品的团簇化学结构参数，采用基于油页岩结构的FLASHCHAIN模型模拟其热解产物的生成过程；模拟结果与TG-FITR实验数据符合较好，印证了模型预测的合理性。
    Abstract: The carbon skeleton structure of oil shales from Gansu Yaojie mine was characterized by the 13C solid-state NMR; the chemical structure parameters of cluster in the oil shales, such as average number of carbons, aromatic carbons, aliphatic carbons and aromatic rings, were determined. TG-FTIR tests were used to obtain the yields of pyrolysis products. Considering the cluster chemical structure parameters determined by 13C solid-state NMR, the release of pyrolysis products was simulated by FLASHCHAIN. The simulation results are in good agreement with the TG-FTIR tests, proving the rationality of the model proposed.
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    • 参考文献(24)
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出版历程
  • 收稿日期:  2013-09-17
  • 修回日期:  2013-12-01
  • 刊出日期:  2014-03-31

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