Volume 41 Issue 08
Aug.  2013
Turn off MathJax
Article Contents
JING Xu-liang, WANG Zhi-qing, YU Zhong-liang, FANG Yi-tian. Multi-circulated gasification reactivity of coal char and its microstructure analysis[J]. Journal of Fuel Chemistry and Technology, 2013, 41(08): 917-921.
Citation: JING Xu-liang, WANG Zhi-qing, YU Zhong-liang, FANG Yi-tian. Multi-circulated gasification reactivity of coal char and its microstructure analysis[J]. Journal of Fuel Chemistry and Technology, 2013, 41(08): 917-921.

Multi-circulated gasification reactivity of coal char and its microstructure analysis

  • Received Date: 2013-04-29
  • Rev Recd Date: 2013-06-17
  • Publish Date: 2013-08-30
  • To investigate the variation in gasification reactivity and microstructure of char from the multi-circulation fluidized bed gasifier, 3 chars from different rank coals were gasified in a simulated multi-circulated reactor (rapid heating-up fixed bed). The carbon conversion was calculated from the weight of residues, and the structure was analyzed by pore and XRD analyzer. The results show that with the increase of cycle time, the carbon conversion of low rank HLH lignite char increases while that of SM bituminous and JC anthracite chars decrease. The evolutions of BET surface area and micropore area have a peak value with the circulate time. The variation of graphitization is similar with the carbon conversion, which can be considered as the key factor to determine the carbon conversion.
  • loading
  • JING X L, WANG Z Q, YU Z L, ZHANG Q, LI C Y, FANG Y T. Experimental and kinetic investigations of CO2 gasification of fine chars separated from a pilot-scale fluidized-bed gasifier [J]. Energy Fuels, 2013, 27(5): 2422-2430.
    VÁRHEGYI G, SEBESTYN Z, CZGNY Z, LEZSOVITS F, KÖNCZÖL S. Combustion kinetics of biomass materials in the kinetic regime[J]. Energy Fuels, 2012, 26(2): 1323-1335.
    MONDAL P, DANG G S, GARG M O. Syngas production through gasification and cleanup for downstream applications-Recent developments[J]. Fuel Process Technol, 2011, 92(8): 1395-1410.
    REN H J, ZHANG Y Q, FANG Y T, WANG Y. Co-gasification behavior of meat and bone meal char and coal char[J]. Fuel Process Technol, 2011, 92(3), 298-307.
    张林仙, 黄戒介, 房倚天, 王洋. 中国无烟煤焦气化活性的研究—水蒸气与二氧化碳气化活性的比较[J]. 燃料化学学报, 2006, 34(3): 265-269. (ZHNAG Lin-xian, HUANG Jie-jie, FANG Yi-tian, WANG Yang. Study on reactivity of Chinese anthracite chars gasification—comparison of reactivity between steam and CO2 gasification[J]. Journal of Fuel Chemistry and Technology, 2006, 34(3): 265-269.)
    WU S Y, GU J, ZHANG X, WU Y Q, GAO J S. Variation of carbon crystalline structures and CO2 gasification reactivity of Shenfu coal chars at elevated temperatures[J]. Energy Fuels, 2008, 22(1): 199-206.
    OCHOA J, CASSANELLO M, BONELLI P, CUKIERMAN A. CO2 gasification of Argentinean coal chars: a kinetic characterization[J]. Fuel Process Technol, 2001, 74(3): 161-176.
    黄艳琴, 苏德仁, 阴秀丽, 吴创之, 马隆龙. 木粉焦CO2和H2O气化过程中孔结构及反应性的变化[J]. 燃料化学学报, 2011, 39(6): 432-437. (HUANG Yan-qin, SU De-ren, YIN Xiu-li, WU Chuang-zhi, MA Long-long. Changes of pore structure and reactivity during CO2 and H2O gasification of fir char[J]. Journal of Fuel Chemistry and Technology, 2011, 39(6): 432-437.)
    李庆峰, 房倚天, 张建民, 王洋, 时铭显, 孙国刚. 气化活性与孔比表面积的关系[J]. 煤炭转化, 2003, 26(3): 45-48. (LI Qing-feng, FANG Yi-tian, ZHANG Jian-min, WANG Yang, SHI Ming-xian, SUN Guo-gang. Relationship of gasification activity and pore structure[J]. Coal Conversion, 2003, 26(3): 45-48.)
    朱子彬, 马智华, 林石英, 平户瑞穗, 堀尾正靱. 高温下煤焦气化反应特性(Ⅱ): 细孔构造对煤焦气化反应的影响[J]. 化工学报, 1994, 45(2): 155-161. (ZHU Zi-bin, MA Zhi-hua, LIN Shi-ying, MITSUHO H, MASAYUKI H. Characteristics of coal char gasification at high temperature(Ⅱ): The effect of pore structure on coal char gasification[J]. Journal of Chemical Industry and Engineering (China), 1994, 45(2): 155-161.
    WANG B, SUN L S, SU S, XIANG J, HU S, FEI H. Char structural evolution during pyrolysis and its influence on combustion reactivity in air and oxy-fuel conditions[J]. Energy Fuels, 2012, 26(3): 1565-1574.
    BLANCO LPEZ M C, MARTINEZ-ALONSO A, TASCN J M D. N2 and CO2 adsorption on activated carbon fibres prepared from Nomex chars[J]. Carbon, 2000, 38(8): 1177-1182.
    赵冰, 周志杰, 丁路, 于广锁. 快速热处理石油焦与煤的微观结构变化及气化活性分析[J]. 燃料化学学报, 2013, 41(1): 40-45. (ZHAO Bing, ZHOU Zhi-jie, DING Lu, YU Guang-suo. Changes in the microstructure and gasification reactivity of petroleum coke and coal samples after rapid pyrolysis[J]. Journal of Fuel Chemistry and Technology, 2013, 41(1): 40-45.)
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Article Metrics

    Article views (1706) PDF downloads(917) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return