Catalytic systems for the direct synthesis of dimethyl carbonate from carbon dioxide and methanol containing dehydrating agent, a review

CHENG Qing-yan; ZHANG Shuai; GU Yun-han; WANG Zhuo; WANG Jin-tao; LI Li; WANG Yan-ji; WANG Huan; QIAO Jin-dong

doi:10.1016/S1872-5813(23)60376-7

Volume 51 Issue 11

Nov. 2023

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Article Navigation > Journal of Fuel Chemistry and Technology > 2023 > 51(11): 1593-1616

CHENG Qing-yan, ZHANG Shuai, GU Yun-han, WANG Zhuo, WANG Jin-tao, LI Li, WANG Yan-ji, WANG Huan, QIAO Jin-dong. Catalytic systems for the direct synthesis of dimethyl carbonate from carbon dioxide and methanol containing dehydrating agent, a review[J]. Journal of Fuel Chemistry and Technology, 2023, 51(11): 1593-1616. doi: 10.1016/S1872-5813(23)60376-7

Citation:

CHENG Qing-yan, ZHANG Shuai, GU Yun-han, WANG Zhuo, WANG Jin-tao, LI Li, WANG Yan-ji, WANG Huan, QIAO Jin-dong. Catalytic systems for the direct synthesis of dimethyl carbonate from carbon dioxide and methanol containing dehydrating agent, a review[J]. Journal of Fuel Chemistry and Technology, 2023, 51(11): 1593-1616. doi: 10.1016/S1872-5813(23)60376-7

Citation:

CHENG Qing-yan, ZHANG Shuai, GU Yun-han, WANG Zhuo, WANG Jin-tao, LI Li, WANG Yan-ji, WANG Huan, QIAO Jin-dong. Catalytic systems for the direct synthesis of dimethyl carbonate from carbon dioxide and methanol containing dehydrating agent, a review[J]. Journal of Fuel Chemistry and Technology, 2023, 51(11): 1593-1616. doi: 10.1016/S1872-5813(23)60376-7

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Catalytic systems for the direct synthesis of dimethyl carbonate from carbon dioxide and methanol containing dehydrating agent, a review

doi: 10.1016/S1872-5813(23)60376-7

1.
Key Laboratory of Green Chemical Technology & High Efficient Energy Saving of Hebei Province, Tianjin Key Laboratory of Chemical Process Safety, Hebei University of Technology, Tianjin 300401, China
2.
HATCH R & D (Tianjin) Technology Co., Ltd, Tianjin 300392, China
3.
Tianjin Jiesiman Building Materials Co., Ltd, Tianjin 300382, China

Funds: The project was supported by the National Natural Science Foundation of China (U20A20152).

Received Date: 2023-04-13
Accepted Date: 2023-05-30
Rev Recd Date: 2023-05-29

Available Online: 2023-07-26

Publish Date: 2023-11-13

Abstract

Abstract

Dimethyl carbonate (DMC) is a widely used environment-friendly green chemical, and the direct synthesis of DMC from CO₂ and CH₃OH has become one of the research focuses on the clean conversion of CO₂ in recent years. The design of efficient and stable catalysts and reaction processes to promote the conversion of CO₂ is the key to realize the direct synthesis of DMC in industry. In this paper, the research progress of catalytic systems for the direct synthesis of DMC from CO₂ and CH₃OH is reviewed and the reaction mechanism of different types of catalysts is summarized, mainly including the ionic liquid catalyst, alkali metal carbonate catalyst, transition metal oxide catalyst, etc. The operation principle of various dehydrating agents and their promoting effect on the production of DMC are expounded, while the advantages and disadvantages of different catalytic-dehydration systems are analyzed. It is predicted that the development of efficient and stable catalysts and membrane materials with strong permeability to water as well as the construction and implementation of new dehydration processes will be the focus of future research on the direct synthesis of DMC from CO₂ and CH₃OH.
- carbon dioxide,
- methanol,
- dimethyl carbonate,
- catalysts,
- dehydrating agents

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References(94)

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