Volume 49 Issue 1
Jan.  2021
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Article Contents
ZHU Jun-sheng, DING Xiao-bo, CAO Jing-pei, ZHANG Shuang-quan, YUE Xiao-ming, HU Guang-zhou. Preparation of lignite-based porous carbon/CoNi2S4 composite materials and their capacitance performance[J]. Journal of Fuel Chemistry and Technology, 2021, 49(1): 20-26. doi: 10.1016/S1872-5813(21)60006-3
Citation: ZHU Jun-sheng, DING Xiao-bo, CAO Jing-pei, ZHANG Shuang-quan, YUE Xiao-ming, HU Guang-zhou. Preparation of lignite-based porous carbon/CoNi2S4 composite materials and their capacitance performance[J]. Journal of Fuel Chemistry and Technology, 2021, 49(1): 20-26. doi: 10.1016/S1872-5813(21)60006-3

Preparation of lignite-based porous carbon/CoNi2S4 composite materials and their capacitance performance

doi: 10.1016/S1872-5813(21)60006-3
Funds:  The project was supported by the Science and Technology Projects of Xuzhou City, China (KC19054)
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  • Corresponding author: E-mail: zhujschina@163.com
  • Received Date: 2020-08-02
  • Rev Recd Date: 2020-10-07
  • Publish Date: 2021-01-29
  • A lignite-based porous carbon was prepared by KOH solution extraction and subsequently by an activation of the extractant with Baoqing lignite as the raw material, and the composite capacitive materials combining the porous carbon with CoNi2S4 were fabricated by a facile hydrothermal method. The effect of different carbon material ratios on the electrochemical performance of lignite-based porous carbon/CoNi2S4 composites was investigated. The results indicate that too high or too low carbon content is not conducive to an improvement in the specific capacitance of the composites, while the lignite-based porous carbon/CoNi2S4 composites with 37% of carbon have higher specific capacitance and better cycling performance. The specific capacitance of the composites is as high as 1318.2 F/g at a current density of 4 A/g, and the capacitance retention is 80.9% after 4000 cycles.
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  • [1]
    SARAVANAKUMAR T, SELVARAJU T, BHOJANAA KB, RAMESH M, PANDIKUMAR A, AKILAN R, SHANKAR R, BASH SJ S. Exploring the synergistic effect of NixSn2xS4x thiospinel with MWCNTs for enhanced performance in dye-sensitized solar cells, the hydrogen evolution reaction, and supercapacitors[J]. Dalton Trans,2020,49:5336−5351. doi: 10.1039/D0DT00839G
    [2]
    AUGUSTYN V, SIMON P, DUNN B. Pseudocapacitive oxide materials for high-rate electrochemical energy storage[J]. Energy Environ Sci,2014,7(5):1597−1614. doi: 10.1039/c3ee44164d
    [3]
    CHEN L, LIAN C, JIANG H, CHEN L, YAN J, LIU H, LI C. Dual-conductive N,S co-doped carbon nanoflowers for high-loading quasi-solid-state supercapacitor[J]. Chem Eng Sci,2020,217:115496. doi: 10.1016/j.ces.2020.115496
    [4]
    DING X, ZHU J, HU G, ZHANG S. Core-shell structured CoNi2S4@polydopamine nanocomposites as advanced electrode materials for supercapacitors[J]. Ionics,2019,25(2):897−901. doi: 10.1007/s11581-018-2798-6
    [5]
    DU W, ZHU Z, WANG Y, LIU J, YANG W, QIAN X, PANG H. One-step synthesis of CoNi2S4 nanoparticles for supercapacitor electrodes[J]. RSC Adv,2014,4(14):6998−7002. doi: 10.1039/c3ra46805d
    [6]
    GAO R, ZHANG Q, SOYEKWO F, LIN C, LV R, QU Y, CHEN M, ZHU A, LIU Q. Novel amorphous nickel sulfide@CoS double-shelled polyhedral nanocages for supercapacitor electrode materials with superior electrochemical properties[J]. Electrochim Acta,2017,237:94−101. doi: 10.1016/j.electacta.2017.03.214
    [7]
    YANG Y, ZHANG Y, ZHU C, XIE Y, LV L, CHEN W, HE Y, HU Z. Synthesis of ultrafine CoNi2S4 nanowire on carbon cloth as an efficient positive electrode material for high-performance hybrid supercapacitors[J]. J Alloy Compd,2020,823:153885. doi: 10.1016/j.jallcom.2020.153885
    [8]
    DU W, WANG Z, ZHU Z, HU S, ZHU X, SHI Y, PANG H, QIAN X. Facile synthesis and superior electrochemical performances of CoNi2S4/graphene nanocomposite suitable for supercapacitor electrodes[J]. J Mater Chem A,2014,2(25):9613−9619. doi: 10.1039/C4TA00414K
    [9]
    徐程, 郭超. 褐煤腐植酸的提取技术和应用研究[J]. 广州化工,2015,43(15):41−42. doi: 10.3969/j.issn.1001-9677.2015.15.017

    XU Cheng, GUO Chao. Study on extraction technology and application of humic acid from lignite[J]. Guangzhou Chem Ind,2015,43(15):41−42. doi: 10.3969/j.issn.1001-9677.2015.15.017
    [10]
    侯朝霞, 屈晨滢, 李建君. 基于超级电容器的多孔电极材料研究进展[J]. 功能材料,2020,51(2):2032−2038. doi: 10.3969/j.issn.1001-9731.2020.02.006

    HOU Zhao-xia, QU Chen-ying, LI Jian-jun. Research progress of porous electrode materials based on supercapacitors[J]. J Funct Mater,2020,51(2):2032−2038. doi: 10.3969/j.issn.1001-9731.2020.02.006
    [11]
    WU Y, CAO J, ZHAO X, HAO Z, ZHUANG Q, ZHU J, WANG X, WEI X. Preparation of porous carbons by hydrothermal carbonization and KOH activation of lignite and their performance for electric double layer capacitor[J]. Electrochim Acta,2017,252:397−407. doi: 10.1016/j.electacta.2017.08.176
    [12]
    XING B, GUO H, CHEN L, CHEN Z, ZHANG C, HUANG G, XIE W, YU J. Lignite-derived high surface area mesoporous activated carbons for electrochemical capacitors[J]. Fuel Process Technol,2015,138:734−742. doi: 10.1016/j.fuproc.2015.07.017
    [13]
    邢宝林, 黄光许, 谌伦建, 张传祥, 王力. 高品质低阶煤基活性炭的制备与表征[J]. 煤炭学报,2013,38:217−222.

    XING Bao-lin, HUANG Guang-xu, CHEN Lun-jian, ZHANG Chuan-xiang, WANG Li. Preparation and characterization of high quality low-rank coal based activated carbon[J]. J China Coal Soc,2013,38:217−222.
    [14]
    张高峰, 张治国, 高艳芳, 刘进荣. 煤基活性炭的制备及其作为超级电容器电极材料的研究[J]. 内蒙古工业大学学报,2014,33(4):273−277.

    ZHANG Gao-feng, ZHANG Zhi-guo, GAO Yan-fang, LIU Jin-rong. Preparation and research of coal-based active carbon as a supercapacitor electrode material[J]. J Inner Mongolia Univ Technol,2014,33(4):273−277.
    [15]
    周娴娴, 曲旋, 张荣, 毕继诚. 超临界水中煤基多孔碳孔隙形成过程的研究[J]. 燃料化学学报,2015,43(9):1025−1031. doi: 10.3969/j.issn.0253-2409.2015.09.001

    ZHOU Xian-xian, QU Xuan, ZHANG Rong, Bi Ji-cheng. Pore evolution of coal based porous carbon in supercritical water[J]. J Fuel Chem Technol,2015,43(9):1025−1031. doi: 10.3969/j.issn.0253-2409.2015.09.001
    [16]
    杨晓霞, 李博, 李文超, 李家乐, 廖语晨. 煤基多孔碳的制备及其对对硝基苯酚吸附性能的研究[J]. 延安大学学报(自然科学版),2020,39(2):49−52.

    YANG Xiao-xia, LI Bo, LI Wen-chao, LI Jia-le, LIAO Yu-chen. Preparation of coal-based porous carbon and its adsorption of p-nitrophenol[J]. J Yanan Univ (Nat Sci Ed),2020,39(2):49−52.
    [17]
    PATIL S J, KIM J H, LEE D W. Self-assembled Ni3S2//CoNi2S4 nanoarrays for ultra high-performance supercapacitor[J]. Chem Eng J,2017,322:498−509. doi: 10.1016/j.cej.2017.03.095
    [18]
    GAO Z, CHEN C, CHANG J, CHEN L, WANG P, WU D, XU F, GUO Y, JIANG K. Enhanced cycleability of faradic CoNi2S4 electrode by reduced graphene oxide coating for efficient asymmetric supercapacitor[J]. Electrochim Acta,2018,281:394−404. doi: 10.1016/j.electacta.2018.05.194
    [19]
    RAJESH J, PARK J, QUY V, KWON J, CHAE J, KANG S, KIM H, AHN K. Rambutan-like cobalt nickel sulfide (CoNi2S4) hierarchitecture for high-performance symmetric aqueous supercapacitors[J]. J Ind Eng Chem,2018,63:73−83. doi: 10.1016/j.jiec.2018.02.001
    [20]
    XU J, YANG Y, CHU H, TANG J, GE Y, SHEN J, YE M. Novel NiCo2S4@reduced graphene oxide@carbon nanotube nanocomposites for high performance supercapacitors[J]. RSC Adv,2016,6(102):100504−100510. doi: 10.1039/C6RA18732C
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