Preparation of Ni/SiO<sub>2</sub> by ammonia evaporation method for synthesis of 2-MTHF from 2-MF hydrogenation

WANG Ying-wen; ZHANG Ya-jing; WANG Kang-jun; TAN Li-mei; CHEN Shu-ying

doi:10.1016/S1872-5813(21)60007-5

Volume 49 Issue 1

Jan. 2021

Turn off MathJax

Article Contents

Article Navigation > Journal of Fuel Chemistry and Technology > 2021 > 49(1): 97-103

WANG Ying-wen, ZHANG Ya-jing, WANG Kang-jun, TAN Li-mei, CHEN Shu-ying. Preparation of Ni/SiO2 by ammonia evaporation method for synthesis of 2-MTHF from 2-MF hydrogenation[J]. Journal of Fuel Chemistry and Technology, 2021, 49(1): 97-103. doi: 10.1016/S1872-5813(21)60007-5

Citation:

WANG Ying-wen, ZHANG Ya-jing, WANG Kang-jun, TAN Li-mei, CHEN Shu-ying. Preparation of Ni/SiO₂ by ammonia evaporation method for synthesis of 2-MTHF from 2-MF hydrogenation[J]. Journal of Fuel Chemistry and Technology, 2021, 49(1): 97-103. doi: 10.1016/S1872-5813(21)60007-5

Citation:

PDF( 1339 KB)

Preparation of Ni/SiO₂ by ammonia evaporation method for synthesis of 2-MTHF from 2-MF hydrogenation

doi: 10.1016/S1872-5813(21)60007-5

College of Chemical Engineering, Shenyang University of Chemical Technology, Shenyang 110142, China

Funds: The project was supported by National Natural Science Foundation of Liaoning Province (2019-ZD-0077), Liaoning Revitalization Talents Program (XLYC1907029), Science Research Foundation of Education Department of Liaoning Province (LQ2020026, LZ2019003), and Liaoning Innovation Talents Program in University

Received Date: 2020-02-18
Rev Recd Date: 2020-11-11
Publish Date: 2021-01-29

Abstract

Abstract

The Ni/SiO₂ catalysts were prepared by ammonia evaporation method, with nickel nitrate as Ni source and silica sol as the SiO₂ source, for synthesis of 2-MTHF from 2-MF hydrogenation. The catalytic performance of catalysts prepared at different calcination temperatures were tested on a fixed-bed reactor. XRD, N₂ adsorption-desorption, H₂-TPR, NH₃-TPD, XPS and TG were employed to characterize the structure and surface properties of these catalysts. The effect of calcination temperature on the structure, surface property and catalytic performance of catalysts were investigated. The result indicated that all the catalysts had a phyllosilicate structure after calcination, and maintained the structure after reduction. Ni particles dispersed well with smaller size and strong metal support interaction showed high activity. The surface acidity of catalysts was influenced by the calcination temperature. The maximum catalytic activity and selectivity were obtained on the catalyst calcined by at 500 ℃, which exhibited a 2-MF conversion of 100% and the 2-MTHF selectivity of 93.5% at the optimized condition, due to smaller particle size and suitable surface acidity.
- 2-methylfuran,
- 2-methyltetrahydrofuran,
- ammonia evaporation,
- hydrogenation,
- Ni/SiO₂ catalysts

FullText(HTML)

References(25)

References

[1]	郭清泉, 陈焕钦. 乙酰丙酸及其衍生物的研究进展[J]. 精细石油化工,2003,20(3):45−48. doi: 10.3969/j.issn.1003-9384.2003.03.016 GUO Qing-quan, CHEN Huan-qin. Development on prepartion of levulinic acid and its derivatives[J]. Spec Petrochem,2003,20(3):45−48. doi: 10.3969/j.issn.1003-9384.2003.03.016
[2]	RAGAN J A, ENDE D J, BRENEK S J, EISENBEIS S A, SINGER R A, TICKNER D L, TEIXEIRA J J, VANDERPLAS B C, WESTONET N. Safe execution of a large-scale ozonolysis: Preparation of the bisulfite adduct of 2-hydroxyindan-2-carboxaldehyde and its utility in a reductive amination[J]. Org Process Res Dev,2003,7(2):155−160. doi: 10.1021/op0202235
[3]	YANG J, ZHENG H, ZHU Y, ZHAO G, ZHANG C, TENG B, XIANG H, LI Y. Effects of calcination temperature on performance of Cu-Zn-Al catalyst for synthesizing c-butyrolactone and 2-methylfuran through the coupling of dehydrogenation and hydrogenation[J]. Catal Commun,2004,5(9):505−510. doi: 10.1016/j.catcom.2004.06.005
[4]	辛炳炜, 曲立强, 孙昌俊. 2-甲基四氢呋喃的制备研究进展[J]. 山东化工,2003,32:13−15. XIN Bing-wei, QU Li-qiang, SUN Chang-jun. Progress on synthesis of Effect of 2-methytetrahydrofuran[J]. Shangdong Chem Ind,2003,32:13−15.
[5]	DONALD B D, DOROTHY Z D, JOHN J G. Cyclodehydration of 1, 4-butanediols by pentaethoxy-phosphorane[J]. J Org Chem,1984,49:2831−2832. doi: 10.1021/jo00189a044
[6]	SANEO J, FUKUMOTO T, NAKAO K. Cyclic ethers from lactones, Japan: 7333745 [P].
[7]	DONG F, ZHU Y, DING G. One-step conversion of furfural into 2-methyltetrahydrofuran under mild conditions[J]. Chem Sus Chem,2015,8(9):1534−1537. doi: 10.1002/cssc.201500178
[8]	MASAAKI Y, RYOZI H. Preparation of dihydropyran from furfural[J]. Kôgakuin Daigaku Kenkyû Hôkoku,1954,1:76.
[9]	PROSKURYAKOV V A, IVANOV P A, GENUSOV M L. Hydrogenation of furfural under pressure[J]. Trudy Leningrad Tekhnol Inst Im Lensoveta,1958,44:3−5.
[10]	李增杰, 黄玉辉, 朱明. Ni/Al₂O₃催化2-甲基呋喃加氢制2-甲基四氢呋喃性能的研究[J]. 燃料化学学报,2018,46(1):54−58. doi: 10.3969/j.issn.0253-2409.2018.01.007 LI Zeng-jie, HUANG Yu-hui, ZHU Ming. Catalytic performance of Ni/Al₂O₃ catalyst for hydrogenation of 2-methylfuran to 2-methyltetrahydrofuran[J]. J Fuel Chem Technol,2018,46(1):54−58. doi: 10.3969/j.issn.0253-2409.2018.01.007
[11]	DING F, ZHANG Y. Synthesis and catalytic performance of Ni/SiO₂ for hydrogenation of 2-methylfuran to 2-methyltetrahydrofuran[J]. J Nanomater,2015.
[12]	ASHOK J, KATHIRASER Y, ANG M L, KAWI S. Ni and/or Ni-Cu alloys supported over SiO₂ catalysts synthesized via phyllosilicate structures for steam reforming of biomass tar reaction[J]. Catal Sci & Technol,2015,5:4398−4409.
[13]	ZHANG H, GAO X, MA Y, HAN X, NIU L, BAI G. A highly dispersed and stable Ni/mSiO₂-AE nanocatalyst for benzoic acid hydrogenation[J]. Catal Sci Technol,2017,7:5993−5999.
[14]	THOMMES M, KANEKO K, NEIMARK A V. Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report)[J]. Pure Appl Chem,2015,87(9/10):1051−1069. doi: 10.1515/pac-2014-1117
[15]	CYCHOSZ K A, NICOLAS R G, MARTNEZ J G. Recent advances in the textural characterization of hierarchically structured nanoporous materials[J]. Chem Soc Rev,2017,46:389−414. doi: 10.1039/C6CS00391E
[16]	CHEN L, GUO P, QIAO M. Cu/SiO₂ catalysts prepared by the ammonia-evaporation method: Texture, structure, and catalytic performance in hydrogenation of dimethyl oxalate to ethylene glycol[J]. J Catal,2008,257(1):172−180. doi: 10.1016/j.jcat.2008.04.021
[17]	KONG X, ZHU Y, ZHENG H. Ni Nanoparticles Inlaid Nickel Phyllosilicate as a metal-acid bifunctional catalyst for low-temperature hydrogenolysis reactions[J]. ACS Catal,2015,5:5914−5920. doi: 10.1021/acscatal.5b01080
[18]	DONG F, DING G, ZHENG H. Highly dispersed Cu nanoparticles as an efficient catalyst for the synthesis of the biofuel 2-methylfuran[J]. Catal Sci Technol,2016,6:767−779. doi: 10.1039/C5CY00857C
[19]	LI Z, MO L, KATHIRASER Y. Yolk-Satellite-Shell structured Ni-Yolk@Ni@SiO₂ nanocomposite: Superb catalyst toward methane CO₂ reforming reaction[J]. ACS Catal,2014,4(5):1526−1536. doi: 10.1021/cs401027p
[20]	SUN K Q, MARCEAU E, CHE M. Evolution of nickel speciation during preparation of Ni-SiO₂ catalysts: Effect of the number of chelating ligands in [Ni(en)_x(H₂O)_6−2x]²⁺ precursor complexes[J]. Phys Chem Chem Phys,2006,8(14):1731−1738. doi: 10.1039/b513319j
[21]	ZHANG C, ZHU W, LI S. Sintering-resistant Ni-based reforming catalysts obtained via the nanoconfinement effect[J]. Chem Commun,2013,49:9383−9385. doi: 10.1039/c3cc43895c
[22]	BURATTIN P, CHE M, LOUIS C. Ni/SiO₂ Materials prepared by deposition-precipitation: Influence of the reduction conditions and mechanism of formation of metal particles[J]. J Phys Chem B,2000,104(45):10482−10489. doi: 10.1021/jp0003151
[23]	刘吉, 王东旭, 肖显斌. 焙烧温度对Ni/γ-Al₂O₃还原条件及催化甲苯水蒸气重整反应的影响[J]. 燃料化学学报,2014,42(10):1225−1232. doi: 10.3969/j.issn.0253-2409.2014.10.011 LIU Ji, WANG Dong-xu, XIAO Xian-bin. Effect of calcination temperature on Ni/γ-Al₂O₃ reduction and catalytic steam reforming of toluene[J]. J Fuel Chem Technol,2014,42(10):1225−1232. doi: 10.3969/j.issn.0253-2409.2014.10.011
[24]	GILKEY M J, PANAGIOTOPOULOU P, MIRONENKO A V, JENNESS G R, VALCHOS DG, XU B[J]. ACS Catal, 2015, 5: 3988-3994.
[25]	SELVAM P, VISWANNATHAN B, SRINIVASAN V. XPS studies of the surface properties of CaNi₅[J]. J Electron Spectrosc Relat Phemon,1989,49:203−211. doi: 10.1016/0368-2048(89)85009-1