由不同镍盐前体制备高分散Ni/SBA-15催化剂：活化氛围的影响

任世彪; 沈周; 张萍; 王知彩; 雷智平; 潘春秀; 康士刚; 水恒福

由不同镍盐前体制备高分散Ni/SBA-15催化剂：活化氛围的影响

安徽工业大学化学与化工学院安徽省煤洁净转化与利用重点实验室, 安徽马鞍山 243002

基金项目: Supported by the National Natural Science Foundation of China (U1361125, U1261208, 21176001, 51174254); the Provincial Innovative Group for Processing & Clean Utilization of Coal Resource; the Innovative Research Team of Anhui University of Technology.

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中图分类号: O643.3
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出版历程
- 收稿日期: 2013-12-16
- 修回日期: 2014-02-25
- 刊出日期: 2014-05-30

Highly dispersed Ni/SBA-15 catalysts prepared with different nickel salts as nickel precursors：Effects of activation atmospheres

School of Chemistry and Chemical Engineering, Anhui Key Laboratory of Clean Coal Conversion and Utilization, Anhui University of Technology, Ma'anshan 243002, China

Funds: Supported by the National Natural Science Foundation of China (U1361125, U1261208, 21176001, 51174254); the Provincial Innovative Group for Processing & Clean Utilization of Coal Resource; the Innovative Research Team of Anhui University of Technology.

摘要

摘要: 以硝酸镍和乙酸镍为镍前体，用浸渍法分别在空气和氢气氛围活化制得系列Ni/SBA-15催化剂，通过XRD、H₂-TPD、N₂物理吸附和在线质谱等物理化学手段对催化剂进行了表征，并结合微型高压反应釜萘加氢反应，评价了催化剂的加氢性能。结果表明，氢气氛围活化对硝酸镍为镍前体所制Ni/SBA-15催化剂的镍分散度和活性有显著促进作用，而空气氛围活化对乙酸镍为镍前体所制催化剂有明显促进作用。根据催化剂前体在不同氛围活化时的热分解产物，提出了活化氛围对不同镍前体制得Ni/SBA-15催化剂所产生的作用机理。
- Ni/SBA-15 /
- 硝酸镍 /
- 乙酸镍 /
- 活化氛围 /
- 分散度 /
- 萘加氢
Abstract: With nickel nitrate and nickel acetate as nickel precursors, a series of Ni/SBA-15 catalysts were prepared by using the impregnation method and activating in air or hydrogen atmosphere. The Ni/SBA-15 catalysts were characterized with XRD, H₂-TPD, N₂ physisorption and online mass spectroscopy. Their catalytic properties were evaluated with hydrogenation of naphthalene as a model reaction. It was shown that activation in hydrogen greatly increased the Ni dispersion and catalytic activity of Ni/SBA-15 prepared with nickel nitrate, while activation in air significantly improved the sample prepared with nickel acetate. In terms of the thermal decomposition products of the catalyst precursors activated in different atmospheres, the affecting mechanism of the activation atmosphere on the Ni/SBA-15 catalysts prepared with different nickel precursors was proposed.
- Ni/SBA-15 /
- nickel nitrate /
- nickel acetate /
- activation atmosphere /
- dispersion /
- hydrogenation of naphthalene

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