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Fe改性对Ru/Al2O3催化剂的马来酸二甲酯加氢性能影响

王磊,  努尔买买提·阿布都克力木,  马昱博,  庆绍军,  高志贤,  吾满江·艾力

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文章导航 > 燃料化学学报（中英文）  > 2014 >  42(07): 839-844
王磊, 努尔买买提·阿布都克力木, 马昱博, 庆绍军, 高志贤, 吾满江·艾力. Fe改性对Ru/Al2O3催化剂的马来酸二甲酯加氢性能影响[J]. 燃料化学学报（中英文）, 2014, 42(07): 839-844.
引用本文: 王磊, 努尔买买提·阿布都克力木, 马昱博, 庆绍军, 高志贤, 吾满江·艾力. Fe改性对Ru/Al2O3催化剂的马来酸二甲酯加氢性能影响[J]. 燃料化学学报（中英文）, 2014, 42(07): 839-844.
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WANG Lei, NUERMAIMAITI Abudukelimu, MA Yu-bo, QING Shao-jun, GAO Zhi-xian, WUMANJIANG Eli. Catalytic performance of Fe-modified Ru/Al2O3 in the hydrogenation of dimethyl maleate[J]. Journal of Fuel Chemistry and Technology, 2014, 42(07): 839-844.
Citation: WANG Lei, NUERMAIMAITI Abudukelimu, MA Yu-bo, QING Shao-jun, GAO Zhi-xian, WUMANJIANG Eli. Catalytic performance of Fe-modified Ru/Al2O3 in the hydrogenation of dimethyl maleate[J]. Journal of Fuel Chemistry and Technology, 2014, 42(07): 839-844.
shu

Fe改性对Ru/Al2O3催化剂的马来酸二甲酯加氢性能影响

  • 1.

    中国科学院新疆理化技术研究所, 新疆 乌鲁木齐 830011;

  • 2.

    中国科学院大学, 北京 100049;

  • 3.

    中国科学院 山西煤炭化学研究所, 山西 太原 030001

详细信息
    通讯作者:

    高志贤，研究员，主要研究方向：催化加氢，双环戊二烯高附加值利用。E-mail：gaozx@sxicc.ac.cn。

  • 中图分类号: O643.38

Catalytic performance of Fe-modified Ru/Al2O3 in the hydrogenation of dimethyl maleate

  • 1.

    Xinjiang Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Ulumqi 830011, China;

  • 2.

    University of Chinese Academy of Sciences, Beijing 100049, China;

  • 3.

    Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China

    摘要
  • 摘要: 以Al2O3为载体，采用吸附-沉淀法制备一系列Ru-Fe/Al2O3催化剂，并进行了H2-TPR、XRD及XPS表征。以马来酸二甲酯（DMM）催化加氢合成丁二酸二甲酯（DMS）为探针反应，考察了Fe的加入对Ru/Al2O3催化性能的影响。评价结果表明，当Fe/Ru原子比小于2时，催化剂活性变化不大；但Fe/Ru 原子比大于或等于2时，催化剂活性明显增加；与Ru/Al2O3催化剂相比，Fe的加入改善了催化剂的高温氧化还原处理稳定性。以甲醇为溶剂，在70℃、1.0 MPa压力、600 r/min转速下，Ru-Fe/Al2O3催化DMM的转化率与生成DMS的选择性均接近100%。XPS和H2-TPR表征结果表明，Ru-Fe/Al2O3中Fe与Ru产生较强的相互作用，促进Ru的分散且调变了Ru的电子特性。
    Abstract: Fe-modified Ru/Al2O3 (Ru-Fe/Al2O3) catalysts were prepared by adsorption-precipitation (AP) method with alumina as the support and characterized by H2-TPR, XRD and XPS; the effect of Fe modification on the catalytic performance of Ru-Fe/Al2O3 was investigated in the selective hydrogenation of dimethyl meleate (DMM) to dimethyl succinate (DMS). The results indicated that through the modification with a Fe/Ru atomic ratio above 2, the catalytic performance of Ru-Fe/Al2O3 and its stability towards high temperature oxidation-reduction treatment is obviously enhanced. Under 70℃, 1.0 MPa and with a stirring speed of 600 r/min, the conversion of DMM and the selectivity to DMS were both nearly 100%. The XPS and H2-TPR results suggest that the promoting effect of Fe on Ru-Fe/Al2O3 may be ascribed to an increase of Ru dispersion as well as a change in Ru electronic state through the modification with Fe.
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  • 收稿日期:  2013-12-30
  • 修回日期:  2014-03-27
  • 刊出日期:  2014-07-30

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