Study on catalytic performance of supported transition metal oxide catalyst for ozone decomposition

LU Jing-lin; WANG Sheng; ZHAO Kun; WANG Ting; NI Chang-jun; WANG Ming-zhe; WANG Shu-dong

doi:10.1016/S1872-5813(21)60044-0

Volume 49 Issue 7

Jul. 2021

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Article Navigation > Journal of Fuel Chemistry and Technology > 2021 > 49(7): 1014-1021

LU Jing-lin, WANG Sheng, ZHAO Kun, WANG Ting, NI Chang-jun, WANG Ming-zhe, WANG Shu-dong. Study on catalytic performance of supported transition metal oxide catalyst for ozone decomposition[J]. Journal of Fuel Chemistry and Technology, 2021, 49(7): 1014-1021. doi: 10.1016/S1872-5813(21)60044-0

Citation:

LU Jing-lin, WANG Sheng, ZHAO Kun, WANG Ting, NI Chang-jun, WANG Ming-zhe, WANG Shu-dong. Study on catalytic performance of supported transition metal oxide catalyst for ozone decomposition[J]. Journal of Fuel Chemistry and Technology, 2021, 49(7): 1014-1021. doi: 10.1016/S1872-5813(21)60044-0

Citation:

LU Jing-lin, WANG Sheng, ZHAO Kun, WANG Ting, NI Chang-jun, WANG Ming-zhe, WANG Shu-dong. Study on catalytic performance of supported transition metal oxide catalyst for ozone decomposition[J]. Journal of Fuel Chemistry and Technology, 2021, 49(7): 1014-1021. doi: 10.1016/S1872-5813(21)60044-0

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Study on catalytic performance of supported transition metal oxide catalyst for ozone decomposition

doi: 10.1016/S1872-5813(21)60044-0

LU Jing-lin^{1, 2
,},
WANG Sheng^{1
,
,},
ZHAO Kun^{1, 2},
WANG Ting^{1, 2},
NI Chang-jun¹,
WANG Ming-zhe¹,
WANG Shu-dong¹

1.
Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China

Funds: The project was supported by the National Natural Science Foundation of China (U20A20132), the National Key Research and Development Plan (2016YFC0204302) and the Innovation Research Fund Project of Dalian Institute of Physics (DICPI201937)

Received Date: 2020-12-18
Rev Recd Date: 2021-01-29

Available Online: 2021-03-30

Publish Date: 2021-07-15

Abstract

Abstract

In this paper, γ-Al₂O₃ supported nickel, manganese, cobalt, and other metal oxide catalysts were prepared by the impregnation method respectively, and its ozone catalytic decomposition performance was studied at 25 ℃ under a WHSV of 200000 mL/(g_cat·h). The results showed that 10% NiO/γ-Al₂O₃ catalyst demonstrates superior catalytic activity, and the ozone conversion rate is higher than 96% within 20 h. According to the characterizations of XRD, XPS, TEM, SEM-EDS and H₂-TPR, its excellent ozone may be attributed to the formation of NiAl₂O₄ spinel on the surface of NiO/γ-Al₂O₃ catalyst. Furthermore, the mechanism of ozone decomposition on different transition metal oxide catalysts is divergent. The related study sheds new light on the reaction mechanism of ozone catalytic decomposition over transition metal oxides such as nickel and manganese, it also provides the guidelines for the development of efficient ozone decomposition catalysts.
- ozone,
- catalytic decomposition,
- catalyst,
- metal oxide

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References(42)

References

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