Oxidation of 5-hydroxylmethylfurfural to 2, 5-furandicarboxylic acid catalyzed by magnetic MnO2-Fe3O4 composite oxides

LU Hong-zhu; BAI Ji-feng; YAN Fei; ZHANG Xin-yue; JIN Ying; WANG Jing-yun; CHEN Ping; ZHOU Ming-dong

doi:10.1016/S1872-5813(21)60020-8

Volume 49 Issue 3

Mar. 2021

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Article Navigation > Journal of Fuel Chemistry and Technology > 2021 > 49(3): 311-320

LU Hong-zhu, BAI Ji-feng, YAN Fei, ZHANG Xin-yue, JIN Ying, WANG Jing-yun, CHEN Ping, ZHOU Ming-dong. Oxidation of 5-hydroxylmethylfurfural to 2, 5-furandicarboxylic acid catalyzed by magnetic MnO2-Fe3O4 composite oxides[J]. Journal of Fuel Chemistry and Technology, 2021, 49(3): 311-320. doi: 10.1016/S1872-5813(21)60020-8

Citation:

LU Hong-zhu, BAI Ji-feng, YAN Fei, ZHANG Xin-yue, JIN Ying, WANG Jing-yun, CHEN Ping, ZHOU Ming-dong. Oxidation of 5-hydroxylmethylfurfural to 2, 5-furandicarboxylic acid catalyzed by magnetic MnO₂-Fe₃O₄ composite oxides[J]. Journal of Fuel Chemistry and Technology, 2021, 49(3): 311-320. doi: 10.1016/S1872-5813(21)60020-8

Citation:

LU Hong-zhu, BAI Ji-feng, YAN Fei, ZHANG Xin-yue, JIN Ying, WANG Jing-yun, CHEN Ping, ZHOU Ming-dong. Oxidation of 5-hydroxylmethylfurfural to 2, 5-furandicarboxylic acid catalyzed by magnetic MnO₂-Fe₃O₄ composite oxides[J]. Journal of Fuel Chemistry and Technology, 2021, 49(3): 311-320. doi: 10.1016/S1872-5813(21)60020-8

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Oxidation of 5-hydroxylmethylfurfural to 2, 5-furandicarboxylic acid catalyzed by magnetic MnO₂-Fe₃O₄ composite oxides

doi: 10.1016/S1872-5813(21)60020-8

1.
School of Petrochemical Technology, Liaoning Shihua University, Fushun 113001, China
2.
Liaoning Province Product Quality Supervision and Inspection Institute, Shenyang 110032, China

Funds: The project was supported by Liaoning Revitalization Talents Program (XLYC1902085), Natural Science Foundation of Liaoning Province (20170540590) and PetroChina Innovation Foundation (2018D-5007-0507).

Received Date: 2020-11-26
Rev Recd Date: 2020-12-18

Available Online: 2021-03-19

Publish Date: 2021-03-19

Abstract

Abstract

MnO₂ with different crystal structures was used to catalyze the oxidation reaction of 5-hydroxylmethylfurfural (HMF), and α-MnO₂ exhibited the highest catalytic activity. Magnetic MnO₂-Fe₃O₄ oxides were prepared by α-MnO₂and Fe₃O₄ and characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), X-ray photoelectron spectroscopy (XPS), temperature programmed desorption of NH₃/CO₂ (NH₃/CO₂-TPD) and Fourier transform infrared reflection spectra of pyridine adsorption (Py-FTIR). The results showed that the composite catalyst still maintained the basic structure of α-MnO₂and Fe₃O₄, whereas the number of active center Mn⁴⁺·O²⁻ion pair increased compared with α-MnO₂and Fe₃O₄, which significantly improved the catalytic activity on HMF oxidation reaction. The reaction conditions of HMF oxidation to 2,5-furandicarboxylic acid (FDCA) were optimized. The composite oxide Mn₈Fe₃O_x showed the best catalytic performance for HMF oxidation. HMF could be completely converted, with 76.9% of FDCA yield under the optimal conditions.
- 5-hydroxymethylfurfural,
- oxidation,
- magnetic MnO₂-Fe₃O₄ mixed oxides,
- 2,5-furanedioic acid

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References(38)

References

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