Ni supported on Ti-doped SBA-15 catalyst for the selective hydrodeoxygenation conversion of lignin derivatives

ZHANG Hongke; WANG Weichen; XIANG Zhiyu; ZHOU Fangyuan; ZHU Wanbin; WANG Hongliang

doi:10.1016/S1872-5813(23)60387-1

Volume 52 Issue 4

Apr. 2024

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Article Navigation > Journal of Fuel Chemistry and Technology > 2024 > 52(4): 536-544

ZHANG Hongke, WANG Weichen, XIANG Zhiyu, ZHOU Fangyuan, ZHU Wanbin, WANG Hongliang. Ni supported on Ti-doped SBA-15 catalyst for the selective hydrodeoxygenation conversion of lignin derivatives[J]. Journal of Fuel Chemistry and Technology, 2024, 52(4): 536-544. doi: 10.1016/S1872-5813(23)60387-1

Citation:

ZHANG Hongke, WANG Weichen, XIANG Zhiyu, ZHOU Fangyuan, ZHU Wanbin, WANG Hongliang. Ni supported on Ti-doped SBA-15 catalyst for the selective hydrodeoxygenation conversion of lignin derivatives[J]. Journal of Fuel Chemistry and Technology, 2024, 52(4): 536-544. doi: 10.1016/S1872-5813(23)60387-1

Citation:

ZHANG Hongke, WANG Weichen, XIANG Zhiyu, ZHOU Fangyuan, ZHU Wanbin, WANG Hongliang. Ni supported on Ti-doped SBA-15 catalyst for the selective hydrodeoxygenation conversion of lignin derivatives[J]. Journal of Fuel Chemistry and Technology, 2024, 52(4): 536-544. doi: 10.1016/S1872-5813(23)60387-1

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Ni supported on Ti-doped SBA-15 catalyst for the selective hydrodeoxygenation conversion of lignin derivatives

doi: 10.1016/S1872-5813(23)60387-1

Biomass Engineering Center, College of Agriculture, China Agricultural University, Beijing 100193, China

Funds: The project was supported by the National Key Research and Development Program (2018YFB1501500), the China Agricultural University Foundation 2115 Talent Training Program (1011-00109018), and the Beijing Modern Agricultural Industry Technology System Innovation Team BAIC08-2022.

Received Date: 2023-07-12
Accepted Date: 2023-09-13
Rev Recd Date: 2023-08-28

Available Online: 2023-11-10

Publish Date: 2024-04-03

Abstract

Abstract

The development of cost-effective and efficient catalysts plays a critical role in the selective hydrodeoxygenation of lignin derivatives for lignin valorization. Herein, we reported “metal-acid” bifunctional catalysts (Ni/Ti-SBA-15) consist of Ni nanoparticles highly dispersed on Ti doped SBA-15, which achieved 100% vanillin conversion and 96.46% selectivity of 2-methoxy-4-methylphenol (MMP) under mild conditions. Characterizations were employed to reveal the morphology and physicochemical properties of the catalysts. The results indicated that doping of Ti species not only increased the number of acidic sites but also promoted the high dispersion of Ni nanoparticles on the support. This research provides a novel concept for the synthesis of cost-effective and efficient catalysts, which contributes to the environmentally friendly and economical conversion of biomass derivatives.
- vanillin,
- hydrodeoxygenation,
- bifunctional catalyst,
- lignin

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References(22)

References

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