Research on the 9,10-dihyroanthrancene assisted catalytic pyrolysis of pine over nitrogen-doped activated carbon for preparation of alkoxyphenols

LI Wentao; ZHANG Chengbo; LI Kai; NIU Qi; LI Jihong; LU Qiang; JIA Bao; GAO Lijuan

doi:10.19906/j.cnki.JFCT.2023081

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LI Wentao, ZHANG Chengbo, LI Kai, NIU Qi, LI Jihong, LU Qiang, JIA Bao, GAO Lijuan. Research on the 9,10-dihyroanthrancene assisted catalytic pyrolysis of pine over nitrogen-doped activated carbon for preparation of alkoxyphenols[J]. Journal of Fuel Chemistry and Technology. doi: 10.19906/j.cnki.JFCT.2023081

Citation:

LI Wentao, ZHANG Chengbo, LI Kai, NIU Qi, LI Jihong, LU Qiang, JIA Bao, GAO Lijuan. Research on the 9,10-dihyroanthrancene assisted catalytic pyrolysis of pine over nitrogen-doped activated carbon for preparation of alkoxyphenols[J]. Journal of Fuel Chemistry and Technology. doi: 10.19906/j.cnki.JFCT.2023081

Citation:

LI Wentao, ZHANG Chengbo, LI Kai, NIU Qi, LI Jihong, LU Qiang, JIA Bao, GAO Lijuan. Research on the 9,10-dihyroanthrancene assisted catalytic pyrolysis of pine over nitrogen-doped activated carbon for preparation of alkoxyphenols[J]. Journal of Fuel Chemistry and Technology. doi: 10.19906/j.cnki.JFCT.2023081

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Research on the 9,10-dihyroanthrancene assisted catalytic pyrolysis of pine over nitrogen-doped activated carbon for preparation of alkoxyphenols

doi: 10.19906/j.cnki.JFCT.2023081

LI Wentao^{1, 2
,},
ZHANG Chengbo^1
,,
LI Kai^{1
,
,},
NIU Qi^1
,,
LI Jihong^1
,,
LU Qiang^1
,,
JIA Bao^2
,,
GAO Lijuan^2
,

1.
National Engineering Research Center of New Energy Power Generation, North China Electric Power University, Beijing 102206, China
2.
Power China Northwest Engineering Corporation Limited, Xi'an 710065, China

Funds: The project was supported by the National Natural Science Foundation of China (52276188, 52276189), Technology Innovation Special Fund of Jiangsu Province for Carbon Dioxide Emission Peaking and Carbon Neutrality (BE2022307), Young Talent Project of Xi'an Talent Program (XAYCQN21002).

Received Date: 2023-10-11
Accepted Date: 2023-12-04
Rev Recd Date: 2023-12-03

Available Online: 2024-01-18

Abstract

Abstract

In this study, nitrogen-doped activated carbon (NAC) was prepared from walnut shell and applied to the catalytic pyrolysis of pine for selective preparation of alkoxyphenols with 9,10-dihyroanthrancene (DHA) as the hydrogen donor. The effects of ammonia concentration on the physicochemical properties of NAC were investigated. The regulatory functions of DHA/pine ratio, pyrolysis temperature, and NAC/pine ratio on the generation of alkoxyphenols were revealed. The results showed that the pore structure and active sites distribution of NAC could be improved by proper ammonia concentration. The NAC prepared at ammonia concentration of 15% was the best for the production of alkoxylphenols. The yield of alkoxylphenols reached its maximum value of 5.27% at DHA/pine ratio of 3, pyrolysis temperature of 550 ℃, and NAC/pine mass ratio of 3, which was much higher than that from catalytic pyrolysis of pure pine (1.74%).
- biomass,
- nitrogen-doped activated carbon,
- catalytic pyrolysis,
- 9,10-dihyroanthrancene,
- alkoxyphenols

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References(32)

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