Synthesis of binuclear metal phthalocyanine and its catalytic performance in the oxidative desulfurization of dibenzothiophene

ZHANG Juan; HU Yan-hui; CHENG Lin-yan; REN Teng-jie; LI Jun-pan; ZHAO Di-shun

Volume 42 Issue 12

Dec. 2014

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Article Navigation > Journal of Fuel Chemistry and Technology > 2014 > 42(12): 1493-1499

ZHANG Juan, HU Yan-hui, CHENG Lin-yan, REN Teng-jie, LI Jun-pan, ZHAO Di-shun. Synthesis of binuclear metal phthalocyanine and its catalytic performance in the oxidative desulfurization of dibenzothiophene[J]. Journal of Fuel Chemistry and Technology, 2014, 42(12): 1493-1499.

Citation:

ZHANG Juan, HU Yan-hui, CHENG Lin-yan, REN Teng-jie, LI Jun-pan, ZHAO Di-shun. Synthesis of binuclear metal phthalocyanine and its catalytic performance in the oxidative desulfurization of dibenzothiophene[J]. Journal of Fuel Chemistry and Technology, 2014, 42(12): 1493-1499.

Citation:

ZHANG Juan, HU Yan-hui, CHENG Lin-yan, REN Teng-jie, LI Jun-pan, ZHAO Di-shun. Synthesis of binuclear metal phthalocyanine and its catalytic performance in the oxidative desulfurization of dibenzothiophene[J]. Journal of Fuel Chemistry and Technology, 2014, 42(12): 1493-1499.

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Synthesis of binuclear metal phthalocyanine and its catalytic performance in the oxidative desulfurization of dibenzothiophene

1.
College of Chemistry and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, China;
2.
China Huanqiu Contracting & Engineering Corporation, Beijing 100000, China

Received Date: 2014-05-29
Rev Recd Date: 2014-09-04
Publish Date: 2014-12-30

Abstract

Abstract

Binuclear cobalt phthalocyanine was synthesized by microwave method and characterized by infrared spectroscopy, UV-visible spectroscopy and thermogravimetry; its catalytic performance in the oxidative desulfurization of dibenzothiophene (DBT) was investigated. The results showed that the binuclear cobalt phthalocyanine exhibits the highest activity among five catalysts; over it, with the catalyst amount of 0.01 g(cat)/5 mL and air flow rate of 80 mL/min, the sulfur removal rate reaches 97.17% after reaction at 40 ℃ for 1 h. The product of DBT oxidation is DBTO₂, as verified by the FT-IR and mass spectrometry. The catalytic performance in the oxidation of aromatics and olefins was also investigated, which illustrates that current process using binuclear cobalt phthalocyanine as the catalyst has little influence on the quality of the oil product. Moreover, the catalyst can be reused for 5 times without significant decrease of its oxidation activity.
- binuclear cobalt phthalocyanine,
- dibenzothiophene,
- catalytic oxidation,
- desulfurization

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