Ni-Sm/SiC catalysts prepared by hydrothermal method for carbon dioxide reforming of methane

WANG Bing; JIN Guo-qiang; WANG Ying-yong; GUO Xiang-yun

Volume 44 Issue 12

Dec. 2016

Turn off MathJax

Article Contents

Article Navigation > Journal of Fuel Chemistry and Technology > 2016 > 44(12): 1473-1478

WANG Bing, JIN Guo-qiang, WANG Ying-yong, GUO Xiang-yun. Ni-Sm/SiC catalysts prepared by hydrothermal method for carbon dioxide reforming of methane[J]. Journal of Fuel Chemistry and Technology, 2016, 44(12): 1473-1478.

Citation:

WANG Bing, JIN Guo-qiang, WANG Ying-yong, GUO Xiang-yun. Ni-Sm/SiC catalysts prepared by hydrothermal method for carbon dioxide reforming of methane[J]. Journal of Fuel Chemistry and Technology, 2016, 44(12): 1473-1478.

Citation:

PDF( 3474 KB)

Ni-Sm/SiC catalysts prepared by hydrothermal method for carbon dioxide reforming of methane

1.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China

Funds:

The project was supported by the Major State Basic Research Development Program of China 973计划，2011CB201405

the Key Science and Technology Projects of Shanxi Province 20131101035

More Information

Corresponding author: Tel/ Fax: 0351-4049306, gqjin@sxicc.ac.cn
Received Date: 2016-08-19
Rev Recd Date: 2016-09-29

Available Online: 2021-01-23

Publish Date: 2016-12-10

Abstract

Abstract

Ni-Sm/SiC (Ni:9%, Sm:5%) catalysts were prepared by a hydrothermal route for carbon dioxide reforming of methane. The catalysts were characterized by XRD, BET, ICP, H₂-TPR, TG-DTA and TEM. The catalytic performance, influence of different nickel precursors and carbon deposition in the CO₂ reforming of CH₄ were investigated. The results suggested that the Ni-Sm/SiC catalysts prepared by a hydrothermal route showed excellent catalytic activity, stability and good coke resistance. Different nickel precursors nearly had no impact on the performance of the catalysts.
- CO₂reforming of CH₄,
- Ni-Sm_x/SiC catalysts,
- hydrothermal method

FullText(HTML)

References(21)

References

[1]	SHARIFI M, HAGHIGHI M, ABDOLLAHIFAR M.Sono-dispersion of bimetallic Ni-Co over zeolite Y used in conversion of greenhouse gases CH₄/CO₂ to high valued syngas[J].J Nat Gas Sci E, 2015, 23:547-558. doi: 10.1016/j.jngse.2015.03.006
[2]	HUANG X, XUE G X, WANG C Z, ZHAO N, SUN N N, WEI W, SUN Y H.Highly stable mesoporous NiO-Y₂O₃-Al₂O₃ catalysts for CO₂ reforming of methane:Effect of Ni embedding and Y₂O₃ promotion[J].Catal Sci Technol, 2016, 6(2):449-459. doi: 10.1039/C5CY01171J
[3]	AMIN M H, MANTRI K, NEWNHAM J, TARDIO J, BHARGAVA S K.Highly stable ytterbium promoted Ni/gamma-Al₂O₃ catalysts for carbon dioxide reforming of methane[J].Appl Catal B:Environ, 2012, 119:217-226. https://www.researchgate.net/publication/262048724_Reforming_of_Methane_by_CO2_over_Bimetallic_Ni-Mngamma-Al2O3_Catalyst
[4]	LIU H T, LI S Q, ZHANG S B, WANG J M, ZHOU G J, CHEN L, WANG X L.Catalytic performance of novel Ni catalysts supported on SiC monolithic foam in carbon dioxide reforming of methane to synthesis gas[J].Catal Commun, 2008, 120(1/2):51-54. https://www.researchgate.net/publication/244319472_Catalytic_performance_of_novel_Ni_catalysts_supported_on_SiC_monolithic_foam_in_carbon_dioxide_reforming_of_methane_to_synthesis_gas
[5]	LI J F, XIA C, AU C T, LIU B S.Y₂O₃-promoted NiO/SBA-15 catalysts highly active for CO₂/CH₄ reforming[J].Int J Hydrogen Energy, 2014, 39(21):10927-10940. doi: 10.1016/j.ijhydene.2014.05.021
[6]	ZANGANEHA R, REZAEI M, ZAMANIYAN A.Dry reforming of methane to synthesis gas on NiO-MgO nanocrystalline solid solution catalysts[J].Int J Hydrogen Energy, 2013, 38(7):3012-3018. doi: 10.1016/j.ijhydene.2012.12.089
[7]	GARCÍA-VARGAS J M, VALVERDE J L, DÍEZ J, SÁNCHEZ P, DORADO F.Influence of alkaline and alkaline-earth cocations on the performance of Ni/β-SiC catalysts in the methane tri-reforming reaction[J].Appl Catal B:Environ, 2014, 148-149:322-329. https://www.researchgate.net/publication/260054031_Influence_of_alkaline_and_alkaline-earth_cocations_on_the_performance_of_Nib-SiC_catalysts_in_the_methane_tri-reforming_reaction
[8]	GUO X N, ZHI G J, YAN X Y, JING Q, GUO X Y, BRAULT P.Methane combustion over Pd/ZrO₂/SiC, Pd/CeO₂/SiC, and Pd/Zr_0.5Ce_0.5O₂/SiC catalysts[J].Catal Commun, 2011, 12(10):870-874. doi: 10.1016/j.catcom.2011.02.007
[9]	GUO P F, JIN G Q, GUO C X, WANG Y Y, TONG X L, GUO X Y.Effect of Yb₂O₃ promotor on the performance of Ni/SiC catalysts in CO₂ reforming of CH₄[J].J Fuel Chem Technol, 2014, 42(6):719-726. doi: 10.1016/S1872-5813(14)60033-5
[10]	YU Y, JIN G Q, WANG Y Y, GUO X Y.Synthesis of natural gas from CO methanation over SiC supported Ni-Co bimetallic catalysts[J].Catal Commun, 2013, 31:5-10. doi: 10.1016/j.catcom.2012.11.005
[11]	ZHI G J, GUO X N, WANG Y Y, JIN G Q, GUO X Y.Effect of La₂O₃ modification on the catalytic performance of Ni/SiC for methanation of carbon dioxide[J].Catal Commun, 2011, 16(1):56-59. doi: 10.1016/j.catcom.2011.08.037
[12]	WANG B, GUO C X, WANG Y Y, JIN G Q, GUO X Y.Performance of Ni-Sm_x/SiC for CO₂ reforming of CH₄[J].J Fuel Chem Technol, 2016, 44(5):587-596.
[13]	SINGHA R K, YADAV A, AGRAWAL A, SHUKLA A, ADAK S, SASAKI T, BAL R.Synthesis of highly coke resistant Ni nanoparticles supported MgO/ZnO catalyst for reforming of methane with carbon dioxide[J].Appl Catal B:Environ, 2016, 191:165-178. doi: 10.1016/j.apcatb.2016.03.029
[14]	ACHARYYA S S, GHOSH S, BAL R.Fabrication of Three-Dimensional (3D) raspberry-like copper chromite spinel catalyst in a facile hydrothermal route and its activity in selective hydroxylation of benzene to phenol[J].ACS Appl Mater Inter, 2014, 6(16):14451-14459. doi: 10.1021/am503722t
[15]	JIN G Q, GUO X Y.Synthesis and characterization of mesoporous silicon carbide[J].Microporous Mesoporous Mater, 2003, 60:207-212. doi: 10.1016/S1387-1811(03)00378-0
[16]	AW M S, ZORKO M, DJINOVC P, PINTAR A.Insights into durable NiCo catalysts onβ-SiC/CeZrO₂ and γ-Al₂O₃/CeZrO₂ advanced supports prepared from facile methods for CH₄-CO₂ dry reforming[J].Appl Catal B:Environ, 2015, 164:100-112. doi: 10.1016/j.apcatb.2014.09.012
[17]	JAHANGIRI A, PAHLAVANZADEH H, AGHABOZORG H.Synthesis, characterization and catalytic study of Sm doped LaNiO₃ nanoparticles in reforming of methane with CO₂ and O₂[J].Int J Hydrogen Energy, 2012, 37:9977-9984. doi: 10.1016/j.ijhydene.2012.03.128
[18]	ZHANG W D, LIU B S, ZHAN Y P, TIAN Y L.Syngas production via CO₂ reforming of of methane over Sm₂O₃-La₂O₃-supported Ni catalyst[J].Ind Eng Chem Res, 2009, 48:7498-7504. doi: 10.1021/ie9001298
[19]	LI J F, XIA C, AU C T, LIU S B.Y₂O₃-promoted NiO/SBA-15 catalystss highly active for CO₂/CH₄ reforming[J].Int J Hydrogen Energy, 2014, 39:10927-10940. doi: 10.1016/j.ijhydene.2014.05.021
[20]	YANG R Q, XING C, LV C G, SHI L, TSUBAK N.Promotional effect of La₂O₃ and CeO₂ on Ni/gamma-Al₂O₃ catalysts for CO₂ reforming of CH₄[J].Appl Catal A:Gen, 2010, 385:92-100. doi: 10.1016/j.apcata.2010.06.050
[21]	XIE S, GUO X N, JIN G Q, TONG X L, WANG Y Y, GUO X Y.In situ grafted carbon on sawtooth-like SiC supported Ni for high-performance supercapacitor electrodes[J].Chem Commun, 2014, 50:228-230. doi: 10.1039/C3CC47019A