Progress of selective ring-opening reaction of decalin

LIU Ya-jie; LIANG Zhen-hui; LIU Xing; YUAN Li-jing

doi:10.1016/S1872-5813(21)60186-X

Volume 50 Issue 5

May 2022

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Article Navigation > Journal of Fuel Chemistry and Technology > 2022 > 50(5): 576-582

LIU Ya-jie, LIANG Zhen-hui, LIU Xing, YUAN Li-jing. Progress of selective ring-opening reaction of decalin[J]. Journal of Fuel Chemistry and Technology, 2022, 50(5): 576-582. doi: 10.1016/S1872-5813(21)60186-X

Citation:

LIU Ya-jie, LIANG Zhen-hui, LIU Xing, YUAN Li-jing. Progress of selective ring-opening reaction of decalin[J]. Journal of Fuel Chemistry and Technology, 2022, 50(5): 576-582. doi: 10.1016/S1872-5813(21)60186-X

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Progress of selective ring-opening reaction of decalin

doi: 10.1016/S1872-5813(21)60186-X

LIU Ya-jie¹,
LIANG Zhen-hui^{2, 3},
LIU Xing^{2, 3},
YUAN Li-jing^{2
,
,}

1.
College of Chemistry and Chemical Engineering, Jinzhong University, Jinzhong 030619, China
2.
Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
3.
University of Chinese Academy of Sciences, Beijing 100049, China

Funds: The project was supported by the Shanxi Science and Technology Department (20201101012) and Shanxi Province Science Foundation for Yout (201901D211584).

Received Date: 2021-10-09
Accepted Date: 2021-12-07
Rev Recd Date: 2021-12-07

Available Online: 2021-12-20

Publish Date: 2022-05-24

Abstract

Abstract

As a typical saturated bicyclic compound, decalin is normally used as a probe molecule of saturated cycloalkanes for the mechanism study of selective ring-opening reaction during the hydrogenation of light cycle oil. In this review, the molecular structure and reaction characteristics of cis-decalin and trans-decalin are introduced. The mechanism of the selective ring-opening reaction of decalin based on different catalytic systems is systematically analyzed, including the carbocation mechanism on monofunctional acid catalysts, the hydrogenolysis reaction mechanism on monofunctional metal catalysts, and the bifunctional ring-opening reaction mechanism on acid-metal bifunctional catalysts. In addition, the effect of the process conditions, such as reaction temperature, support acidity and zeolite pore size, on the performance of selective ring-opening reaction of decalin are summarized. Finally, the shortcomings of current research are put forward, and the urgent and deserved research topics are proposed.
- decalin,
- catalyst,
- selective ring opening,
- reaction mechanism

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References(30)

References

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