Study on catalytic performance of Co-Ni-B/SBA-15 for hydroformylation of 1-octene

GUO Jing; FAN Su-bing; GAO Xin-hua; MA Qing-xiang; ZHANG Jian-li; ZHAO Tian-sheng

doi:10.1016/S1872-5813(21)60048-8

Volume 49 Issue 7

Jul. 2021

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Article Navigation > Journal of Fuel Chemistry and Technology > 2021 > 49(7): 945-951

GUO Jing, FAN Su-bing, GAO Xin-hua, MA Qing-xiang, ZHANG Jian-li, ZHAO Tian-sheng. Study on catalytic performance of Co-Ni-B/SBA-15 for hydroformylation of 1-octene[J]. Journal of Fuel Chemistry and Technology, 2021, 49(7): 945-951. doi: 10.1016/S1872-5813(21)60048-8

Citation:

GUO Jing, FAN Su-bing, GAO Xin-hua, MA Qing-xiang, ZHANG Jian-li, ZHAO Tian-sheng. Study on catalytic performance of Co-Ni-B/SBA-15 for hydroformylation of 1-octene[J]. Journal of Fuel Chemistry and Technology, 2021, 49(7): 945-951. doi: 10.1016/S1872-5813(21)60048-8

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Study on catalytic performance of Co-Ni-B/SBA-15 for hydroformylation of 1-octene

doi: 10.1016/S1872-5813(21)60048-8

State Key Laboratory of High-Efficiency Utilization of Coal and Green Chemical Engineering, College of Chemistry and Chemical Engineering, Ningxia University, Yinchuan 750021, China

Funds: The project was supported by the East-West Cooperation Project, Key R & D Plan of Ningxia (2017BY063)

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Corresponding author: Tel：0951-2062237, E-mail：zhaots@nxu.edu.cn.
Received Date: 2021-01-11
Rev Recd Date: 2021-02-01

Available Online: 2021-03-30

Publish Date: 2021-07-15

Abstract

Abstract

SBA-15 zeolite supported amorphous ternary Co-Ni-B was prepared by the ultrasonic-assisted impregnation method for catalyzing the hydroformylation of 1-octene to nonanal. Supporting on SBA-15 increased the dispersion of nano amorphous Co-Ni-B. The crystallization temperature of amorphous Co-Ni-B was elevated by 280 ℃ that improves the thermal stability of Co-Ni-B. Using Co-Ni-B/SBA-15 with Co loading of 17.22% and the ratio of n(Ni)/n(Co) of 0.157 and n(B)/n(Co + Ni) of 0.434, the conversion of 1-octene and the selectivity of nonanal reached 100% and 91.24%, respectively, in the hydroformylation reaction at 120 °C and 5 MPa. The selectivity of side-product was reduced by 1 time compared with that of Co-Ni-B. The Co-Ni-B/SBA-15 is stable after repeated used for 5 times.
- Co-Ni-B,
- SBA-15,
- 1-octene,
- hydroformylation,
- catalytic activity

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References(34)

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