Volume 40 Issue 02
Feb.  2012
Turn off MathJax
Article Contents
WANG Yong-wei, WANG Ze, SONG Wen-li, LIN Wei-gang. Experimental study of bio-oil gasification with steam[J]. Journal of Fuel Chemistry and Technology, 2012, 40(02): 170-176.
Citation: WANG Yong-wei, WANG Ze, SONG Wen-li, LIN Wei-gang. Experimental study of bio-oil gasification with steam[J]. Journal of Fuel Chemistry and Technology, 2012, 40(02): 170-176.

Experimental study of bio-oil gasification with steam

  • Received Date: 2011-03-19
  • Rev Recd Date: 2011-05-24
  • Publish Date: 2012-02-29
  • The experiment on the non-catalytic steam gasification of bio-oil was carried out in a lab-scale fixed bed reactor. The influence of operating parameters such as the temperature and the mol ratio of steam to carbon (S/C) on the gas yield and composition was investigated. The results show that increasing temperature can enhance the conversion of bio-oil to syngas; the carbon conversion of bio-oil can be as high as 97.8% at 1 200 ℃, and the proportion of effective gas component (H2+CO) in the product gas is nearly 77% with a mol ratio of H2/CO=1.19. The mol ratio of H2/CO increases with an increase of S/C mol ratio, and reaches up to 3.69 at S/C=4. However, the addition of steam does not favor the increase of the composition of effective syngas. The product gas from steam gasification has a medium heating value.
  • loading
  • 刘荣厚, 牛卫生, 张大雷. 生物质热化学转换技术[M]. 北京: 化学工业出版社, 2005. (LIU Rong-hou, NIU Wei-sheng, ZHANG Da-lei. Biomass thermo-conversion technology[M]. Beijing: Chemical Industry Press, 2005.)
    VENDERBOSCH R H, PRINS W. Fast pyrolysis technology development[J]. Biofuels, Bioprod Bioref, 2010, 4(2): 178-208.
    BRIDGWATER A V, PEACOCKE G V C. Fast pyrolysis processes for biomass[J]. Renewable Sustainable Energy Rev, 2000, 4(1): 1-73.
    姚建中, 陈洪章, 张均容, 李桂兰, 万宝春. 玉米秸秆快速热解研究[J]. 化工冶金, 2000, 21(4): 434-437. (YAO Jian-zhong, CHEN Hong-zhang, ZHANG Jun-rong, LI Gui-lan, WANG Bao-chun. Fast pyrolysis of corn straw[J]. Engineering Chemistry & Metallurgy, 2000, 21(4): 434-437.)
    朱锡锋, 郑冀鲁, 陆强, 郭庆祥, 朱清时. 生物质热解液化装置研制与试验研究[J]. 中国工程科学, 2006, 8(10): 89-93. (ZHU Xi-feng, ZHENG Ji-lu, LU Qiang, GUO Qing-xiang, ZHU Qing-shi. Development of biomass pyrolysis set and its experimental research[J]. Engineering Science, 2006, 8(10): 89-93.)
    CZERNIK S, BRIDGWATER A V. Overview of applications of biomass fast pyrolysis oil[J]. Energy Fuels, 2004, 18(2): 590-598.
    HENRICH E, DINJUS E. Tar-free, high pressure synthesis gas from biomass// Expert Meeting on Pyrolysis and Gasification of Biomass. Strasbourg, France: 30 Sept.-1 Oct, 2002.
    HENRICH E, WEIRICH F. Pressurized entrained flow gasifiers for biomass[J]. Environ Eng Sci, 2004, 21(1): 53-64.
    李理, 阴秀丽, 吴创之, 马隆龙, 周肇秋. 生物质热解油气化制备合成气的研究[J].可再生能源, 2007, 25(1): 40-43. (LI Li, YIN Xiu-li, WU Chuang-zhi, MA Long-long, ZHOU Zhao-qiu. Research on gasification of bio-oil for synthesis gas[J]. Renewable Energy, 2007, 25(1): 40-43.)
    朱锡锋, VENDERBOSCH R H. 生物质热解油气化试验研究[J]. 燃料化学学报, 2004, 32(4): 510-512. (ZHU Xi-feng, VENDERBOSCH R H. Experimental research on gasification of bio-oil derived from biomass pyrolysis[J]. Journal of Fuel Chemistry and Technology, 2004, 32(4): 510-512.)
    Van ROSSUM G, KERSTEN S R A, van SWAAIJ W P M. Catalytic and noncatalytic gasification of pyrolysis oil[J]. Ind Eng Chem Res, 2007, 46(12): 3959-3967.
    LI H, XU Q, XUE H, YAN Y. Catalytic reforming of the aqueous phase derived from fast pyrolysis of biomass[J]. Renewable Energy, 2009, 34(12): 2872-2877.
    WANG D, CZERNIK S, CHORNET E. Production of hydrogen from biomass by catalytic steam reforming of fast pyrolysis oils[J]. Energy Fuels, 1998, 12(1): 19-24.
    贺永德主编. 现代煤化工技术手册[M]. 北京: 化学工业出版社, 2003. (HE Yong-de. Handbook of modern coal engineering and technology[M]. Beijing: Chemical Industry Press, 2003.)
    FRANCO C, PINTO F, GULYURTLU I, CABRITA I. The study of reactions influencing the biomass steam gasification process[J]. Fuel, 2003, 82(7): 835-842.
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Article Metrics

    Article views (1390) PDF downloads(929) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return