Preparation and properties of MnCu/Ce catalyst for CO preferential oxidation reaction

WU Jiaxin; HAN Jiao; LI Xue; XING Yue; ZHANG Caishun; LIU Daosheng; HOU Xiaoning; LIU Yajie; ZHANG Lei; GAO Zhixian

doi:10.19906/j.cnki.JFCT.2023080

Volume 52 Issue 4

Apr. 2024

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Article Navigation > Journal of Fuel Chemistry and Technology > 2024 > 52(4): 565-576

WU Jiaxin, HAN Jiao, LI Xue, XING Yue, ZHANG Caishun, LIU Daosheng, HOU Xiaoning, LIU Yajie, ZHANG Lei, GAO Zhixian. Preparation and properties of MnCu/Ce catalyst for CO preferential oxidation reaction[J]. Journal of Fuel Chemistry and Technology, 2024, 52(4): 565-576. doi: 10.19906/j.cnki.JFCT.2023080

Citation:

WU Jiaxin, HAN Jiao, LI Xue, XING Yue, ZHANG Caishun, LIU Daosheng, HOU Xiaoning, LIU Yajie, ZHANG Lei, GAO Zhixian. Preparation and properties of MnCu/Ce catalyst for CO preferential oxidation reaction[J]. Journal of Fuel Chemistry and Technology, 2024, 52(4): 565-576. doi: 10.19906/j.cnki.JFCT.2023080

Citation:

WU Jiaxin, HAN Jiao, LI Xue, XING Yue, ZHANG Caishun, LIU Daosheng, HOU Xiaoning, LIU Yajie, ZHANG Lei, GAO Zhixian. Preparation and properties of MnCu/Ce catalyst for CO preferential oxidation reaction[J]. Journal of Fuel Chemistry and Technology, 2024, 52(4): 565-576. doi: 10.19906/j.cnki.JFCT.2023080

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Preparation and properties of MnCu/Ce catalyst for CO preferential oxidation reaction

doi: 10.19906/j.cnki.JFCT.2023080

WU Jiaxin^1
,,
HAN Jiao^1
,,
LI Xue^2
,,
XING Yue^1
,,
ZHANG Caishun^1
,,
LIU Daosheng^1
,,
HOU Xiaoning^3
,,
LIU Yajie^4
,,
ZHANG Lei^{1
,
,},
GAO Zhixian^{1
,
,}

1.
School of Petrochemical Engineering, Liaoning Petrochemical University, Fushun 113001, China
2.
Petrochina Tianjin Gas Pipeline Co., LTD., Petrochina, Tianjin 300457, China
3.
School of Chemistry and Materials Science, Shanxi Normal University, Taiyuan 030032, China
4.
Department of Chemistry and Chemical Engineering, Jinzhong University, Jinzhong 030619, China

Funds: The project was supported by National Natural Science Foundation of China (22379059), Applied Basic Research Program Project of Liaoning Province (2023JH2/101300224), Service Local Project of the Education Department of Liaoning Province (Enlisting and Leading) (LJKFZ20220201), General Project of the Educational Department of Liaoning Province (LJKMZ20220728), Fundamental Research Program (Free Exploration) of Shanxi Province (20210302124338), Supported by Talent Scientific Research Fund of Liaoning Petrochemical University (2019-XJJL-028)

Received Date: 2023-08-22
Accepted Date: 2023-11-23
Rev Recd Date: 2023-11-23

Available Online: 2023-12-13

Publish Date: 2024-04-03

Abstract

Abstract

The MnCu/Ce catalyst with a lower Cu content was prepared by co-impregnation method, and then was characterized by XRD, BET, H₂-TPR, XPS and CO₂-TPD. The effects of calcination temperature on the structure and properties of the catalyst and the preferential oxidation of CO in a hydrogen-rich atmosphere containing CO₂ were investigated. The results indicated that Cu/Mn-O-Ce solid solution was formed in all MnCu/Ce catalysts. Of theses sample, the one calcined at 600 ℃ had strong interaction among Mn, Cu and Ce, formed more ternary oxide solid solution with more oxygen vacancies/Ce³⁺, and revealed good CO-Prox activity. In addition, it was found that the addition of different percentage of Ar had little effects on the CO-Prox activity of the catalyst, while the space velocity and oxygen excess coefficient had great effects on the catalytic performance, and the presence of CO₂ in the reaction feedstock gas had a negative effect on the CO-Prox reaction. At an oxygen excess coefficient of 1.2 and the space velocity of 20266−30400 mL/(g·h), the highest CO conversion rate reached 94.7%.
- low content copper,
- roasting temperature,
- cerium oxide,
- CO₂/H₂ atmosphere,
- reaction condition

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References(48)

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