Effects of preparation methods on the performance of InZr/SAPO-34 composite catalysts for CO<sub>2</sub> hydrogenation to light olefins

GUO Shuai; FENG Likui; YU Zhiyong; XU Di; LIU Kaidi; SONG Xiaoning; CHENG Yijie; CAO Qiuyang; WANG Guanghui; DING Mingyue

doi:10.1016/S1872-5813(24)60433-0

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GUO Shuai, FENG Likui, YU Zhiyong, XU Di, LIU Kaidi, SONG Xiaoning, CHENG Yijie, CAO Qiuyang, WANG Guanghui, DING Mingyue. Effects of preparation methods on the performance of InZr/SAPO-34 composite catalysts for CO2 hydrogenation to light olefins[J]. Journal of Fuel Chemistry and Technology. doi: 10.1016/S1872-5813(24)60433-0

Citation:

GUO Shuai, FENG Likui, YU Zhiyong, XU Di, LIU Kaidi, SONG Xiaoning, CHENG Yijie, CAO Qiuyang, WANG Guanghui, DING Mingyue. Effects of preparation methods on the performance of InZr/SAPO-34 composite catalysts for CO₂ hydrogenation to light olefins[J]. Journal of Fuel Chemistry and Technology. doi: 10.1016/S1872-5813(24)60433-0

Citation:

GUO Shuai, FENG Likui, YU Zhiyong, XU Di, LIU Kaidi, SONG Xiaoning, CHENG Yijie, CAO Qiuyang, WANG Guanghui, DING Mingyue. Effects of preparation methods on the performance of InZr/SAPO-34 composite catalysts for CO₂ hydrogenation to light olefins[J]. Journal of Fuel Chemistry and Technology. doi: 10.1016/S1872-5813(24)60433-0

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Effects of preparation methods on the performance of InZr/SAPO-34 composite catalysts for CO₂ hydrogenation to light olefins

doi: 10.1016/S1872-5813(24)60433-0

GUO Shuai^{1, 2
,},
FENG Likui^2
,,
YU Zhiyong^{1, 2
,},
XU Di^{3
,
,},
LIU Kaidi^3
,,
SONG Xiaoning²,
CHENG Yijie^{1, 2
,},
CAO Qiuyang^2
,,
WANG Guanghui^1
,,
DING Mingyue^{3
,
,}

1.
E-energy Technology Co., LTD, Hangzhou 310014, China
2.
State Grid Zhejiang Electric Power Co., LTD. Research Institute, Hangzhou 310014, China
3.
School of Power and Mechanical Engineering, Wuhan University, Wuhan 430072, China

Funds: The project was supported by the School-Enterprise Cooperation Project “Study on catalyst and process for light olefins synthesis from carbon dioxide in flue gas of power plant”.

Received Date: 2023-12-05
Accepted Date: 2024-01-16
Rev Recd Date: 2024-01-07

Available Online: 2024-03-26

Abstract

Abstract

Light olefins are of great importance as chemical raw materials, and ethylene is a crucial symbol to evaluate the development level of petrochemical industry. Catalytic hydrogenation of CO₂ to light olefins is one of the most vital approaches to utilize CO₂with high added valued. InZr/SAPO-34 composite catalyst shows prominent potential in research and application because of their high light olefins selectivity and high stability in CO₂ hydrogenation. In this study, the effects of different preparation methods of InZr/SAPO-34 composite catalyst for CO₂ hydrogenation to light olefins were studied in depth. The catalyst prepared by co-precipitation method showed the highest catalytic activity, and the catalyst prepared by sol-gel-precipitation method showed the highest light olefins selectivity. The structure-activity relationship of InZr/SAPO-34 catalysts were revealed by various characterization methods.
- CO₂ hydrogenation,
- light olefins,
- InZr composite oxide,
- SAPO-34,
- structure-activity relationship

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References(33)

References

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