Hydrolytic hydrogenation of cellulose over Ni-WO<sub>3</sub>/SBA-15 catalysts

CAO Yue-ling; WANG Jun-wei; LI Qi-feng; YIN Ning; LIU Zhen-min; KANG Mao-qing; ZHU Yu-lei

Volume 41 Issue 08

Aug. 2013

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Article Navigation > Journal of Fuel Chemistry and Technology > 2013 > 41(08): 943-949

CAO Yue-ling, WANG Jun-wei, LI Qi-feng, YIN Ning, LIU Zhen-min, KANG Mao-qing, ZHU Yu-lei. Hydrolytic hydrogenation of cellulose over Ni-WO3/SBA-15 catalysts[J]. Journal of Fuel Chemistry and Technology, 2013, 41(08): 943-949.

Citation:

CAO Yue-ling, WANG Jun-wei, LI Qi-feng, YIN Ning, LIU Zhen-min, KANG Mao-qing, ZHU Yu-lei. Hydrolytic hydrogenation of cellulose over Ni-WO₃/SBA-15 catalysts[J]. Journal of Fuel Chemistry and Technology, 2013, 41(08): 943-949.

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Hydrolytic hydrogenation of cellulose over Ni-WO₃/SBA-15 catalysts

1.
Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China;
2.
University of Chinese Academy of Sciences, Beijing 100049, China

Received Date: 2013-04-13
Rev Recd Date: 2013-06-21
Publish Date: 2013-08-30

Abstract

Abstract

Series of non-precious metal catalysts Ni-WO₃/SBA-15 were prepared by means of incipient impregnation and applied to the hydrogenalysis of cellulose in aqueous solution. The effect of reaction temperature on the hydrolysis and morphology of cellulose, and the influence of Ni, WO₃ loading on the conversion of cellulose were investigated. High crystalline cellulose was transformed gradually into amorphous state with the increase of reaction temperature. H₂ temperature program reduction of the catalyst proved that a strong interaction existed between nickel and tungsten trioxide, which enhanced the ability of tungsten species to the cleavage of C-C bond and the activity of hydrogenation of nickel. Thus, the transformation of cellulose into ethylene glycol was strengthened markedly. The complete conversion of cellulose and 70.7% ethylene glycol yield were obtained over a 3%Ni-15%WO₃/SBA-15 catalyst under the reaction condition of 230 ℃and 6.0 MPa H₂ for 6.0 h.
- cellulose,
- Ni-WO₃/SBA-15,
- hydrogenolysis,
- ethylene glycol

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References(23)

References

ONDA A, OCHI T, YANAGISAWA K. Selective hydrolysis of cellulose into glucose over solid catalysts[J]. Green Chem, 2008, 10(10): 1033-1037.

SU Y, BROWN H M, HUANG X W, ZHOU X D, AMONETTE J E, ZHANG Z C. Single-step conversion of cellulose to 5-hydroxymethylfurfural(HMF), a versatile platform chemical[J]. Appl Catal A: Gen, 2009, 361(1/2): 117-122.

ZHENG M Y, WANG A Q, JI N, PANG J F, WANG X D, ZHANG T. Transition metal-tungsten bimetallic catalysts for the conversion of cellulose into ethylene glycol[J]. ChemSusChem, 2010, 3(1): 63-66.

HUBER G W, CHHEDA J N, BARRETT C J, DUMESIC J A. Production of liquid alkanes by aqueous-phase processing of biomass-derived carbohydrates[J]. Science, 2005, 308(5727): 1446-1450.

ZHANG J Z, LIU X, SUN M, MA X H, HAN Y. Direct conversion of cellulose to glycolic acid with a phosphomolybdic acid catalyst in a water medium[J]. ACS Catal, 2012, 2(8): 1698-1702.

FUKUOKA A, DHEPE P L. Catalytic conversion of cellulose into sugar alcohols[J]. Angew Chem, 2006, 118(31): 5285-5287.

DENG W P, TAN X S, FANG W H, ZHANG Q H, WANG Y. Conversion of cellusoe into sorbitol over carbon nanotube-supported ruthenium catalyst[J]. Catal Lett, 2009, 133(2): 167-174.

YOU S J, BAEK I G, KIM Y T, JEONG K E, CHAE H J, KIM T W, KIM C U, JEONG S Y, KIM T J, CHUNG Y M, OH S H, PARK E D. Direct conversion of cellulose into polyols or H₂ over Pt/Na(H)-ZSM-5[J]. Korean J Chem Eng, 2011, 28(3): 744-750.

GEBOERS J, VAN DE VYVER S, CARPENTIER K, JACOBS P, SELS B. Efficient catalytic conversion of concentrated cellulose feeds to hexitols with heteropoly acids and Ru on carbon[J]. Catal Commun, 2010, 46(20): 3577-3579.

LIANG G F, WU C Y, HE L M, MING J, CHENG H Y, ZHUO L H, ZHAO F Y. Selective conversion of concentrated microcrystalline cellulose to isosorbide over Ru/C catalyst[J]. Green Chem, 2011, 13(4): 839-842.

GEBOERS J, VAN DE VYVER S, CARPENTIER K, JACOBS P, SELS B. Efficient hydrolytic hydrogenation of cellulose in the presence of Ru-loaded zeolites and trace amounts of mineral acid[J]. Catal Commun, 2011, 47(19): 5590-5592.

JI N, ZHANG T, ZHENG M Y, WANG A Q, WANG H, WANG X D, CHENG J G. Direct catalytic conversion of cellulose into ethylene glycol using nickel-promoted tungsten carbide catalysts[J]. Angew Chem, 2008, 120(44): 8638-8641.

ZHANG Y H, WANG A Q, ZHANG T. A new 3D mesoporous carbon replicated from commercial silica as a catalyst support for direct conversion of cellulose into ethylene glycol[J]. Chem Comm, 2010, 46(6): 862-864.

WANG X C, MENG L Q, WU F, JIANG Y J, WANG L, MU X D. Efficient conversion of microcrystalline cellulose to 1,2- alkanediols over supported Ni catalysts[J]. Green Chem, 2012, 14(3): 758-765.

DING L N, WANG A Q, ZHENG M Y, ZHANG T. Selective transformation of cellulose into sorbitol by using a bifunc-tional nickel phosphide catalyst[J]. ChemSusChem, 2010, 3(7): 818-821.

REYES-LUYANDA D, FLORES-CRUZ J, MORALES-PREZ P J, ENCARNACIN-GMEZ L G, SHI F, VOYLES P M, CARDO-NA-MARTNEZ N. Bifunctional materials for the catalytic conversion of cellulose into soluble renewable biorefinery feedstocks[J]. Top Catal, 2012, 55(3): 148-161.

JOLLET V, CHAMBON F, RATABOUL F, CABIAC A, PINEL C, GUILLON E, ESSAYEM N. Non-catalyzed and Pt/γ-Al₂O₃-catalyzed hydrothermal cellulose dissolution-conversion: Influence of the reaction parameters and analysis of the unreacted cellulose[J]. Green Chem, 2009, 11(12): 2052-2060.

SHROTRI A, TANKSALE A, BELTRAMINI J N, GURAV H, CHILUKURI S V. Conversion of cellulose to polyols over promoted nickel catalysts[J]. Catal Sci Technol, 2012, 2(9): 1852-1858.

CAMPBELL C T, GOODMAN D W. A surface science investigation of the role of potassium promoters in nickel catalysts for CO hydrogenation[J]. Surf Sci, 1982, 123(2/3): 413-426.

SWAAN H M, KROLL V C H, MARTIN G A, MIRODATOS C. Deactivation of supported nickel catalysts during the re-forming of methane by carbon dioxide[J]. Catal Today, 1994, 21(1): 571-578.

LIU Y, LUO C, LIU H C. Tungsten trioxide promoted selective conversion of cellulose into propylene glycol and ethylene glycol on a ruthenium catalyst[J]. Angew Chem Int Ed, 2012, 51(13): 3249-3253.

VAN DE VYVER S, GEBOERS J, JACOBS P A, SELS B F. Recent advances in the catalytic conversion of cellulose[J]. ChemCatChem, 2011, 3(1): 82-94.

TAI Z J, ZHANG J Y, WANG A Q, ZHENG M Y, ZHANG T. Temperature-controlled phase-transfer catalysis for ethylene glycol production from cellulose[J]. Chem Commun, 2012, 48(56): 7052-7054.

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