Volume 40 Issue 02
Feb.  2012
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ZHANG Wei, ZHAO Zeng-li, ZHENG An-qing, CHANG Sheng, LI Hai-bin. Characterization and storage stability analysis of bio-oil[J]. Journal of Fuel Chemistry and Technology, 2012, 40(02): 184-189.
Citation: ZHANG Wei, ZHAO Zeng-li, ZHENG An-qing, CHANG Sheng, LI Hai-bin. Characterization and storage stability analysis of bio-oil[J]. Journal of Fuel Chemistry and Technology, 2012, 40(02): 184-189.

Characterization and storage stability analysis of bio-oil

  • Received Date: 2011-01-06
  • Rev Recd Date: 2011-05-23
  • Publish Date: 2012-02-29
  • A storage stability test was conducted on the bio-oil produced by fast pyrolysis of pine and corncob. The viscosity, water content and solids content of bio-oil increased after storage. However, there were no significant changes in the pH value, heating value and density of bio-oil. The quantitative analysis by GC/MS showed that the content of 1-hydroxy-2-propanone, acetic acid, and furfural were significant decreased. The content of 2-methoxy phenol, 4-methyl-2-methoxy-phenol, and 4-methyl-phenol increased. 13C NMR spectral analysis showed that the alkyl carbon and di-O-alkyl carbon content of bio-oil decreased after storage, while the content of aromatic and unsaturated carbon increased. Therefore, the aromaticity of bio-oil increased.
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  • BRIDGWATER A V, PEACOCKE G V C. Fast pyrolysis processes for biomass[J]. Renewable Sustainable Energy Rev, 2000, 4(1): 1-73.
    MOHAN D, PITTMAN C U, STEELE P H. Pyrolysis of wood/biomass for bio-oil: A critical review[J]. Energy Fuels, 2006, 20(3): 848-889.
    董芃, 齐国利, 王丽, 翟明. 生物质快速热解制取生物质油[J]. 太阳能学报, 2007, 28(2): 223-226. (DONG Peng, QI Guo-li, WANG Li, ZHAI Ming. Experiment study on producing biomass pyrolysis oil biomass flash pyrolysis[J]. Acta Energiae Solaris Sinica, 2007, 28(2): 223-226.)
    CZERNIK S, BRIDGWATER A V. Overview of applications of biomass fast pyrolysis oil[J]. Energy Fuels, 2004, 18(2): 590-598.
    YANIK J, KOMMAYER C, SAGLAM M, YVKSEL M. Fast pyrolysis of agricultural wastes: Characterization of pyrolysis products[J]. Fuel Process Technol, 2007, 88(10) : 942-947.
    王丽红, 贾官臣, 柏雪源, 易维明, 殷哲. 生物质热解生物油的成分分析[J]. 太阳能学报, 2009, 30(8): 1124-1128. (WANG Li-hong, JIA Guan-chen, BAI Xue-yuan, YI Wei-ming, YIN Zhe. Compositional analysis of bio-oil derived from pyrolysis of biomass[J]. Acta Energiae Solaris Sinica, 2009, 30(8): 1124-1128.)
    CZERNIK S, JOHNSON D K, BLACK S. Stability of wood fast pyrolysis oil[J]. Biomass Bioenergy, 1994, 7(1/6): 187-192.
    OASMAA A, KUOPPALA E. Fast pyrolysis of forestry residue: 3 Storage stability of liquid fuel[J]. Energy Fuels, 2003, 17(4): 1075-1084.
    BAYERBACH R, MEIER D. Characterization of the water-insoluble fraction from fast pyrolysis liquids (pyrolytic lignin): Part IV Structure elucidation of oligomeric molecules[J]. J Anal Appl Pyrolysis, 2009, 85(1/2): 98-107.
    BA T, CHAALA A, GARCIA-PEREZ M, ROY C. Colloidal properties of bio-oils obtained by vacuum pyrolysis of softwood bark. Storage stability[J]. Energy Fuels, 2004, 18(1): 188-201.
    CHAALA A, BA T, GARCIA-PEREZ M, Roy C. Colloidal properties of bio-oils obtained by vacuum pyrolysis of softwood bark: Aging and thermal stability[J]. Energy Fuels, 2004, 18(5): 1535-1542.
    DIEBOLD J P, CZERNIK S. Additives to lower and stabilize the viscosity of pyrolysis oils during storage[J]. Energy Fuels, 1997, 11(5): 1081-1091.
    OASMAA A, SIPLIA K, SOLANTAUSTA Y, KUOPPALA E. Quality improvement of pyrolysis liquid: Effect of light volatiles on the stability of pyrolysis liquids[J]. Energy Fuels, 2005, 19(6): 2556-2561.
    VENDERBOSCH R, ARDIYANTI A, WILDSCHUT J, OASMAA A, HEERES H J. Stabilization of biomass-derived pyrolysis oils[J]. J Chem Technol Biotechnol, 2010, 85(5): 674-686.
    DIEBOLD J P.A review of the chemical and physical mechanisms of the storage stability of fast pyrolysis bio-oils[M]. Golden,Colorado: National Renewable Energy Laboratory, 2000.
    FRATINI E, BONINI M, OASMAA A, SOLANTAUSTA Y, TEIXEIRA J, BAGLIONI P. SANS analysis of the microstructural evolution during the aging of pyrolysis oils from biomass[J]. Langmuir, 2006, 22(1): 306-312.
    常胜, 赵增立, 张伟, 郑安庆, 吴文强, 李海滨. 不同种类生物油化学组成结构的对比研究[J]. 燃料化学学报, 2011, 39(10): 746-753. (CHANG Sheng, ZHAO Zeng-li, ZHANG Wei, ZHENG An-qing, WU Wen-qiang, LI Hai-bin. Comparison of chemical composition and structure of different kinds of bio-oils[J]. Journal of Fuel Chemistry and Technology, 2011, 39(10): 746-753.
    OASMAA A, MEIER D. Norms and standards for fast pyrolysis liquids: 1 Round robin test[J]. J Anal Appl Pyrolysis, 2005, 73(2): 323-334.
    OASMAA A, PEACOCKE C. A guide to physical property characterisation of biomass-derived fast pyrolysis liquids[M]. Espoo: VTT Publications, 2001.
    FAHMI R, BRIDGWATER A, DONNISONI, YATES N, JONES J M. The effect of lignin and inorganic species in biomass on pyrolysis oil yields, quality and stability[J]. Fuel, 2008, 87(7): 1230-1240.
    SCHNITZER M I, MONREAL C M, FACEY G A, FRANSHAM P B. The conversion of chicken manure to biooil by fast pyrolysis: I Analyses of chicken manure, biooils and char by C-13 and H-1 NMR and FTIR spectrophotometry[J]. J Environ Sci Health Part B, 2007, 42(1): 71-77.
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