Effects of metal doping on the catalytic performance of LaFe-based perovskites for CO<sub>2</sub> hydrogenation to light olefins

MA Li-hai; GAO Xin-hua; ZHANG Jian-li; MA Jing-jing; HU Xiu-de; GUO Qing-jie

doi:10.1016/S1872-5813(22)60063-X

Volume 51 Issue 1

Jan. 2023

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Article Navigation > Journal of Fuel Chemistry and Technology > 2023 > 51(1): 101-110

MA Li-hai, GAO Xin-hua, ZHANG Jian-li, MA Jing-jing, HU Xiu-de, GUO Qing-jie. Effects of metal doping on the catalytic performance of LaFe-based perovskites for CO2 hydrogenation to light olefins[J]. Journal of Fuel Chemistry and Technology, 2023, 51(1): 101-110. doi: 10.1016/S1872-5813(22)60063-X

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MA Li-hai, GAO Xin-hua, ZHANG Jian-li, MA Jing-jing, HU Xiu-de, GUO Qing-jie. Effects of metal doping on the catalytic performance of LaFe-based perovskites for CO₂ hydrogenation to light olefins[J]. Journal of Fuel Chemistry and Technology, 2023, 51(1): 101-110. doi: 10.1016/S1872-5813(22)60063-X

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Effects of metal doping on the catalytic performance of LaFe-based perovskites for CO₂ hydrogenation to light olefins

doi: 10.1016/S1872-5813(22)60063-X

1.
State Key Laboratory of High-effciency Utilization of Coal and Green Chemical Engineering, College of Chemistry & Chemical Engineering, Ningxia University, Yinchuan 750021, China

Funds: The project was supported by the Key Project of Natural Science Foundation of Ningxia (2022AAC02002) and the National Natural Science Foundation of China (U20A20124)

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Corresponding author: E-mail: zhangjl@nxu.edu.cn; qingjie_guo@163.com
Received Date: 2022-05-30
Accepted Date: 2022-07-31
Rev Recd Date: 2022-07-28

Available Online: 2022-10-18

Publish Date: 2023-01-10

Abstract

Abstract

The catalytic behavior of K/LaFeBO₃ (B =Cu, Zr, Al, Mn, Ni, and Zn) perovskite catalysts prepared by sol-gel and impregnation methods was investigated for CO₂ hydrogenation to light olefins. The structure of various catalysts was characterized in detail by SEM, XRD, N₂ adsorption-desorption, H₂-TPR, CO₂-TPD, TG, and XPS analysis. With the addition of Cu and Zn, the particles size decreased with high dispersion of Fe, while the exposed basic sites increased with lower hydrogen desorption temperature. The oxygen mobility in perovskites exhibited a considerable impact on catalytic activity and olefins selectivity, which considerably increased when Fe was substituted by Cu and Zn at the B site. Olefins were formed preferentially from oxygen species of the surface lattice with low binding energies (BEs). In addition, a faster diffusion rate of oxygen would lead to an enrichment of lattice oxygen species on the surface and increase the production of olefins.
- CO₂ hydrogenation,
- perovskite,
- LaFeBO₃ catalyst,
- oxygen mobility

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References(33)

References

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