生物质“热溶富碳”及其产物利用

李致煜; 郭柱; 李显; 胡振中; 易琳琳; 李建; 钟梅; 罗光前; 姚洪

doi:10.19906/j.cnki.JFCT.2022076

生物质“热溶富碳”及其产物利用

doi: 10.19906/j.cnki.JFCT.2022076

李致煜^1,,
郭柱¹,
李显^2, ,,
胡振中²,
易琳琳²,
李建¹,
钟梅^1, ,,
罗光前²,
姚洪²

1.
新疆大学化工学院省部共建碳基能源资源化学与利用国家重点实验室, 新疆煤炭清洁转化与化工过程重点实验室, 新疆乌鲁木齐 830000
2.
华中科技大学能源与动力工程学院煤燃烧国家重点实验室, 湖北武汉 430074

基金项目: 国家自然科学基金（22169019）和新疆维吾尔自治区区域协同创新专项（上海合作组织科技伙伴计划及国际科技合作计划）（2020E01018）

详细信息

通讯作者:
Tel：13396090358，13669931725，E-mail：xian_li@hust.edu.cn

zhongmei0504@126.com

中图分类号: TQ917
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出版历程
- 收稿日期: 2022-02-22
- 修回日期: 2022-05-20
- 录用日期: 2022-05-26
- 网络出版日期: 2022-10-17
- 刊出日期: 2023-01-18

" Thermal dissolution based carbon enrichment " of biomass waste and the product utilization

LI Zhi-yu^1
,,
GUO Zhu¹,
LI Xian^{2
, ,},
HU Zhen-zhong²,
YI Lin-lin²,
LI Jian¹,
ZHONG Mei^{1
, ,},
LUO Guang-qian²,
YAO Hong²

1.
State Key Laboratory of Chemistry and Utilization of Carbon-based Energy Resources, Key Laboratory of Coal Clean Conversion and Chemical Process Autonomous Region, College of Chemical Engineering, Xinjiang University, Urumqi 830000, China
2.
State Key Laboratory of Coal Combustion, School of Energy and Power Engineering, Huazhong University of Science and Technology, Wuhan 430074, China

Funds: The project was supported by the National Natural Science Foundation of China (22169019) and Xinjiang Uygur Autonomous Region Regional Collaborative Innovation Project (Shanghai Cooperation Organization Science and Technology Partnership Program and International Science and Technology Cooperation Program) (2020E01018)

摘要

摘要: 生物质“热溶富碳”（Thermal Dissolution based Carbon Enrichment, TDCE）是利用非/弱极性有机溶剂在温和条件（350 ℃、氮气氛围）下对木质纤维素类生物质废弃物进行热萃取，经过一系列脱氧和芳构化反应，获得的目标固体产物Soluble和Deposit具有无水、无灰、高热值等优点，同时该技术还具有溶剂不参与化学反应，可回收循环利用的优势。因此，热溶富碳是实现生物质能源转化的有效途径之一。本综述首先介绍了目前生物质利用的各类方式；然后重点综述了生物质热溶富碳影响因素、反应机理以及产物利用途径。在“碳中和”的国家战略背景下，生物质热溶富碳技术具有较明显的经济价值和社会意义。
- 生物质废弃物 /
- 热溶富碳 /
- 萃取物 /
- 炼焦黏结剂 /
- 两段液化 /
- 炭纤维
Abstract: "Thermal Dissolution based Carbon Enrichment" (TDCE) is the thermal extraction of lignocellulosic biomass wastes using non/weak polar organic solvents under mild conditions (350 °C, nitrogen atmosphere). After a series of deoxygenation and aromatization reactions, the obtained target solid products Soluble and Deposit have the advantages of anhydrous, ashless, high calorific value, etc. At the same time, this technology also has the advantages that the solvent does not participate in the chemical reaction and can be recycled and reused. Therefore, thermal solution carbon enrichment is one of the effective ways to realize biomass energy conversion. This paper firstly introduces various ways of biomass utilization at present; and then focuses on the factors affecting carbon-enrichment, reaction mechanism and product utilization pathways of biomass thermal solution. Under the background of the national strategy of "carbon neutrality", biomass thermal solution carbon-enriching technology has obvious economic value and social significance.
- biomass waste /
- thermal dissolution based carbon enrichment /
- extract /
- binder /
- two-stage liquefaction /
- carbon fiber

HTML全文

FIG. 2089. FIG. 2089.

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图 1 两段式间歇反应系统^[43]

Figure 1 Two-stage batch reaction system^[43]

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图 2 热溶富碳实验流程图^[43]

Figure 2 Flow chart of TDCE experiment^[43]

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图 3 连续热溶实验装置图^[48]

Figure 3 Diagram of the continuous hot melt experiment device^[48]

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图 4 神府煤与稻杆不同温度下共热溶的热溶率与热溶物产率实验值（TSY）与理论计算值（TDY）之差^[48]

Figure 4 Thermal dissolution rate of ShenFu coal and rice straw co-thermally dissolved at different temperatures between TSY and TDY^[48]

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图 5 煤和生物质热溶富碳处理中试系统流程图

Figure 5 Flow chart of pilot-scale system for TDCE of coal and biomass

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图 6 不同生物质热溶富碳产物分子量分布^[36]

Figure 6 Molecular weight distribution of TDCE products of different biomass^[36] (350 ℃，60 min)（with permission from ACS Publications）

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图 7 不同生物质热溶富碳产物的FT-IR谱图^[36]

Figure 7 FT-IR analysis of different biomass TDCE products^[36](with permission from ACS Publications)

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图 8 原料和Soluble热解特性(TGA)^[49]

Figure 8 Feedstock and Soluble pyrolysis characteristics (TGA)^[49]

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图 9 不同温度下稻杆和木屑Soluble(S)和Deposit(D)热解特性^[44]

Figure 9 Pyrolysis characteristics of rice straw and wood chips Soluble(S) and Deposit(D) at different temperatures^[44]

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图 10 热溶富碳与传统生物质热处理产物组成及特性比较^{[15, 19, 36, 50-55]}

Figure 10 Comparison of composition and properties of TDCE and traditional biomass thermal treatment products^{[15, 19, 36, 50-55]}

（Torr.: Torrefaction，HTL: Hydrothermal liquefaction，Slow-Pyr.: Slow pyrolysis， Fast-Pyr.: Fast pyrolysis）

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图 11 生物质热溶富碳与传统热处理固体产物的Van-Krevelen图^{[15, 19, 36, 50-55]}

Figure 11 Van-Krevelen diagram of biomass TDCE and traditional thermally treated solid products^{[15, 19, 36, 50-55]}

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图 12 基于BP-Adaboost法对原料特性与产物收率的相关性预测^[40]

Figure 12 Prediction of the correlation between raw material properties and product yield based on BP-Adaboost method^[40] (with permission from Elsevier)

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图 13 生物质热溶富碳溶剂循环路线示意图^[60]

Figure 13 Circulation route map of biomass TDCE solvent^[60] (with permission from ACS Publications)

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图 14 生物质热溶富碳反应机理示意图^[61]

Figure 14 Mechanism diagram of biomass TDCE reaction^[61] (with permission from Elsevier)

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图 15 300和350 ℃生物质热溶富碳反应路径模型^[62]

Figure 15 Biomass TDCE reaction path model at 300 and 350 ℃^[62] (with permission from ACS Publications)

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图 16 不同温度下稻杆和木屑Soluble(S)和Deposit(D)热塑性^[44]

Figure 16 Soluble(S) and Deposit(D) thermoplastics of rice straw and wood chips at different temperatures^[44]

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图 17 生物质热溶富碳产物用做炼焦黏结剂思路^[71]

Figure 17 Idea of using biomass TDCE products as coking binder^[71](with permission from Elsevier)

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图 18 生物质热溶富碳产物对焦炭品质的影响^[71]

Figure 18 Effect of biomass TDCE product on coke quality^[71](with permission from Elsevier)

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图 19 生物质热溶富碳-催化加氢液化/热解制备生物油路线示意图^{[73, 75]}

Figure 19 Biomass TDCE-catalytic hydroliquefaction/pyrolysis route map for bio-oil production^{[73, 75]}(with permission from ACS Publications)

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表 1 不同生物质原料的各产物产率^[36]

Table 1 Product yields of different biomass feedstocks^[36]

Sample	Yeild w_daf/%
Sample	soluble	deposit	residue	gas	liquid*
Cellulose	28.3	4.9	4.1	8.2	54.6
Hemicellulose	24.5	3.3	13.4	18.1	40.8
Lignin	20.7	1.5	49.0	10.6	18.2
Leucaena	36.9	3.8	12.3	17.0	29.4
Eucalyptus	45.0	5.2	8.8	11.9	29.1
Oil palm EFB	24.3	3.0	20.4	20.6	31.7
Rice straw	31.5	2.3	14.6	17.0	34.0
Rice husk	31.4	6.4	11.9	17.2	33.0
Napier grass	21.3	3.8	17.4	20.0	37.5
Jatropha trunk	23.6	3.0	19.0	18.0	36.5
Cassava rhizome	25.4	3.3	17.3	22.8	31.2
*: by difference

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表 2 热溶富碳-热解两段法与其他生物油制备技术比较^[75]

Table 2 Comparison of two-stage TDCE -pyrolysis method and other bio-oil preparation technologies^[75]

Technology	Mass yield^a /%	Mass yield /%	Oxygen content /%	Carbon-based yield^a /%	HHV /(MJ·kg⁻¹)	Energy yield^a /%	Catalyst
Direct biomass pyrolysis	35−65	20−30	35−40	~ 54	16−25	~ 53.5	no
Two-stage method (Rice straw)	11.7	<1	0.6	20.9	44.6	~ 32.6	no
Two-stage method (Sawdust)	23.7	<1	0.9	40.2	42.3	52.8	no
Catalytic pyrolysis	30−48	28.1−65	4.9−29.0	27−62	23.7−42.0	30−67	yes
Hydrodeoxygenation	12−35	4.3−58	16−40	20−38	16.0−37.9	23−42.7	yes
Pyrolysis after torrefaction	17−50	16.5−40	24−39	25−43.9	15.6−28.7	30−53	no
^a: On the basis of dry raw biomass

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生物质“热溶富碳”及其产物利用

doi: 10.19906/j.cnki.JFCT.2022076

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生物质“热溶富碳”及其产物利用

doi: 10.19906/j.cnki.JFCT.2022076

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