Preparation of NiPt/Ti<sub>2</sub>O<sub>3</sub> nanocatalyst and its catalytic performance for hydrogen production from hydrazine hydrate

ZHAO Rongqi; XU Linlin; LIU Tong

doi:10.19906/j.cnki.JFCT.2023062

Volume 52 Issue 3

Mar. 2024

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Article Navigation > Journal of Fuel Chemistry and Technology > 2024 > 52(3): 421-428

ZHAO Rongqi, XU Linlin, LIU Tong. Preparation of NiPt/Ti2O3 nanocatalyst and its catalytic performance for hydrogen production from hydrazine hydrate[J]. Journal of Fuel Chemistry and Technology, 2024, 52(3): 421-428. doi: 10.19906/j.cnki.JFCT.2023062

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ZHAO Rongqi, XU Linlin, LIU Tong. Preparation of NiPt/Ti₂O₃ nanocatalyst and its catalytic performance for hydrogen production from hydrazine hydrate[J]. Journal of Fuel Chemistry and Technology, 2024, 52(3): 421-428. doi: 10.19906/j.cnki.JFCT.2023062

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Preparation of NiPt/Ti₂O₃ nanocatalyst and its catalytic performance for hydrogen production from hydrazine hydrate

doi: 10.19906/j.cnki.JFCT.2023062

ZHAO Rongqi^1
,,
XU Linlin^{2
,
,},
LIU Tong^{1
,
,}

1.
Qingdao University of Science and Technology, Qingdao 266000, China
2.
Qingdao Hengxing University of Science and Technology, Qingdao 266000, China

Funds: The project was supported by Shandong Provincial Natural Science Foundation (ZR2019QEM004).

Received Date: 2023-07-12
Accepted Date: 2023-08-12
Rev Recd Date: 2023-08-04

Available Online: 2023-09-18

Publish Date: 2024-03-10

Abstract

Abstract

Hydrazine hydrate is the most promising hydrogen storage material with a hydrogen content of 8.0%. In this paper, after Ti₂O₃ support was prepared by H₂ reduction, NiPt/Ti₂O₃ nanocatalyst was prepared by wet chemistry impregnation reduction method and used to catalyze hydrazine hydrate. The research shows that an alloy is formed between Ni and Pt during the preparation of the catalyst, and the formation of the alloy increases the catalytic activity of the catalyst. The interaction between Ti₂O₃ and NiPt alloy is helpful for the catalytic performance and cyclic stability of the catalyst. The TOF value of the Ni₅Pt₅/Ti₂O₃ catalyst for hydrogen production from hydrazine hydrate is 1076.1 h⁻¹, which is superior to the reported catalyst performance.
- hydrazine hydrate,
- hydrogen production through decomposition,
- NiPt,
- Ti₂O₃

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References(39)

References

[1]	YIN Y, LI B, YUAN Z M, et al. Enhanced hydrogen storage performance of Mg-Cu-Ni system catalyzed by CeO₂ additive[J]. J Rare Earths,2020,38(9):983−993. doi: 10.1016/j.jre.2019.07.010
[2]	XU X X, ZHOU Q, YU D H. The future of hydrogen energy: Bio-hydrogen production technology[J]. Int J Hydrogen Energy,2022,47(79):33677−33698. doi: 10.1016/j.ijhydene.2022.07.261
[3]	邹爱华, 徐晓梅, 周浪, 等. 石墨烯负载Co-CeOx纳米复合物的制备及其对氨硼烷水解产氢的催化性能[J]. 燃料化学学报,2021,49(9):1371−1378. doi: 10.1016/S1872-5813(21)60085-3 ZOU Aihua, XU Xiaomei, ZHOU Lang, et al. Preparation of graphene-supported Co-CeO_x nanocomposites as a catalyst for thehydrolytic dehydrogenation of ammonia borane[J]. J Fuel Chem Technol,2021,49(9):1371−1378. doi: 10.1016/S1872-5813(21)60085-3
[4]	ZHAO Y, SOTO LEYTAN K N, MCDONELL V, et al. Investigation of visible light emission from hydrogen-air research flames[J]. Int J Hydrogen Energy,2019,44(39):22347−22354. doi: 10.1016/j.ijhydene.2019.06.105
[5]	KARATAIRI E, SARTORI S. Reviving hydrogen as an energy carrier[J]. MRS Bull,2020,45(6):424−426. doi: 10.1557/mrs.2020.157
[6]	YANG K, YANG K K, ZHANG S L, et al. Complete dehydrogenation of hydrazine borane and hydrazine catalyzed by MIL-101 supported NiFePd nano-particles[J]. J Alloys Compd,2018,732:363−371. doi: 10.1016/j.jallcom.2017.10.241
[7]	周亮亮. Pt-Ni双金属催化剂的合成与催化水合肼分解制氢性能研究[D]. 广州: 华南理工大学, 2021 ZHOU Liangliang. Synthesis of Pt-Ni bimetallic catalysts and performance study of catalytic hydrogen production from hydrous hydrazine decomposition[D]. Guang zhou: South China University of Technology, 2021.
[8]	SINGH S K, ZHANG X B, XU Q. Room-temperature hydrogen generation from hydrous hydrazine for chemical hydrogen storage[J]. J Am Chem Soc,2009,131(29):9894−9895. doi: 10.1021/ja903869y
[9]	雍辉, 季燕全, 胡季帆,等. Mg-Y-Ni 储氢合金吸放氢动力学性能的研究[J]. 稀有金属,2022,46(8):1021−1030. YONG Hui, JI Yanquan, HU Jifan, et al. Absorption and desorption hydrogen kinetic of Mg-Y-Ni based hydrogen storage alloy[J]. Rare Metals,2022,46(8):1021−1030.
[10]	CHENG Y, WU X, XU H. Catalytic decomposition of hydrous hydrazine for hydrogen production[J]. Sustainable Energy Fuels,2019,3(2):343−365. doi: 10.1039/C8SE00538A
[11]	YAO Q, CHEN X, LU Z. Catalytic dehydrogenation of NH₃BH₃, N₂H₄, and N₂H₄BH₃ for chemical hydrogen storage[J]. Energy Environ Focus,2014,3(3):236−245. doi: 10.1166/eef.2014.1106
[12]	WAN C, SUN L, XU L X, et. al. Novel NiPt alloy nanoparticle decorated 2D layered g-C₃N₄nanosheets: A highly efficient catalyst for hydrogen generatio-n from hydrous hydrazine[J]. J Mater Chem A,2019,7(15):8798−8804. doi: 10.1039/C9TA01535C
[13]	JIANG Y Y, DAI H B, ZHONG Y J, et. al. Complete and rapid conversion of hydrazine monohydrate to hydrogen oversupported Ni-Pt nanoparticles on mesoporous ceria for chemical hydrogen storage[J]. Chem Eur J,2015,21(43):15439−15445. doi: 10.1002/chem.201502421
[14]	WANG J, LI W, WEN Y, et. al. Rh-Ni-B nanoparticles as highly efficient catalysts for hydrogen generation from hydrous hydrazine[J]. Adv Energy Mater,2015,5(10):1401879. doi: 10.1002/aenm.201401879
[15]	TUNÇ N, RAKAP M. Preparation and characterization of Ni-M (M: Ru, Rh, Pd) nanoclusters as efficient catalysts for hydrogen evolution from ammonia borane methanolysis[J]. Renewable Energy,2020,155:1222−1230. doi: 10.1016/j.renene.2020.04.079
[16]	MEN Y N, DU X Q, CHENG G Z, et al. CeO_x-modified NiFe nanodendrits grown on rGO for efficient catalytic hydrogen generation from alkaline soluti-on of hydrazine[J]. Int J Hydrogen Energy,2017,42(44):27165−27173. doi: 10.1016/j.ijhydene.2017.08.214
[17]	CHEN J M, ZOU H T, YAO Q L, et al. Cr₂O₃-modified NiFe nanoparticles as a noble-metal-free catalyst for complete dehydrogenation of hydrazine in a-queous solution[J]. Appl Surf Sci,2020,501:144247. doi: 10.1016/j.apsusc.2019.144247
[18]	HE L, HUANG Y Q, WANG A Q, et al. A noble metal-free catalyst derived from Ni-Al hydrotalcite for hydrogen generation from N₂H₄$H₂O decomposi-tion[J]. Angew Chem Int Ed,2012,51:6191−6194. doi: 10.1002/anie.201201737
[19]	HE L, HUANG Y Q, LIU X Y, et al. Structural and catalytic properties of supported Ni-Ir alloy catalysts for H₂ generation via hydrous hydrazine decom-position[J]. Appl Cata B: Environ,2014,147:779−788. doi: 10.1016/j.apcatb.2013.10.022
[20]	LIU T, YU J, BIE H, et al. Highly effificient hydrogen generation from hydrous hydrazine using a reduced graphene oxide-supported NiPtP nanoparticle c-atalyst[J]. J Alloys Compd,2017,690:783−790. doi: 10.1016/j.jallcom.2016.08.113
[21]	DAI H, DAI H B, ZHONG Y J, et al. Kinetics of catalytic decomposition of hydrous hydrazine over CeO₂-supported bimetallic Ni-Pt nanocatalysts[J]. Int J Hydrogen Energy,2017,42(9):5684−5693. doi: 10.1016/j.ijhydene.2016.10.160
[22]	ZHONG Y J, DAI H B, JIANG Y Y, et al. Highly effificient Ni@Ni-Pt/La₂O₃ catalyst for hydrogen generation from hydrous hydrazine decomposition: Effect of Ni-Pt surface alloying[J]. J Power Sources,2015,300:294−300. doi: 10.1016/j.jpowsour.2015.09.071
[23]	DAI H, ZHONG Y, WANG P. Hydrogen generation from decomposition of hydrous hydrazine over Ni-Ir/CeO₂ catalyst[J]. Prog Nat Sci Mater,2017,27(1):121−125.
[24]	WU D, WEN M, GU C, et al. 2D NiFe/CeO₂ basic-site-enhanced catalyst via in-situ topotactic reduction for selectively catalyzing the H₂ generation from N₂H₄·H₂O[J]. ACS Appl Mater,2017,9:16103−16108. doi: 10.1021/acsami.7b00652
[25]	QIU Y P, YIN H, DAI H, et al. Tuning the surface composition of Ni/meso-CeO₂ with iridium as an effificient catalyst for hydrogen generation from hydr-ous hydrazine[J]. Chem Eur J,2018,24:4902−4908. doi: 10.1002/chem.201705923
[26]	LANG C, JIA Y, YAO X, et al. Recent advances in liquid-phase chemical hydrogen storage[J]. Energy Storage Mater,2020,26:290−312.
[27]	QIU Y, ZHOU L, SHI Q, et al. Free-standing Pt-Ni nanowires catalyst for H2 generation from hydrous hydrazine[J]. Chem Commun,2021,57(5):623−626.
[28]	石张平, 祁晓岚, 李旭光, 等. La₂O₃助剂对Rh/SiO₂催化CO加氢反应性能的影响[J]. 燃料化学学报,2020,48(4):483−489. SHI Zhangping, QI Xiaolan, LI Xuguang, et al. Effect of La₂O₃ addition on the catalytic performance of Rh/SiO₂ for CO hydrogenation[J]. J Fuel Chem Technol,2020,48(4):483−489.
[29]	WU D, WEN M, LIN X, et al. A NiCo/NiO-CoO_x ultrathin layered catalyst with strong basic sites for high-performance H₂ generation from hydrous hydr-azine[J]. J Mater Chem A,2016,4(17):6595−6602. doi: 10.1039/C6TA01092J
[30]	WANG Q, GUAN S Y, LI B. 2D graphitic-C₃N₄ hybridized with 1D flux-grown Na-modified K₂Ti₆O₁₃ nanobelts for enhanced simulated sunlight and vi-sible-light photocatalytic performance[J]. Catal Sci Technol, 7(18): 4064–4078.
[31]	QING S, QIU Y P, DAI H, et al. Study of formation mechanism of Ni-Pt/CeO₂ catalyst for hydrogen generation from hydrous hydrazine[J]. Catal Sci Technol,2019,787:1187−1194.
[32]	LU R, HU M, XU C L, et al. Hydrogen evolution from hydrolysis of ammonia boranecatalyzed by Rh/g-C₃N₄ under mild conditions[J]. Int J Hydrogen Energy,2018,43(14):7038−7045. doi: 10.1016/j.ijhydene.2018.02.148
[33]	ALSAWAT M, ALTALHI T, SANTOS A, et al. Facile and controllable route for nitrogen doping of carbon nanotubes composite membranes by catalyst-free chemical vapour deposition[J]. Carbon,2016,106:295−305. doi: 10.1016/j.carbon.2016.05.043
[34]	MAJEED A, NOORI F M, ZEESHAN A, et al. Analysis of activation energy in magnetohydrodynamic flow with chemical reaction and second or-der momentum slip model[J]. Case Stud Therm Eng,2018,12:765−773. doi: 10.1016/j.csite.2018.10.007
[35]	LAHNEMAN D J, KIM H, JIANG H, et al. Electronic and optical properties of strain-locked metallic Ti₂O₃ films[J]. Curr Appl Phys, 2023, 47: 9−14.
[36]	DU X, DU C, CAI P, et al. NiPt nanocata-lysts supported on boron and nitrogen Co-doped graphene for superior hydrazine dehydrogenation and methanol oxidation[J]. ChemCatChem,2016,8(7):1410. doi: 10.1002/cctc.201501405
[37]	WANG C, WANG H L, GAO D W, et al. Amorphous NiCoPt/Ce₂O₃ nanoparticles as highly efficient catalyst for hydrogen generation from hydrous hyd-razine[J]. Mater Sci Forum,2017,898:1862. doi: 10.4028/www.scientific.net/MSF.898.1862
[38]	CHEN J M, LU Z H, HUANG W, et al. Galvanic replacement synthesis of NiPt/graphene as highly efficient catalysts for hydrogen release from hydrazin-e and hydrazine borane[J]. J Alloys Compd,2017,695:3036−3043. doi: 10.1016/j.jallcom.2016.11.351
[39]	SONG F Z, YANG X C, XU Q. Ultrafine bimetallic Pt-Ni nanoparticles achieved by metal-organic framework templated zirconia/porous carbon/reduced graphene oxide: Remarkable catalytic activity in dehydrogenation of hydrous hydrazine[J]. Small Methods,2020,4(1):1900707. doi: 10.1002/smtd.201900707