Effect of Ce doping on the performance of MoSn catalyst in the selective oxidation of dimethyl ether to methyl formate

LI Ming-jie; GAO Xiu-juan; YANG Qi; FENG Ru; ZHANG Jun-feng; SONG Fa-en; ZHANG Qing-de; HAN Yi-zhuo; TAN Yi-sheng

Volume 48 Issue 10

Oct. 2020

Turn off MathJax

Article Contents

Article Navigation > Journal of Fuel Chemistry and Technology > 2020 > 48(10): 1248-1255

LI Ming-jie, GAO Xiu-juan, YANG Qi, FENG Ru, ZHANG Jun-feng, SONG Fa-en, ZHANG Qing-de, HAN Yi-zhuo, TAN Yi-sheng. Effect of Ce doping on the performance of MoSn catalyst in the selective oxidation of dimethyl ether to methyl formate[J]. Journal of Fuel Chemistry and Technology, 2020, 48(10): 1248-1255.

Citation:

LI Ming-jie, GAO Xiu-juan, YANG Qi, FENG Ru, ZHANG Jun-feng, SONG Fa-en, ZHANG Qing-de, HAN Yi-zhuo, TAN Yi-sheng. Effect of Ce doping on the performance of MoSn catalyst in the selective oxidation of dimethyl ether to methyl formate[J]. Journal of Fuel Chemistry and Technology, 2020, 48(10): 1248-1255.

Citation:

LI Ming-jie, GAO Xiu-juan, YANG Qi, FENG Ru, ZHANG Jun-feng, SONG Fa-en, ZHANG Qing-de, HAN Yi-zhuo, TAN Yi-sheng. Effect of Ce doping on the performance of MoSn catalyst in the selective oxidation of dimethyl ether to methyl formate[J]. Journal of Fuel Chemistry and Technology, 2020, 48(10): 1248-1255.

PDF( 7015 KB)

Effect of Ce doping on the performance of MoSn catalyst in the selective oxidation of dimethyl ether to methyl formate

LI Ming-jie^{1, 2},
GAO Xiu-juan^{1, 2},
YANG Qi^{1, 2},
FENG Ru^{1, 2},
ZHANG Jun-feng¹,
SONG Fa-en¹,
ZHANG Qing-de^{1, 3
,
,},
HAN Yi-zhuo¹,
TAN Yi-sheng¹

1.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China
3.
Dalian National Laboratory for Clean Energy, Dalian 116023, China

Funds:

The National Natural Science Foundation of China 21773283

The National Natural Science Foundation of China 21373253

CAS Interdisciplinary Innovation Team BK2018001

The Dalian National Laboratory For Clean Energy (DNL) Cooperation Fund, CAS DNL 201903

The Youth Innovation Promotion Association CAS 2014155

The Open Project Program of State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University 201624

More Information

Corresponding author: ZHANG Qing-de,Tel: +86-351-4044388, Fax: +86-351-4044287, E-mail:qdzhang@sxicc.ac.cn
Received Date: 2020-07-30
Rev Recd Date: 2020-09-08

Available Online: 2021-01-23

Publish Date: 2020-10-10

Abstract

Abstract

A series of MoSn catalysts doped with different Ce loadings were prepared by hydrothermal method and their catalytic performance in the selective oxidation of dimethyl ether (DME) to methyl formate (MF) was investigated. The results indicate that the introduction of 0.5% Ce can significantly improve the activity of the MoSn catalyst over the 0.5%Ce-MoSn catalyst, the conversion of DME reaches 11.8% at 130 ℃, with a selectivity of 92.2% for MF. The MoSn catalysts were characterized by nitrogen sorption, XRD, NH₃-TPD, CO₂-TPD, H₂-TPR, XPS and in situ-IR; the results illustrate that a small amount of Ce in the MoSn catalyst can obviously increase the quantity of Mo⁵⁺, though it has little effect on the structure of the MoSn catalyst.
- MoSn catalyst,
- dimethyl ether,
- selective oxidation,
- methyl formate,
- hydrothermal method

FullText(HTML)

References(25)

References

[1]	WANG D S, HAN Y Z, TAN Y S, TSUBAKI N. Effect of H₂O on Cu-based catalyst in one-step slurry phase dimethyl ether synthesis[J]. Fuel Process Technol, 2009, 90(3):446-451. doi: 10.1016/j.fuproc.2008.11.007
[2]	孙明, 余林, 孙长勇, 宋一兵, 孙健.二甲醚的应用及下游产品开发[J].精细化工, 2003, 20(11):695-699. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=jxhg200311017 SUN Ming, YU Lin, SUN Chang-yong, SONG Yi-bing, SUN Jian. Application of dimethyl ether and development of its downstream products[J]. Fine Chem, 2003, 20(11):695-699. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=jxhg200311017
[3]	黄秀敏, 徐奕德, 申文杰.负载型MoO_x和VO_x催化剂上二甲醚选择氧化制甲醛反应[J].催化学报, 2004, 25(4):267-271. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=cuihuaxb200404006 HUANG Xiu-min, XU yi-de, SHEN Wen-jie. Selective oxidation of dimethyl ether to formaldehyde over supported MoOx and VOx catalysts[J]. Chin J Catal, 2004, 25(4):267-271. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=cuihuaxb200404006
[4]	HUANG X M, LIU J L, CHEN J L, XU Y D, SHEN W J. Mechanistic study of selective oxidation of dimethyl ether to formaldehyde over Alumina-supported molybdenum oxide catalyst[J]. Catal Lett, 2006, 108(1/2):79-86. doi: 10.1007/s10562-006-0019-9
[5]	LIU H C, CHEUNG P, IGLESIA E. Structure and support effects on the selective oxidation of dimethyl ether to formaldehyde catalyzed by MoO_x domains[J]. J Catal, 2003, 217(1):222-232. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=180d6d3f82f0282854bdd2714ae015e2
[6]	LIU H C, IGLESIA E. Selective oxidation of dimethyl ether to formaldehyde on small molybdenum oxide domains[J]. J Catal, 2002, 208(1):1-5. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=7d22cf6c8d4e827a2925e781c26f5eeb
[7]	汪多仁.甲酸甲酯的生产发展与应用前景[J].石油与天然气化工, 1998, 27(3):149-151. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=QK199800540043 WANG Duo-ren. Production development and application prospects of methyl formate[J]. Chem Eng Oil Gas, 1998, 27(3):149-151. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=QK199800540043
[8]	周寿祖.甲酸甲酯的生产技术和应用前景[J].化工科技市场, 2003, 26(2):13-18. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=hgkjsc200302004 ZHOU Shou-zu. Production technology and application foreground of methyl formate[J]. Chem Technol Market, 2003, 26(2):13-18. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=hgkjsc200302004
[9]	李振香.浅谈甲醇羰基化合成甲酸甲酯[J].小氮肥设计技术, 2003, 24(1):60-62. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=xdfsjjs200301023 LI Zhen-xiang. Brief discussion on methanol carbonylation to synthesize methyl formate[J].Small Nitrogen Fert Des Technol, 2003, 24(1):60-62. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=xdfsjjs200301023
[10]	汪青松, 李国儒, 李工.研磨法和浸渍法制备Cu/SBA-15和Cu-ZnO/SBA-15及对甲醇脱氢制甲酸甲酯的催化性能[J].常州大学学报, 2014, 26(1):23-26. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=jssyhgxyxb201401006 WANG Qing-song, LI Guo-ru, LI Gong. Catalytic activity of methanol dehydrogenation to MF over Cu/SBA-15 and Cu-ZnO/SBA-15 prepared by grinding and impregnation[J]. J Changzhou Univ, 2014, 26(1):23-26. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=jssyhgxyxb201401006
[11]	TONNER S P, TRIMM D L, WAINWEIGHT M S, CANT N W. Dehydrogenation of methanol to methyl formate over copper-catalysts[J]. Ind Eng Chem Prod Res Dev, 1984, 23(3):384-388. doi: 10.1021/i300015a012
[12]	AI M. The production of methyl formate by the vapor-phase oxidation of methanol[J]. Chem Technol Market, 2003, 26(2):13-18. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=e3f3f3492468b3d76c12c7ba1bdb1945
[13]	AI M. The reaction of formaldehyde on various metal-oxide catalysts[J]. J Catal, 1982, 77(1):279-288. http://www.sciencedirect.com/science/article/pii/0021951783900374
[14]	刘广波, 张清德, 韩怡卓, 椿范立, 谭猗生. MoSn催化剂上二甲醚低温氧化高选择性制备甲酸甲酯[J].燃料化学学报, 2013, 41(2):223-227. http://www.ccspublishing.org.cn/article/id/11894 LIU Guang-bo, ZHANG Qing-de, HAN Yi-zhuo, TSUBAKI Noritatsu, TAN Yi-sheng. Low-temperature oxidation of dimethyl ether to methyl formate with high selectivity over MoSn catalysts[J]. J Fuel Chem Technol, 2013, 41(2):223-227. http://www.ccspublishing.org.cn/article/id/11894
[15]	LIU G B, ZHANG Q D, HAN Y Z, TSUBAKI N, TAN Y S. Selective oxidation of dimethyl ether to methyl formate over trifunctional MoSn catalyst under mild conditions[J]. Green Chem, 2013, 15(6):1501-1504. doi: 10.1039/c3gc40279g
[16]	LIU G B, ZHANG Q D, HAN Y Z, TSUBAKI N, TAN Y S. Effects of the MoO₃ structure of Mo-Sn catalysts on dimethyl ether oxidation to methyl formate under mild conditions[J]. Green Chem, 2015, 17(2):1057-1064. doi: 10.1039/C4GC01591F
[17]	ZHANG Z Z, ZHANG Q D, HAN Y Z, TSUBAKI N, TAN Y S. The effects of the Mo-Sn contact interface on the oxidation reaction of dimethyl ether to methyl formate at a low reaction temperature[J]. Catal Sci Technol, 2016, 6(15):6109-6117. doi: 10.1039/C6CY00460A
[18]	ZHANG Z Z, ZHANG Q D, HAN Y Z, TSUBAKI N, TAN Y S. Effect of MoO₃ crystalline structure of MoSn catalysts on selective oxidation of glycol dimethyl ether to 1, 2-propandiol[J]. 2016, 6(6):1842-1849.
[19]	ZHANG Z Z, ZHANG Q D, HAN Y Z, TSUBAKI N, TAN Y S. Effect of tetrahedral molybdenum oxide species and MoOx domains on the selective oxidation of dimethyl ether under mild condition[J]. Catal Sci Technol, 2016, 6(9):2975-2983. doi: 10.1039/C5CY01569C
[20]	杨奇, 高秀娟, 冯茹, 李明杰, 张俊峰, 张清德, 韩怡卓, 谭猗生.水热合成的MoSn催化剂催化氧化二甲醚的性能研究[J].燃料化学学报, 2019, 47(8):934-941. http://www.ccspublishing.org.cn/article/id/f54ec827-f8ff-45c8-9d34-ac36adcfacf3 YANG Qi, GAO Xiu-juan, FENG Ru, LI Ming-jie, ZHANG Jun-feng, ZHANG Qing-de, HAN Yi-zhuo, TAN Yi-sheng. MoSn catalyst prepared by hydrothermal synthesis method for dimethyl ether catalytic oxidation[J]. J Fuel Chem Technol, 2019, 47(8):934-941. http://www.ccspublishing.org.cn/article/id/f54ec827-f8ff-45c8-9d34-ac36adcfacf3
[21]	STAMPF S, CHEN Y, DUMESIC J A, HILL C G. Interactions of molybdenum oxide with various oxide supports:Calcination of mechanical mixtures[J]. J Catal, 1987, 105(2):445-454. http://www.sciencedirect.com/science/article/pii/0021951787900728
[22]	MENG Y L, WANG T, CHEN S, GONE J L. Selective oxidation of methanol to dimethoxymethane on V₂O₅-MoO₃/γ-Al₂O₃ catalysts[J]. Appl Catal B:Environ, 2014, 160-161(1):161-172. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=de3bc6bf39bb6c7cf988ad6f4ae76b0e
[23]	WHITING G T, KONDRAT S A, HAMMOND C, DIMITRATOS N, HUTCHINGS G J. Methyl formate formation from methanol oxidation using supported Gold-Palladium nanoparticles[J]. ACS Catal, 2015, 5(2):637-644. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=abc2df00fda2795c07bf97bc61991bc3
[24]	GONCALVES F, MEDEIROS P R S, EON J G, APPEL L G. Active sites for ethanol oxidation over SnO₂-supported molybdenum oxides[J]. Appl Catal A:Gen, 2000, 193(1/2):195-202. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=3e9f3819bf721b2b4608bb2ff36b370f
[25]	HABER J, LALIK E. Catalytic properties of MoO₃ revisited[J]. Catal Today, 1997, 33(1/3):119-137. http://www.sciencedirect.com/science/article/pii/S0920586196001071