甲醇制备甲酸甲酯、甲缩醛和聚甲醛二甲醚的催化反应研究进展

武建兵; 吴志伟; 王瑞义; 师瑞萍; 秦张峰; 朱华青; 董梅; 樊卫斌; 王建国

甲醇制备甲酸甲酯、甲缩醛和聚甲醛二甲醚的催化反应研究进展

1.
中国科学院山西煤炭化学研究所煤转化国家重点实验室, 山西太原 030001;
2.
中国科学院大学, 北京 100049

基金项目: 国家自然科学基金(21227002, 21403268, 51302282, 21273264, 21203231); 国家重点基础研究发展规划(973计划, 2011CB201400)。

详细信息

通讯作者:
秦张峰, 王建国

中图分类号: O643;TQ519
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- 被引次数: 0
出版历程
- 收稿日期: 2015-04-10
- 修回日期: 2015-06-16
- 刊出日期: 2015-07-30

Recent research progresses in the catalytic synthesis of methyl formate, dimethoxymethane and polyoxymethylene dimethyl ethers from methanol

1.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China;
2.
University of Chinese Academy of Sciences, Beijing 100049, China

摘要

摘要: 由甲醇向下游衍生合成甲酸甲酯、甲缩醛和聚甲醛二甲醚等反应过程,不仅可以有效延伸甲醇产业链,消化业已形成的甲醇过剩产能,而且还可以带来巨大的经济和环境保护方面的效益,近年来受到研究者的广泛关注,与之相关的催化研究和开发也已取得长足的进步和发展。述评概述了近年来由甲醇出发制备甲酸甲酯、甲缩醛以及聚甲醛二甲醚等过程在催化剂制备和反应机理探索方面的研究进展,侧重介绍了贵金属催化剂上甲醇选择氧化制甲酸甲酯、钒基催化剂上甲醇选择氧化制甲缩醛以及分子筛催化剂上甲醇或甲缩醛与三聚甲醛合成聚甲醛二甲醚等催化反应过程。最后,对甲醇催化转化利用的未来发展方向进行了展望。
- 甲醇 /
- 甲酸甲酯 /
- 甲缩醛 /
- 聚甲醛二甲醚 /
- 贵金属催化剂 /
- 钒基催化剂 /
- 分子筛催化剂
Abstract: The synthesis of methyl formate (MF), dimethoxymethane (DMM) and polyoxymethylene dimethyl ethers (PODE_n) from methanol can not only extend the methanol industry chain and digest the large surplus production capacity of methanol, but also bring on enormous benefits in respects of economic development and environmental protection. As a result, it has attracted extensive attention in recent years and great progresses have also been made in the research and development of efficient catalysts and production processes. This paper attempts to make a review on the recent research progresses in the catalytic synthesis of MF, DMM and PODE_n from methanol, in the aspects of developing efficient catalysts and exploring the catalytic reaction mechanism. Especially, the review focuses on the selective oxidation of methanol to MF over noble metal catalysts, the selective oxidation of methanol to DMM over vanadium-based catalysts, and the synthesis of PODE_n from trioxymethylene (TOM) with methanol or DMM over acidic zeolite catalysts. Lastly, an outlook is given on the possible trends in the development of new efficient catalysts and processes to acquire methanol-down-stream products with high value.
- methanol /
- methyl formate /
- dimethoxymethane /
- polyoxymethylene dimethyl ethers /
- noble metal catalysts /
- vanadium-based catalysts /
- zeolite catalysts

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