Isomerization and hydroformylation of butenes under the catalysis of Rh-BIPHEPHOS

JIANG Wei-li; HE Li-mei; HUANG Bin; CHEN Ya-qi; ZHOU Guang-lin; ZHOU Hong-jun

doi:10.1016/S1872-5813(21)60126-3

Volume 49 Issue 8

Aug. 2021

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Article Navigation > Journal of Fuel Chemistry and Technology > 2021 > 49(8): 1173-1180

JIANG Wei-li, HE Li-mei, HUANG Bin, CHEN Ya-qi, ZHOU Guang-lin, ZHOU Hong-jun. Isomerization and hydroformylation of butenes under the catalysis of Rh-BIPHEPHOS[J]. Journal of Fuel Chemistry and Technology, 2021, 49(8): 1173-1180. doi: 10.1016/S1872-5813(21)60126-3

Citation:

JIANG Wei-li, HE Li-mei, HUANG Bin, CHEN Ya-qi, ZHOU Guang-lin, ZHOU Hong-jun. Isomerization and hydroformylation of butenes under the catalysis of Rh-BIPHEPHOS[J]. Journal of Fuel Chemistry and Technology, 2021, 49(8): 1173-1180. doi: 10.1016/S1872-5813(21)60126-3

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Isomerization and hydroformylation of butenes under the catalysis of Rh-BIPHEPHOS

doi: 10.1016/S1872-5813(21)60126-3

1.
College of New Energy and Materials, Beijing Key Laboratory of Biogas Upgrading Utilization, China University of Petroleum (Beijing), Beijing 102249, China
2.
BOE Technology Group Co., Ltd, Chengdu 610000, China

Funds: The project was supported by the Scientific Research and Technological Development Project of CNPC (LH-17-08-53-02) and the Strategic Cooperation Technology Projects of CNPC and CUPB (ZLZX2020-04).

More Information

Corresponding author: E-mail: zhouguanglin2@163.com
Received Date: 2021-01-27
Rev Recd Date: 2021-03-02

Available Online: 2021-06-29

Publish Date: 2021-08-31

Abstract

Abstract

The isomerization and hydroformylation of butene under the catalysis of Rh-BIPHEPHOS were investigated by varying the butene feed and reaction temperature. The results indicate that in the presence of syngas, with 1-butene as feed, more isomerization product (i.e. 2-butene) is detected in comparison with the hydroformylation products, whereas with 2-butene as the feed, the hydroformylation is superior to isomerization. Due to the equilibrium limit between 1-butene and 2-butene, the increase of temperature shows a great positive effect on the isomerization reaction. Furthermore, under the catalysis of Rh-BIPHEPHOS, more n-pentanal is always formed than i-pentanal, as the larger bite angle of BIPHEPHOS restricts the intermediate rearrangement in the formation of i-pentanal.
- hydroformylation,
- rhodium,
- catalysis,
- butene,
- pentanal,
- isomerization

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References(44)

References

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