Study on catalytic performance of Ni-Co-P amorphous alloy for HDO of vanillin

CHENG Qing-yan; LIU Dong-jie; WANG Ming-ming; WANG Yan-ji

Volume 47 Issue 10

Oct. 2019

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CHENG Qing-yan, LIU Dong-jie, WANG Ming-ming, WANG Yan-ji. Study on catalytic performance of Ni-Co-P amorphous alloy for HDO of vanillin[J]. Journal of Fuel Chemistry and Technology, 2019, 47(10): 1205-1213.

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CHENG Qing-yan, LIU Dong-jie, WANG Ming-ming, WANG Yan-ji. Study on catalytic performance of Ni-Co-P amorphous alloy for HDO of vanillin[J]. Journal of Fuel Chemistry and Technology, 2019, 47(10): 1205-1213.

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Study on catalytic performance of Ni-Co-P amorphous alloy for HDO of vanillin

Key Laboratory of Green Chemical Technology & High Efficient Energy Saving of Hebei Province, Tianjin Key Laboratory of Chemical Process Safety, Hebei University of Technology, Tianjin 300130, China

Funds:

the Natural Science Foundation of Hebei Province B2018202293

Received Date: 2019-06-18
Rev Recd Date: 2019-08-25

Available Online: 2021-01-23

Publish Date: 2019-10-10

Abstract

Abstract

The Ni-P amorphous alloy was synthesized by chemical reduction, modified by adding element Co, and characterized by XRD, SEM, XPS and DSC. The hydrodeoxygenation (HDO) performance of the amorphous alloy was investigated by hydrodeoxygenation of vanillin to 2-methoxy-4-methylphenol (MMP). It is shown that the synergy between Ni and Co not only contributes to the reduction of Ni, increases the number of active centers of the catalyst, but also improves the dispersion, disorder and thermal stability of the amorphous alloy. Under the optimized reaction conditions:n_Co/(n_Co + n_Ni)=0.08 (molar ratio), H₂ partial pressure of 2.0 MPa, reaction temperature of 150℃, reaction time of 180 min, catalyst dosage of 0.05 g, vanillin conversion and the MMP selectivity can reach 100% and 82.7%, respectively. After 5 cycles of the catalyst, the conversion of vanillin remains 100% and the selectivity of MMP decreases to 68.7%.
- vanillin,
- amorphous alloy,
- 2-methoxy-4-methylphenol,
- hydrodeoxygenation

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References(43)

References

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