Effect of alkaline earth metal doping on the catalytic performance of cobalt-based spinel composite metal oxides in N<sub>2</sub>O decomposition

LI Si-xuan; XIA Lei; LI Jing-yu; LIU Xiao-gang; SUN Jin-ru; WANG Hong; CHI Yao-ling; LI Cui-qing; SONG Yong-ji

Volume 46 Issue 11

Nov. 2018

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Article Navigation > Journal of Fuel Chemistry and Technology > 2018 > 46(11): 1377-1385

LI Si-xuan, XIA Lei, LI Jing-yu, LIU Xiao-gang, SUN Jin-ru, WANG Hong, CHI Yao-ling, LI Cui-qing, SONG Yong-ji. Effect of alkaline earth metal doping on the catalytic performance of cobalt-based spinel composite metal oxides in N2O decomposition[J]. Journal of Fuel Chemistry and Technology, 2018, 46(11): 1377-1385.

Citation:

LI Si-xuan, XIA Lei, LI Jing-yu, LIU Xiao-gang, SUN Jin-ru, WANG Hong, CHI Yao-ling, LI Cui-qing, SONG Yong-ji. Effect of alkaline earth metal doping on the catalytic performance of cobalt-based spinel composite metal oxides in N₂O decomposition[J]. Journal of Fuel Chemistry and Technology, 2018, 46(11): 1377-1385.

Citation:

LI Si-xuan, XIA Lei, LI Jing-yu, LIU Xiao-gang, SUN Jin-ru, WANG Hong, CHI Yao-ling, LI Cui-qing, SONG Yong-ji. Effect of alkaline earth metal doping on the catalytic performance of cobalt-based spinel composite metal oxides in N₂O decomposition[J]. Journal of Fuel Chemistry and Technology, 2018, 46(11): 1377-1385.

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Effect of alkaline earth metal doping on the catalytic performance of cobalt-based spinel composite metal oxides in N₂O decomposition

LI Si-xuan^{1, 2},
XIA Lei¹,
LI Jing-yu¹,
LIU Xiao-gang¹,
SUN Jin-ru^{1, 3},
WANG Hong^{1
,
,},
CHI Yao-ling^{1
,
,},
LI Cui-qing¹,
SONG Yong-ji¹

1.
College of Chemical Engineering, Beijing Institute of Petrochemical Technology/Beijing Key Laboratory of Fuels Cleaning and Advanced Catalytic Emission Reduction Technology, Beijing 102617, China
2.
College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China
3.
College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124, China

Funds:

the National Natural Science Foundation of China 21343009

the National Natural Science Foundation of China U1662103

the National Natural Science Foundation of China 2167329

the Beijing Key Laboratory of Fuels Cleaning and Advanced Catalytic Emission Reduction Technology BZ041420180007

the Beijing College Students Innovation and Entrepreneurship Training Program 2018J00035

Received Date: 2018-07-16
Rev Recd Date: 2018-08-23

Available Online: 2021-01-23

Publish Date: 2018-11-10

Abstract

Abstract

A series of cobalt-based spinel composite metal oxides doped with alkaline earth metals, viz., M_xCo_3-xO₄ (M=Mg, Ca, Sr and Ba; x=0, 0.1, 0.3, 0.5, 0.7 and 0.9), were prepared by the coprecipitation method and characterized by XRD, SEM, nitrogen sorption, H₂-TPR, O₂-TPD-MS and XPS; the effect of alkaline earth metal doping on the catalytic performance of M_xCo_3-xO₄ composites in N₂O decomposition was investigated in a fixed bed micro-reactor. The results showed that after doping with the alkaline earth metals, the particle size of M_xCo_3-xO₄ catalysts is decreased, accompanying with an increase in the specific surface area and the amount of surface adsorbed oxygen and Co²⁺ species. Meanwhile, the redox performance and catalytic activity of M_xCo_3-xO₄ in N₂O decomposition are also greatly enhanced. Under the conditions of 0.68% N₂O, 3% O₂ and Ar as balance gas, the Sr_0.7Co_2.3O₄ catalyst doped with Sr (x=0.7) exhibits highest activity in N₂O decomposition; the reaction temperatures where the N₂O conversion reaches 10% and 95% are as low as 312 and 451℃, respectively.
- catalytic decomposition,
- nitrous oxide,
- cobalt-based spinel,
- alkaline earth metal,
- doping,
- composite metal oxides

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References(38)

References

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