Catalytic decomposition of N<sub>2</sub>O over potassium-modified Cu-Co spinel oxides

DOU Zhe; ZHANG Hai-jie; PAN Yan-fei; XU Xiu-feng

Volume 42 Issue 02

Feb. 2014

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DOU Zhe, ZHANG Hai-jie, PAN Yan-fei, XU Xiu-feng. Catalytic decomposition of N2O over potassium-modified Cu-Co spinel oxides[J]. Journal of Fuel Chemistry and Technology, 2014, 42(02): 238-245.

Citation:

DOU Zhe, ZHANG Hai-jie, PAN Yan-fei, XU Xiu-feng. Catalytic decomposition of N₂O over potassium-modified Cu-Co spinel oxides[J]. Journal of Fuel Chemistry and Technology, 2014, 42(02): 238-245.

DOU Zhe, ZHANG Hai-jie, PAN Yan-fei, XU Xiu-feng. Catalytic decomposition of N2O over potassium-modified Cu-Co spinel oxides[J]. Journal of Fuel Chemistry and Technology, 2014, 42(02): 238-245.

Citation:

DOU Zhe, ZHANG Hai-jie, PAN Yan-fei, XU Xiu-feng. Catalytic decomposition of N₂O over potassium-modified Cu-Co spinel oxides[J]. Journal of Fuel Chemistry and Technology, 2014, 42(02): 238-245.

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Catalytic decomposition of N₂O over potassium-modified Cu-Co spinel oxides

School of Chemistry and Chemical Engineering; Shandong Provincial Key Lab of Chemical Engineering and Process, Yantai University, Yantai 264005, China

Funds: Research Project from Shandong Provincial Department of Science and Technology (2012GSF11708).

Received Date: 2013-09-01
Rev Recd Date: 2013-12-04
Publish Date: 2014-02-28

Abstract

Abstract

Cu-Co spinel oxides with different compositions were prepared for N₂O catalytic decomposition in the presence of oxygen. The active catalyst of Cu_0.8Co_0.2Co₂O₄ was incipiently impregnated by alkali metal salt solutions to prepare the modified catalysts. These catalysts were characterized by BET, XRD, SEM and XPS techniques, and their catalytic activity for N₂O decomposition was tested. The effect of alkali metal species, potassium precursors and potassium loadings on catalytic activity was investigated. It was found that the catalytic activity of Cu_0.8Co_0.2Co₂O₄ modified by K₂CO₃ was much higher than that of bare oxide, while Cs/Cu_0.8Co_0.2Co₂O₄ was inferior to Cu_0.8Co_0.2Co₂O₄ for N₂O decomposition. In the case of K/Cu_0.8Co_0.2Co₂O₄ with different potassium precursors, the catalyst activity was largely enhanced by the addition of K₂CO₃, while the doping of KNO₃ and CH₃COOK notably depressed the catalytic activity. Over the optimal catalyst of 0.05K/Cu_0.8Co_0.2Co₂O₄, 100% and 87.6% conversion of N₂O was reached at 400 SymbolpB@ C under the atmosphere of oxygen only and oxygen-steam together, respectively. In addition, K₂CO₃-modified catalyst in both reaction atmospheres showed higher stability than un-modified catalyst.
- catalytic decomposition of N₂O,
- Cu-Co mixed oxides,
- potassium additive,
- catalytic activity

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References(14)

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